Multifunctional Catalysts for H2O2-Resistant Hydrogen Fuel Cells
Yuki Mori
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Tatsuya Ando
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Takahiro Matsumoto
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Takeshi Yatabe
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Mitsuhiro Kikkawa
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Ki-Seok Yoon
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Prof. Seiji Ogo
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorYuki Mori
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Tatsuya Ando
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Takahiro Matsumoto
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Takeshi Yatabe
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Mitsuhiro Kikkawa
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorDr. Ki-Seok Yoon
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorCorresponding Author
Prof. Seiji Ogo
Department of Chemistry and Biochemistry, Graduate School of Engineering, Center for Small Molecule Energy, International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395 Japan
Search for more papers by this authorGraphical Abstract
Peroxide allowed: The development of hydrogen fuel cells is greatly hindered by the unwanted generation of H2O2 at the cathode. A non-Pt cathode catalyst is now shown to be capable of simultaneously reducing both O2 and H2O2, thus rendering H2O2 a useful part of the feed stream. The applicability of this unique catalyst is demonstrated by employing it in a fuel cell running on H2/CO and O2/H2O2.
Abstract
The development of hydrogen fuel cells is greatly hindered by the unwanted generation of H2O2 at the cathode. A non-Pt cathode catalyst is now shown to be capable of simultaneously reducing both O2 and H2O2, thus rendering H2O2 a useful part of the feed stream. The applicability of this unique catalyst is demonstrated by employing it in a fuel cell running on H2/CO and O2/H2O2.
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