New Avenues in s-Block Chemistry: Beryllium(0) Complexes
Corresponding Author
Dr. Jason L. Dutton
Department of Chemistry and Physics, La Trobe Institute for Molecular Sciences, La Trobe University, Melbourne, Victoria, Australia
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Prof. Dr. Gernot Frenking
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 1, 35032 Marburg, Germany
Search for more papers by this authorCorresponding Author
Dr. Jason L. Dutton
Department of Chemistry and Physics, La Trobe Institute for Molecular Sciences, La Trobe University, Melbourne, Victoria, Australia
Search for more papers by this authorCorresponding Author
Prof. Dr. Gernot Frenking
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 1, 35032 Marburg, Germany
Search for more papers by this authorGraphical Abstract
A rarely used element: The chemistry of ligand-stabilized complexes in oxidation state zero was recently extended to the s block with the discovery of a Be1 complex stabilized by a cyclic (alkyl)(amino)carbene. Combined experimental and theoretical studies provided conclusive evidence that the complex contains beryllium(0).
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