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The Role of Organoferrates in Iron-Catalyzed Cross-Couplings
M. Sc. Sebastian Sandl,
Prof. Dr. Axel Jacobi von Wangelin,
M. Sc. Sebastian Sandl
Department of Chemistry, University of Hamburg, Martin Luther King Platz 6, 20146 Hamburg, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Axel Jacobi von Wangelin
Department of Chemistry, University of Hamburg, Martin Luther King Platz 6, 20146 Hamburg, Germany
Search for more papers by this authorM. Sc. Sebastian Sandl,
Prof. Dr. Axel Jacobi von Wangelin,
M. Sc. Sebastian Sandl
Department of Chemistry, University of Hamburg, Martin Luther King Platz 6, 20146 Hamburg, Germany
Search for more papers by this authorCorresponding Author
Prof. Dr. Axel Jacobi von Wangelin
Department of Chemistry, University of Hamburg, Martin Luther King Platz 6, 20146 Hamburg, Germany
Search for more papers by this authorDedicated to Professor Klaus Jonas
Graphical Abstract
Recent groundbreaking studies on organoferrates have demonstrated that coordinatively unsaturated three-coordinate-σ-alkylferrates are active catalysts in Fe-catalyzed cross-couplings with Grignard reagents and that pronounced solvent and counterion effects dictate metalate speciation and catalyst activity. Thanks to modern spectroscopic methods, sensitive catalyst intermediates could be analyzed.
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