Article

Epoxy coating with self-healing capability based on a 2-mercaptobenzothiazole-loaded CeO₂ nanocontainer

Corresponding Author

Mir Ghasem Hosseini

[email protected]

orcid.org/0000-0002-3117-8608

Electrochemistry Research Laboratory, Department of Physical Chemistry, Chemistry Faculty, University of Tabriz, Tabriz, Iran

Department of Materials Science and Nanotechnology, Engineering Faculty, Near East University, North Cyprus, Mersin 10, Nicosia, 99138 Turkey

Correspondence to: M. G. Hosseini (E-mail: [email protected])Search for more papers by this author

Khadijeh Aboutalebi,

Khadijeh Aboutalebi

Electrochemistry Research Laboratory, Department of Physical Chemistry, Chemistry Faculty, University of Tabriz, Tabriz, Iran

Search for more papers by this author

Mir Ghasem Hosseini,

Corresponding Author

Mir Ghasem Hosseini

[email protected]

orcid.org/0000-0002-3117-8608

Electrochemistry Research Laboratory, Department of Physical Chemistry, Chemistry Faculty, University of Tabriz, Tabriz, Iran

Department of Materials Science and Nanotechnology, Engineering Faculty, Near East University, North Cyprus, Mersin 10, Nicosia, 99138 Turkey

Correspondence to: M. G. Hosseini (E-mail: [email protected])Search for more papers by this author

Khadijeh Aboutalebi,

Khadijeh Aboutalebi

Electrochemistry Research Laboratory, Department of Physical Chemistry, Chemistry Faculty, University of Tabriz, Tabriz, Iran

Search for more papers by this author

First published: 18 December 2018

https://doi.org/10.1002/app.47297

Citations: 22

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ABSTRACT

In this study, we demonstrated a facile approach for the synthesis of nanocontainers using the encapsulation of a 2-mercaptobenzothiazole (MBT) inhibitor; these nanocontainers were capable of responsively releasing a corrosion inhibitor and of self-healing performances. The anticorrosive performance of the CeO₂ nanocontainers was investigated with electrochemical impedance spectroscopy (EIS) measurement in a saline electrolyte via the incorporation of different weight percentages (0.5, 1, and 2 wt %) of synthesized nanocontainer in epoxy (EP) resin. The EIS results show that the loading of 1 wt % CeO₂ nanocontainer containing MBT inhibitor in the epoxy (EP) coating [EP/NC MBT–CeO₂ (1%)] provided the highest R_coat, the lowest constant phase element of coating, and the optimum release of MBT at different operating pHs. The highest coating resistance R_coat values of this coating (7.81 × 10⁷ Ω cm²) were about 12 and 8573 times greater than those considered for EP–CeO₂ and EP coatings, respectively. Different releases of the MBT inhibitor were detected at various pHs. We found that the coating operating in acidic media exhibited a better self-healing performance. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47297.

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Volume136, Issue15

April 15, 2019

47297

Epoxy coating with self-healing capability based on a 2-mercaptobenzothiazole-loaded CeO₂ nanocontainer

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Epoxy coating with self-healing capability based on a 2-mercaptobenzothiazole-loaded CeO₂ nanocontainer