Mechanical properties and morphology of hot drawn polyacrylonitrile nanofibrous yarn
Corresponding Author
S. A. Hosseini Ravandi
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Nanotechnology & Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156 83111, Iran
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran===Search for more papers by this authorE. Hassanabadi
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Search for more papers by this authorH. Tavanai
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Search for more papers by this authorR. A. Abuzade
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Nanotechnology & Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156 83111, Iran
Search for more papers by this authorCorresponding Author
S. A. Hosseini Ravandi
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Nanotechnology & Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156 83111, Iran
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran===Search for more papers by this authorE. Hassanabadi
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Search for more papers by this authorH. Tavanai
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Search for more papers by this authorR. A. Abuzade
Department of Textile Engineering, Isfahan University of Technology, Isfahan 84156-83111, Iran
Nanotechnology & Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156 83111, Iran
Search for more papers by this authorAbstract
In this study PAN nanofibrous yarn was produced by two-nozzle conjugated electrospinning method. The nanofibrous yarns were drawn continuously in boiling water with drawing ratios of 1, 2, 3, and 4. The morphology of drawn yarns was investigated by scanning electron microscopy and tested for tensile properties as well as untreated yarn. The results showed that the nanofiber alignment in the yarn axis direction, the tensile strength, and tensile modulus of yarn increases as a result of drawing while the tensile strain and work of rapture decrease. X-ray diffraction patterns of the produced yarns were analyzed as well. It was found that crystallinity index increases as the draw ratio increases. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
References
- 1 Ondarcuhu, T.; Joachim, C.; Eur Phys Lett 1998, 42, 215.
- 2 Martin, C. R. Chem Mater 1996, 8, 1739.
- 3
Feng, L.;
Li, S.;
Li, H.; Zhai, J.; Song, Y.; Jiang, L.; Zhu, D.
Angew Chem Int Ed
2002,
41,
1221.
10.1002/1521-3773(20020402)41:7<1221::AID-ANIE1221>3.0.CO;2-G CAS PubMed Web of Science® Google Scholar
- 4
Ma, P. X.;
Zhang, R.
J Biomed Mat Res
1999,
46,
60.
10.1002/(SICI)1097-4636(199907)46:1<60::AID-JBM7>3.0.CO;2-H CAS PubMed Web of Science® Google Scholar
- 5
Liu, G. J.;
Ding, J. F.;
Qiao, L. J.; Guo, A.; Dymov, B. P.; Gleeson, J. T.; Hashimoto, T.; Saijo, K.
Chem A Eur J
1999,
5,
2740.
10.1002/(SICI)1521-3765(19990903)5:9<2740::AID-CHEM2740>3.0.CO;2-V CAS Web of Science® Google Scholar
- 6 Whitesides, G. M.; Grzybowski, B. Science 2002, 295, 2418.
- 7 Deitzel, J. M.; Kleinmeyer, J.; Hirvonen, J. K.; Beck, T. N. C.; Polymer 2001, 42, 8163.
- 8 Smith, L. A. Colloids Surf B Biointerf 2004, 39, 125.
- 9 Greiner, A.; Wendorff, J. H. Angew Chem Int Ed 2007, 46, 5670.
- 10 Li, D.; Xia, Y. Adv Mater 2004, 14, 1151.
- 11 Yarin, A. L.; Koombhongse, S.; Reneker, D. H. J Appl Phys 2001, 89, 3018.
- 12 Shin, Y. M.; Hohman, M. M.; Brenner, M. P.; Rutledge, G. C. Appl Phys Lett 2001, 78, 1149.
- 13 Subbiah, T.; Bhat, G. S.; Tock, R. W.; Parameswaran, S.; Ramkumar, S. S. J Appl Polym Sci 2005, 96, 557.
- 14 Quynh, P. P.; Upma, S. Tissue Eng 2006, 12, 1197.
- 15 Yang, F.; Kotaki, M. J Biomater Sci Polym Ed 2004, 15, 1483.
- 16 Huang, Z. M.; Zhang, Y. Z.; Kotaki, M.; Ramakrishna, S. Compos Sci Technol 2003, 63, 2223.
- 17 Chuangchote, S.; Supaphol, P. J Nanosci Nanotechnol 2006, 6, 125.
- 18 Bazbouz, M. B.; Stylios, G. K. J Appl Polym Sci 2008, 107, 3023.
- 19 Moon, S. C.; Choi, J.; Farris, R. J. J Appl Polym Sci 2008, 109, 691.
- 20 Yang, D.; Zhang, J.; Zhang, J.; Nie, J. J Appl Polym Sci 2008, 110, 3368.
- 21 Chanunpanich, N.; Byun, H. J Appl Polym Sci 2007, 106, 3648.
- 22 Pan, H.; Li, L.; Hu, L.; Cui, X. Polymer 2006, 47, 4901.
- 23 Matthews, J. A.; Wnek, G. E.; Simpson, D. G.; Bowlin, G. L.; Biomacromolecules 2002, 3, 232.
- 24 Doshi, J.; Reneker, D. H. J Electrost 1995, 35, 151.
- 25 Bornat, A. US Pat 1987, 46,89,186.
- 26 Berry, J. P. US Pat 1990, 49,65,110.
- 27 Theron, A.; Zussman, E.; Yarin, A. L.; Nanotechnol 2001, 12, 384.
- 28 Dersch, R.; Liu, T.; Schaper, A. K.; Greiner, A.; Wendorff, J. H. J Polym Sci A 2003, 41, 545.
- 29 Tan, E. P. S.; Ng, S. Y.; Lim, C. T. Biomaterials 2005, 26, 1453.
- 30 Li, D.; Wang, Y.; Xia, Y. Nano Lett 2003, 3, 1167.
- 31 Li, D.; Wang, Y.; Xia, Y. Adv Mater 2004, 16, 361.
- 32 Fennessey, S. F.; Farris, R. J. Polymer 2004, 45, 4217.
- 33 Fennessey, S. F.; Pedicini, A.; Farris, R. J. ACS Symp Ser 2006, 918, 300.
- 34 Wang, X.; Zhang, K.; Zhu, M.; Hsiao, B. S.; Chu, B. Macromol Rapid Commun 2008, 29, 826.
- 35 Dabirian, F.; Hosseini, Y.; Ravandi, S. A. H. J Text Inst 2007, 98, 237.
- 36 Dabirian, F.; Hosseini, S. A. Fibres Text East Eur 2009, 74, 45.
- 37 Jalili, R.; Morshed, M.; Hosseini, S. A. J Appl Polym Sci 2006, 101, 4350.
- 38 Hou, H. Q.; Ge, J. J.; Zeng, J.; Li, Q.; Reneker, D. H.; Greiner, A.; Cheng, S. Z. D. Chem Mater 2005, 17, 967.
- 39 Xu, Q.; Xu, L.; Cao, W.; Wu, S. Polym Adv Technol 2005, 16, 642.
- 40 Sadrjahani, M.; Hosseini, S. A.; Mottaghitalab, V.; Haghi, A. K.; Braz J Chem Eng 2010, 27, 583.
- 41 Zhou, Z.; Lai, C.; Zhang, L.; Qian, Y.; Hou, H.; Reneker, D. H.; Fong, H. Polymer 2009, 50, 2999.
- 42 Zussman, E.; Chen, X.; Ding, W.; Calabri, L.; Dikin, D. A.; Quintana, J. P.; Ruoff, R. S. Carbon 2005, 43, 2175.
- 43
Gupta, V. B.;
Kothari, V. K.
Manufactured Fiber Technology;
Chapman & Hall:
London,
1997.
10.1007/978-94-011-5854-1 Google Scholar
- 44 Zhang, J.; Huang, L. Q.; Wang, S. Y. J Appl Polym Sci 2006, 101, 787.
- 45 Gupta, A. K.; Maiti, A. K. J Appl Polym Sci 1982, 27, 2409.
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