Efficient Coupling of Solar Energy to Catalytic Hydrogenation by Using Well-Designed Palladium Nanostructures†
Dr. Ran Long
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
These authors contributed equally to this work.
Search for more papers by this authorZhoulv Rao
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
These authors contributed equally to this work.
Search for more papers by this authorKeke Mao
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorYu Li
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorChao Zhang
Laboratory of Optical Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (P. R. China)
Search for more papers by this authorQiliang Liu
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorDr. Chengming Wang
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorProf. Zhi-Yuan Li
Laboratory of Optical Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (P. R. China)
College of Physics and Optoelectronics, South China University of Technology, Guangzhou 510641 (P. R. China)
Search for more papers by this authorProf. Xiaojun Wu
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorCorresponding Author
Prof. Yujie Xiong
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/Search for more papers by this authorDr. Ran Long
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
These authors contributed equally to this work.
Search for more papers by this authorZhoulv Rao
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
These authors contributed equally to this work.
Search for more papers by this authorKeke Mao
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorYu Li
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorChao Zhang
Laboratory of Optical Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (P. R. China)
Search for more papers by this authorQiliang Liu
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorDr. Chengming Wang
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorProf. Zhi-Yuan Li
Laboratory of Optical Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (P. R. China)
College of Physics and Optoelectronics, South China University of Technology, Guangzhou 510641 (P. R. China)
Search for more papers by this authorProf. Xiaojun Wu
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Search for more papers by this authorCorresponding Author
Prof. Yujie Xiong
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/
Hefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Materials Science and CAS Key Laboratory of Materials for Energy Conversion, University of Science and Technology of China, Hefei, Anhui 230026 (P. R. China) http://staff.ustc.edu.cn/∼yjxiong/Search for more papers by this authorThis work was financially supported by the NSFC (No. 21101145, 91123010), Recruitment Program of Global Experts, CAS Hundred Talent Program, Specialized Research Fund for the Doctoral Program of Higher Education (No. 20123402110050), and Fundamental Research Funds for the Central Universities (No. WK2060190025, WK2060190037).
Graphical Abstract
Taking shape: A Ru3+-mediated synthesis has been developed for unique Pd concave nanostructures which can directly harvest UV-to-visible light for styrene hydrogenation (see figure). The catalytic efficiency under full-spectrum irradiation at room temperature turns out to be comparable to that of the thermally (70 °C) driven reaction. The yields are higher than those obtained using Pd nanocrystals such as nanocubes and octahedrons.
Abstract
A Ru3+-mediated synthesis for the unique Pd concave nanostructures, which can directly harvest UV-to-visible light for styrene hydrogenation, is described. The catalytic efficiency under 100 mW cm−2 full-spectrum irradiation at room temperature turns out to be comparable to that of thermally (70 °C) driven reactions. The yields obtained with other Pd nanocrystals, such as nanocubes and octahedrons, are lower. The nanostructures reported here have sufficient plasmonic cross-sections for light harvesting in a broad spectral range owing to the reduced shape symmetry, which increases the solution temperature for the reaction by the photothermal effect. They possess a large quantity of atoms at corners and edges where local heat is more efficiently generated, thus providing active sites for the reaction. Taken together, these factors drastically enhance the hydrogenation reaction by light illumination.
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