Volume 55, Issue 43 pp. 13380-13382
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New Avenues in s-Block Chemistry: Beryllium(0) Complexes

Dr. Jason L. Dutton

Corresponding Author

Dr. Jason L. Dutton

Department of Chemistry and Physics, La Trobe Institute for Molecular Sciences, La Trobe University, Melbourne, Victoria, Australia

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Prof. Dr. Gernot Frenking

Corresponding Author

Prof. Dr. Gernot Frenking

Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 1, 35032 Marburg, Germany

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First published: 17 August 2016
Citations: 29

Graphical Abstract

A rarely used element: The chemistry of ligand-stabilized complexes in oxidation state zero was recently extended to the s block with the discovery of a Be1 complex stabilized by a cyclic (alkyl)(amino)carbene. Combined experimental and theoretical studies provided conclusive evidence that the complex contains beryllium(0).

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