A Crystal-to-Crystal Synthesis of Triazolyl-Linked Polysaccharide†
Atchutarao Pathigoolla
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, CET-Campus, Thiruvananthapuram-695016 (India) http://iisertvm.ac.in/scientists/kana-m-sureshan/personal-information.html
Search for more papers by this authorCorresponding Author
Prof. Dr. Kana M. Sureshan
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, CET-Campus, Thiruvananthapuram-695016 (India) http://iisertvm.ac.in/scientists/kana-m-sureshan/personal-information.html
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, CET-Campus, Thiruvananthapuram-695016 (India) http://iisertvm.ac.in/scientists/kana-m-sureshan/personal-information.htmlSearch for more papers by this authorAtchutarao Pathigoolla
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, CET-Campus, Thiruvananthapuram-695016 (India) http://iisertvm.ac.in/scientists/kana-m-sureshan/personal-information.html
Search for more papers by this authorCorresponding Author
Prof. Dr. Kana M. Sureshan
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, CET-Campus, Thiruvananthapuram-695016 (India) http://iisertvm.ac.in/scientists/kana-m-sureshan/personal-information.html
School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, CET-Campus, Thiruvananthapuram-695016 (India) http://iisertvm.ac.in/scientists/kana-m-sureshan/personal-information.htmlSearch for more papers by this authorA.P. thanks CSIR-India for Senior Research Fellowship assistance. K.M.S. thanks the Department of Science and Technology (DST, India) for a Ramanujan Fellowship. This work was made possible by financial support from DST and CSIR.
Graphical Abstract
Crystal sweets: Polysaccharide synthesis is hampered by many factors. These problems can be circumvented by the crystal-to-crystal azide–alkyne cycloaddition polymerization of an unprotected monosaccharide, which gives a crystalline glycopolymer regiospecifically in quantitative yield.
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