Volume 53, Issue 48 pp. 13088-13092

Communication

Entrapment of Elusive Guests within Metal-Seamed Nanocapsules^†

Dr. Harshita Kumari,

Dr. Harshita Kumari

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

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Dr. Ping Jin,

Dr. Ping Jin

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

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Dr. Simon J. Teat,

Dr. Simon J. Teat

Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley CA, 94720 (USA)

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Dr. Charles L. Barnes,

Dr. Charles L. Barnes

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

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Dr. Scott J. Dalgarno,

Dr. Scott J. Dalgarno

Institute of Chemical Sciences, William Perkin Building, Heriot-Watt University, Riccarton, Edinburgh, EH14 4AS (Scotland)

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Prof. Jerry L. Atwood,

Corresponding Author

Prof. Jerry L. Atwood

[email protected]

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)Search for more papers by this author

Dr. Harshita Kumari,

Dr. Harshita Kumari

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

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Dr. Ping Jin,

Dr. Ping Jin

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

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Dr. Simon J. Teat,

Dr. Simon J. Teat

Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley CA, 94720 (USA)

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Dr. Charles L. Barnes,

Dr. Charles L. Barnes

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

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Dr. Scott J. Dalgarno,

Dr. Scott J. Dalgarno

Institute of Chemical Sciences, William Perkin Building, Heriot-Watt University, Riccarton, Edinburgh, EH14 4AS (Scotland)

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Prof. Jerry L. Atwood,

Corresponding Author

Prof. Jerry L. Atwood

[email protected]

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)

Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211 (USA)Search for more papers by this author

First published: 08 October 2014

https://doi.org/10.1002/anie.201406776

Citations: 26

^†

We thank the NSF (J.L.A.), NSF CHE-95-31247, and NIH 1S10RR11962-01 for financial support of this work. We also thank Dr. Wei G. Wycoff for NMR support and valuable discussions. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231.

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Graphical Abstract

Anions play a crucial role in locking alkali metals on the interior of metal–organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.

Abstract

Anions play a crucial role in locking alkali metals on the interior of metal–organic capsules that contain structural water gates. This role is further evidenced when stitching-up the capsule seam, resulting in either expulsion or trapping of cesium ions depending on the anion employed.

Supporting Information

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Volume53, Issue48

November 24, 2014

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Entrapment of Elusive Guests within Metal-Seamed Nanocapsules^†

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Entrapment of Elusive Guests within Metal-Seamed Nanocapsules^†