High iso Aldehyde Selectivity in the Hydroformylation of Short-Chain Alkenes
Dr. Leo Iu
EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. José A. Fuentes
EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. Mesfin E. Janka
Eastman Chemical Company, 200 South Wilcox Drive, Kingsport, TN, 37660 USA
Search for more papers by this authorDr. Kevin J. Fontenot
Eastman Chemical Company, 200 South Wilcox Drive, Kingsport, TN, 37660 USA
Search for more papers by this authorCorresponding Author
Prof. Matthew L. Clarke
EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. Leo Iu
EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. José A. Fuentes
EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST UK
Search for more papers by this authorDr. Mesfin E. Janka
Eastman Chemical Company, 200 South Wilcox Drive, Kingsport, TN, 37660 USA
Search for more papers by this authorDr. Kevin J. Fontenot
Eastman Chemical Company, 200 South Wilcox Drive, Kingsport, TN, 37660 USA
Search for more papers by this authorCorresponding Author
Prof. Matthew L. Clarke
EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, KY16 9ST UK
Search for more papers by this authorGraphical Abstract
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.
Abstract
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.
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