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The Formal Oxidation States of Iridium Now Run from −III to +IX^†

Corresponding Author

Prof. Dr. Pekka Pyykkö

[email protected]

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)Search for more papers by this author

Dr. Wen-Hua Xu,

Dr. Wen-Hua Xu

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, 710127 Xi'an (China)

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Prof. Dr. Pekka Pyykkö,

Corresponding Author

Prof. Dr. Pekka Pyykkö

[email protected]

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)Search for more papers by this author

Dr. Wen-Hua Xu,

Dr. Wen-Hua Xu

Department of Chemistry, University of Helsinki, P.O. Box 55 (A.I. Virtasen aukio 1), FIN-00014 Helsinki (Finland)

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University, 710127 Xi'an (China)

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First published: 16 December 2014

https://doi.org/10.1002/anie.201410615

Citations: 29

^†

We thank Prof. Dage Sundholm for organizing the support from The Academy of Finland (Project 275845) for W.-H.X. at Helsinki and the Northwest University, Xi'an for a leave of absence.

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Graphical Abstract

Rarer than a new element: Recently Wang et al. produced the [(Ir^+IX)O₄]⁺ ion by a pulsed laser vaporization/thermal expansion method and studied it by IR photodissociation spectroscopy. The oxidation state of +IX had been unknown previously. The picture shows the mass spectra for the argon-tagged iridium oxide species.

References

1G.-J. Wang, M.-F. Zhou, J. T. Goettel, G. J. Schrobilgen, J. Su, J. Li, T. Schlöder, S. Riedel, Nature 2014, 514, 475–478.
10.1038/nature13795
CAS PubMed Web of Science® Google Scholar
2J. M. Allen, W. W. Brennessel, C. E. Buss, J. E. Ellis, M. E. Minyaev, M. Pink, G. F. Warnock, M. L. Winzenburg, V. G. Young, Jr., Inorg. Chem. 2001, 40, 5279–5284.
10.1021/ic0105011
CAS PubMed Web of Science® Google Scholar
3Y. T. Oganessian, F. S. Abdullin, P. D. Bailey, D. E. Benker, M. E. Bennett, S. N. Dmitriev, J. G. Ezold, J. H. Hamilton, R. A. Henderson, M. G. Itkis, Y. V. Lobanov, A. N. Mezentsev, K. J. Moody, S. L. Nelson, A. N. Polyakov, C. E. Porter, A. Ramayya, F. D. Riley, J. B. Roberto, M. A. Ryabinin, K. P. Rykaczewski, R. N. Sagaidak, D. A. Shaughnessy, I. Shirokovsky, M. A. Stoyer, V. G. Subbotin, R. Sudowe, A. M. Sukhov, Y. S. Tsyganov, V. K. Utyonkov, A. A. Voinov, G. K. Vostokin, P. A. Wilk, Phys. Rev. Lett. 2010, 104, 142502.
10.1103/PhysRevLett.104.142502
CAS PubMed Web of Science® Google Scholar
4A. Karpov, J. Nuss, U. Wedig, M. Jansen, Angew. Chem. Int. Ed. 2003, 42, 4818–4821;
10.1002/anie.200352314
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2003, 115, 4966–4969.
10.1002/ange.200352314
Web of Science® Google Scholar
5C. H. L. Goodman, J. Phys. Chem. Solids 1958, 6, 305–314.
10.1016/0022-3697(58)90050-7
CAS Web of Science® Google Scholar
6P. Pyykkö, Angew. Chem. Int. Ed. 2002, 41, 3573–3578;
10.1002/1521-3773(20021004)41:19<3573::AID-ANIE3573>3.0.CO;2-R
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2002, 114, 3723–3728.
10.1002/1521-3757(20021004)114:19<3723::AID-ANGE3723>3.0.CO;2-6
Web of Science® Google Scholar
7P. Pyykkö, Phys. Chem. Chem. Phys. 2012, 14, 14734–14742.
10.1039/c2cp24003c
CAS PubMed Web of Science® Google Scholar
8P. Pyykkö, J. Organomet. Chem. 2006, 691, 4336–4340.
10.1016/j.jorganchem.2006.01.064
CAS Web of Science® Google Scholar
9J. E. Ellis, Inorg. Chem. 2006, 45, 3167–3186.
10.1021/ic052110i
CAS PubMed Web of Science® Google Scholar
10W. T. K. Chan, W. T. Wong, Polyhedron 2013, 52, 43–61.
10.1016/j.poly.2012.09.004
CAS Web of Science® Google Scholar
11P. Pyykkö, Angew. Chem. Int. Ed. 2004, 43, 4412–4456;
10.1002/anie.200300624
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2004, 116, 4512–4557.
10.1002/ange.200300624
Web of Science® Google Scholar
12Y. Gong, M.-F. Zhou, M. Kaupp, S. Riedel, Angew. Chem. Int. Ed. 2009, 48, 7879–7883;
10.1002/anie.200902733
CAS PubMed Web of Science® Google Scholar
Angew. Chem. 2009, 121, 8019–8023.
10.1002/ange.200902733
Web of Science® Google Scholar
13D. Himmel, C. Knapp, M. Patzschke, S. Riedel, ChemPhysChem 2010, 11, 865–869. See also [15].
10.1002/cphc.200900910
CAS PubMed Web of Science® Google Scholar
14S. Ritter, Chem. Eng. News 2014, 92( 43), 7.
Web of Science® Google Scholar
15A. I. Dement′ev, M. L. Kuznetsov, Y. M. Kiselev, Russian J. Inorg. Chem. 1997, 42, 1052–1057;
Google Scholar
A. I. Dement′ev, M. L. Kuznetsov, Y. M. Kiselev, Zh. Neorg. Khim. 1997, 42, 1167–1172.
Web of Science® Google Scholar

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Volume54, Issue4

January 19, 2015

Pages 1080-1081

The Formal Oxidation States of Iridium Now Run from −III to +IX^†

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The Formal Oxidation States of Iridium Now Run from −III to +IX†

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The Formal Oxidation States of Iridium Now Run from −III to +IX^†