The first report on the atom transfer radical polymerization of an optically active acidic monomer based on L-phenylalanine
Corresponding Author
Shadpour Mallakpour
Department of Chemistry, Organic Polymer Chemistry Research Laboratory, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran
Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran
Department of Chemistry, Organic Polymer Chemistry Research Laboratory, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran===Search for more papers by this authorZahra Rafiee
Department of Chemistry, Yasouj University, Yasouj 75914-353, Islamic Republic of Iran
Search for more papers by this authorCorresponding Author
Shadpour Mallakpour
Department of Chemistry, Organic Polymer Chemistry Research Laboratory, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran
Nanotechnology and Advanced Materials Institute, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran
Department of Chemistry, Organic Polymer Chemistry Research Laboratory, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran===Search for more papers by this authorZahra Rafiee
Department of Chemistry, Yasouj University, Yasouj 75914-353, Islamic Republic of Iran
Search for more papers by this authorAbstract
For the first time, acidic monomer chiral N-acryloyl-L-phenylalanine was polymerized directly by atom transfer radical polymerization under mild conditions. Controlled polymerization was carried out in pure water, methanol/water mixture, or pure methanol using water-soluble initiators, such as 2-hydroxyethyl-2′-methyl-2′-bromopropionate and sodium-4-(bromomethyl)benzoate at room temperature. The corresponding optically active biocompatible amino acid-based homopolymers were obtained in good yields with narrow molecular weight distributions. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
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