Tensile-Strained Cu Penetration Electrode Boosts Asymmetric C−C Coupling for Ampere-Level CO2-to-C2+ Reduction in Acid
Shoujie Li
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
These authors contributed equally to this work.
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Resources (lead), Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorGangfeng Wu
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
These authors contributed equally to this work.
Contribution: Data curation (equal), Writing - original draft (equal)
Search for more papers by this authorJianing Mao
University of Chinese Academy of Sciences, 100049 Beijing, China
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 201204 Shanghai, China
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201204 Shanghai, China
These authors contributed equally to this work.
Contribution: Data curation (equal), Writing - original draft (equal)
Search for more papers by this authorAohui Chen
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorXiaohu Liu
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorJianrong Zeng
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201204 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorYiheng Wei
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorJiangjiang Wang
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorHuanyi Zhu
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorJiayu Xia
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorXiaotong Wang
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorGuihua Li
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorYanfang Song
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorCorresponding Author
Xiao Dong
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Conceptualization (equal), Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Wei Wei
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Supervision (equal)
Search for more papers by this authorCorresponding Author
Wei Chen
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Search for more papers by this authorShoujie Li
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
These authors contributed equally to this work.
Contribution: Conceptualization (lead), Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Resources (lead), Writing - original draft (lead), Writing - review & editing (lead)
Search for more papers by this authorGangfeng Wu
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
These authors contributed equally to this work.
Contribution: Data curation (equal), Writing - original draft (equal)
Search for more papers by this authorJianing Mao
University of Chinese Academy of Sciences, 100049 Beijing, China
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 201204 Shanghai, China
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201204 Shanghai, China
These authors contributed equally to this work.
Contribution: Data curation (equal), Writing - original draft (equal)
Search for more papers by this authorAohui Chen
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorXiaohu Liu
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorJianrong Zeng
Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201204 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorYiheng Wei
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorJiangjiang Wang
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorHuanyi Zhu
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorJiayu Xia
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorXiaotong Wang
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorGuihua Li
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorYanfang Song
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Data curation (supporting)
Search for more papers by this authorCorresponding Author
Xiao Dong
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Conceptualization (equal), Supervision (equal), Writing - review & editing (equal)
Search for more papers by this authorCorresponding Author
Wei Wei
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Contribution: Supervision (equal)
Search for more papers by this authorCorresponding Author
Wei Chen
Low-Carbon Conversion Science and Engineering Center, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
University of Chinese Academy of Sciences, 100049 Beijing, China
State Key Laboratory of Low Carbon Catalysis and Carbon Dioxide Utilization, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 201210 Shanghai, China
Search for more papers by this authorGraphical Abstract
Tensile-strained copper hollow-fiber penetration electrode (Cu HPE) enhances the asymmetric C−C coupling to steer the selectivity and activity of multicarbon (C2+) products. A faradaic efficiency of 84.5 % and a partial current density as high as 3.1 A cm−2 for C2+ products, alongside a single-pass carbon efficiency of 81.5 % and stable electrolysis for 240 h were demonstrated in a strong acidic electrolyte (pH=1).
Abstract
The synthesis of multicarbon (C2+) products remains a substantial challenge in sustainable CO2 electroreduction owing to the need for sufficient current density and faradaic efficiency alongside carbon efficiency. Herein, we demonstrate ampere-level high-efficiency CO2 electroreduction to C2+ products in both neutral and strongly acidic (pH=1) electrolytes using a hierarchical Cu hollow-fiber penetration electrode (HPE). High concentration of K+ could concurrently suppress hydrogen evolution reaction and facilitate C−C coupling, thereby promoting C2+ production in strong acid. By optimizing the K+ and H+ concentration and CO2 flow rate, a faradaic efficiency of 84.5 % and a partial current density as high as 3.1 A cm−2 for C2+ products, alongside a single-pass carbon efficiency of 81.5 % and stable electrolysis for 240 h were demonstrated in a strong acidic solution of H2SO4 and KCl (pH=1). Experimental measurements and density functional theory simulations suggested that tensile-strained Cu HPE enhances the asymmetric C−C coupling to steer the selectivity and activity of C2+ products.
Conflict of Interests
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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