Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal–Organic Framework Thin Film†
Chunjing Lu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Teng Ben
Department of Chemistry, Jilin University, Changchun, 130012 (China)
Teng Ben, Department of Chemistry, Jilin University, Changchun, 130012 (China)
Shilun Qiu, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorShixian Xu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shilun Qiu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Teng Ben, Department of Chemistry, Jilin University, Changchun, 130012 (China)
Shilun Qiu, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorChunjing Lu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Teng Ben
Department of Chemistry, Jilin University, Changchun, 130012 (China)
Teng Ben, Department of Chemistry, Jilin University, Changchun, 130012 (China)
Shilun Qiu, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorShixian Xu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Shilun Qiu
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Teng Ben, Department of Chemistry, Jilin University, Changchun, 130012 (China)
Shilun Qiu, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China)
Search for more papers by this authorThis work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700, 2011CB808703), NSFC (21261130584, 91022030), “111” project (B07016), Award Project of KAUST (CRG-1-2012-LAI-009), and the Ministry of Education, Science and Technology Development Center Project (20120061130012).
Graphical Abstract
A 3D microporous conductive polymer has been achieved in the electrochemical synthesis of a porous polyaniline network with a MOF thin film. The prepared microporous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2.
Abstract
A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m2 g−1 and a high electric conductivity of 0.125 S cm−1 when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
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