Direct NO Reduction by a Biomimetic Iron(II) Pyrazolate MOF
Dr. Zhongzheng Cai
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorDr. Wenjie Tao
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorDr. Curtis E. Moore
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorProf. Dr. Shiyu Zhang
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Casey R. Wade
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorDr. Zhongzheng Cai
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorDr. Wenjie Tao
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorDr. Curtis E. Moore
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorProf. Dr. Shiyu Zhang
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorCorresponding Author
Prof. Dr. Casey R. Wade
Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Ave, Columbus, OH, 43210 USA
Search for more papers by this authorGraphical Abstract
A novel iron(II) metal–organic framework containing accessible coordination sites on adjacent metal centers facilitates the direct reduction of NO to N2O.
Abstract
A novel metal-organic framework (MOF) containing one-dimensional, Fe2+ chains bridged by dipyrazolate linkers and N,N-dimethylformamide (DMF) ligands has been synthesized. The unusual chain-type metal nodes feature accessible coordination sites on adjacent metal centers, resulting in motifs that are reminiscent of the active sites in non-heme diiron enzymes. The MOF facilitates direct reduction of nitric oxide (NO), producing nearly quantitative yields of nitrous oxide (N2O) and emulating the reactivity of flavodiiron nitric oxide reductases (FNORs). The ferrous form of the MOF can be regenerated via a synthetic cycle involving reduction with cobaltocene (CoCp2) followed by reaction with trimethylsilyl triflate (TMSOTf).
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