Minireview
Morphological Anisotropy in Metal–Organic Framework Micro/Nanostructures
Tong Bao,
Yingying Zou,
Chaoqi Zhang,
Prof. Chengzhong Yu,
Prof. Chao Liu,
Tong Bao
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorYingying Zou
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorChaoqi Zhang
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Chengzhong Yu
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, QLD 4072 Australia
Search for more papers by this authorCorresponding Author
Prof. Chao Liu
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorTong Bao,
Yingying Zou,
Chaoqi Zhang,
Prof. Chengzhong Yu,
Prof. Chao Liu,
Tong Bao
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorYingying Zou
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorChaoqi Zhang
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorCorresponding Author
Prof. Chengzhong Yu
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Australian Institute for Bioengineering and Nanotechnology, The University of Queensland, Brisbane, QLD 4072 Australia
Search for more papers by this authorCorresponding Author
Prof. Chao Liu
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai, 200241 P. R. China
Search for more papers by this authorGraphical Abstract
Metal–organic framework micro/nanoparticles (MOF MNPs) are reviewed with a focus on their morphological anisotropy, which plays a unique role in producing innovative structures and regulating properties with enhanced performance.
Abstract
Anisotropy plays a unique role in the structural regulation of metal–organic frameworks (MOFs) and their composites, especially at the micro- and nanoscale. However, there is a lack of a understanding of MOF micro/nanoparticles (MNPs) from the perspective of morphological anisotropy. In this Minireview, recent advances in anisotropic MOF MNPs are summarized, with a focus on how morphological anisotropy leads to innovative structures and modulates properties. First, anisotropic pristine MOF MNPs with diverse morphologies are introduced and classified by their morphology-dependent and morphology-independent anisotropy. Secondly, the anisotropy-enabled site-selective higher-order construction of MOF-based materials is highlighted. Finally, challenges and prospects for anisotropic MOFs are discussed, aiming to provide inspiration for further developments in this interesting research field.
Conflict of interest
The authors declare no conflict of interest.
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