A Thermoresponsive Hydrogel Formed from a Star–Star Supramolecular Architecture†
Dr. Zhong-Xing Zhang
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)
Search for more papers by this authorDr. Kerh Li Liu
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jun Li
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)
Department of Bioengineering, Faculty of Engineering, National University of Singapore, 7 Engineering Drive 1, Singapore 117574 (Singapore)
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)Search for more papers by this authorDr. Zhong-Xing Zhang
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)
Search for more papers by this authorDr. Kerh Li Liu
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)
Search for more papers by this authorCorresponding Author
Prof. Dr. Jun Li
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)
Department of Bioengineering, Faculty of Engineering, National University of Singapore, 7 Engineering Drive 1, Singapore 117574 (Singapore)
Institute of Materials Research and Engineering, A*STAR (Agency for Science, Technology and Research), 3 Research Link, Singapore 117602 (Singapore)Search for more papers by this authorWe acknowledge financial support from A*STAR (SERC PSF Grant 1021010024 and JCO Grant 10/03/FG/06/05) and the National University of Singapore (FSF Grant R-397-000-136-112 and R-397-000-136-731).
Graphical Abstract
Smart stars: A novel star–star supramolecular architecture was self-assembled from a star-shaped adamantyl-terminated 8-arm poly(ethylene glycol) and a star-shaped poly(N-isopropylacrylamide) with a β-cyclodextrin core through inclusion complexation. The star–star supramolecules further self-aggregated into a 3D network in response to temperature change, forming a thermoresponsive reversible “smart” hydrogel.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| anie_201301956_sm_miscellaneous_information.pdf404.4 KB | miscellaneous_information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1D. Astruc, E. Boisselier, C. Ornelas, Chem. Rev. 2010, 110, 1857–1959.
- 2A. D. Schlüter, J. P. Rabe, Angew. Chem. 2000, 112, 860–880;
10.1002/(SICI)1521-3757(20000303)112:5<860::AID-ANGE860>3.0.CO;2-H Google ScholarAngew. Chem. Int. Ed. 2000, 39, 864–883.10.1002/(SICI)1521-3773(20000303)39:5<864::AID-ANIE864>3.0.CO;2-E CAS PubMed Web of Science® Google Scholar
- 3M. Fischer, F. Vogtle, Angew. Chem. 1999, 111, 934–955;
Angew. Chem. Int. Ed. 1999, 38, 884–905.
10.1002/(SICI)1521-3773(19990401)38:7<884::AID-ANIE884>3.0.CO;2-K CAS PubMed Web of Science® Google Scholar
- 4A. W. Bosman, H. M. Janssen, E. W. Meijer, Chem. Rev. 1999, 99, 1665–1688.
- 5J. Szejtli, Chem. Rev. 1998, 98, 1743–1753.
- 6A. Harada, J. Li, M. Kamachi, Nature 1992, 356, 325–327.
- 7J. Li, A. Harada, M. Kamachi, Polym. J. 1994, 26, 1019–1026.
- 8G. Wenz, Angew. Chem. 1994, 106, 851–870; Angew. Chem. Int. Ed. Engl. 1994, 33, 803–822.
- 9J. Li, X. Li, Z. H. Zhou, X. P. Ni, K. W. Leong, Macromolecules 2001, 34, 7236–7237.
- 10K. L. Liu, S. H. Goh, J. Li, Macromolecules 2008, 41, 6027–6034.
- 11Y.-L. Wu, J. Li, Angew. Chem. 2009, 121, 3900–3903; Angew. Chem. Int. Ed. 2009, 48, 3842–3845.
- 12S. A. Nepogodiev, J. F. Stoddart, Chem. Rev. 1998, 98, 1959–1976.
- 13K. Uekama, F. Hirayama, T. Irie, Chem. Rev. 1998, 98, 2045–2076.
- 14N. Yui, T. Ooya, Chem. Eur. J. 2006, 12, 6730–6737.
- 15J. Li, X. Li, X. P. Ni, X. Wang, H. Z. Li, K. W. Leong, Biomaterials 2006, 27, 4132–4140.
- 16J. Li, C. Yang, H. Li, X. Wang, S. H. Goh, J. L. Ding, D. Y. Wang, K. W. Leong, Adv. Mater. 2006, 18, 2969–2974.
- 17J. Li, X. J. Loh, Adv. Drug Delivery Rev. 2008, 60, 1000–1017.
- 18K. L. Liu, J.-l. Zhu, J. Li, Soft Matter 2010, 6, 2300–2311.
- 19Y. Ping, C. Liu, Z. Zhang, K. L. Liu, J. Chen, J. Li, Biomaterials 2011, 32, 8328–8341.
- 20Z.-X. Zhang, X. Liu, F. J. Xu, X. J. Loh, E.-T. Kang, K.-G. Neoh, J. Li, Macromolecules 2008, 41, 5967–5970.
- 21Z.-X. Zhang, K. L. Liu, J. Li, Macromolecules 2011, 44, 1182–1193.
- 22H. G. Schild, Prog. Polym. Sci. 1992, 17, 163–249.
- 23A. Sandier, W. Brown, H. Mays, C. Amiel, Langmuir 2000, 16, 1634–1642.
- 24R. Auzély-Velty, M. Rinaudo, Macromolecules 2002, 35, 7955–7962.
- 25O. Kretschmann, S. W. Choi, M. Miyauchi, I. Tomatsu, A. Harada, H. Ritter, Angew. Chem. 2006, 118, 4468–4472;
10.1002/ange.200504539 Google ScholarAngew. Chem. Int. Ed. 2006, 45, 4361–4365.
- 26A. Charlot, R. Auzely-Velty, M. Rinaudo, J. Phys. Chem. B 2003, 107, 8248–8254.
- 27A. Charlot, R. Auzely-Velty, Macromolecules 2007, 40, 1147–1158.
- 28C. Koopmans, H. Ritter, Macromolecules 2008, 41, 7418–7422.
- 29A. S. Hoffman, Adv. Drug Delivery Rev. 2002, 54, 3–12.
- 30B. Jeong, S. W. Kim, Y. H. Bae, Adv. Drug Delivery Rev. 2002, 54, 37–51.
- 31T. Kissel, Y. X. Li, F. Unger, Adv. Drug Delivery Rev. 2002, 54, 99–134.
- 32L. Yu, J. Ding, Chem. Soc. Rev. 2008, 37, 1473–1481.
- 33J. Li, Adv. Polym. Sci. 2009, 222, 79–113.
- 34Y. F. Liu, D. M. Peng, K. L. Huang, S. Q. Liu, Z. B. Liu, J. Appl. Polym. Sci. 2011, 122, 3248–3254.
- 35N. M. Sangeetha, U. Maitra, Chem. Soc. Rev. 2005, 34, 821–836.
- 36N. A. Peppas, J. Z. Hilt, A. Khademhosseini, R. Langer, Adv. Mater. 2006, 18, 1345–1360.
- 37S. Chaterji, I. K. Kwon, K. Park, Prog. Polym. Sci. 2007, 32, 1083–1122.
- 38E. A. Appel, F. Biedermann, U. Rauwald, S. T. Jones, J. M. Zayed, O. A. Scherman, J. Am. Chem. Soc. 2010, 132, 14251–14260.
- 39M. Nakahata, Y. Takashima, H. Yamaguchi, A. Harada, Nat. Commun. 2011, 2, 511.
- 40J. Cui, A. del Campo, Chem. Commun. 2012, 48, 9302–9304.
- 41M. Zhang, D. Xu, X. Yan, J. Chen, S. Dong, B. Zheng, F. Huang, Angew. Chem. 2012, 124, 7117–7121; Angew. Chem. Int. Ed. 2012, 51, 7011–7015.
- 42F. van de Manakker, T. Vermonden, N. el Morabit, C. F. van Nostrum, W. E. Hennink, Langmuir 2008, 24, 12559–12567.
- 43F. van de Manakker, M. van der Pot, T. Vermonden, C. F. van Nostrum, W. E. Hennink, Macromolecules 2008, 41, 1766–1773.
- 44P. Du, J. Liu, G. Chen, M. Jiang, Langmuir 2011, 27, 9602–9608.
- 45L. Tan, Y. Liu, W. Ha, L.-S. Ding, S.-L. Peng, S. Zhang, B.-J. Li, Soft Matter 2012, 8, 5746–5749.
- 46B. Chen, K. L. Liu, Z. Zhang, X. Ni, S. H. Goh, J. Li, Chem. Commun. 2012, 48, 5638–5640.
- 47S. Y. Dong, Y. Luo, X. Z. Yan, B. Zheng, X. Ding, Y. H. Yu, Z. Ma, Q. L. Zhao, F. H. Huang, Angew. Chem. 2011, 123, 1945–1949; Angew. Chem. Int. Ed. 2011, 50, 1905–1909.
- 48X. Z. Yan, D. H. Xu, X. D. Chi, J. Z. Chen, S. Y. Dong, X. Ding, Y. H. Yu, F. H. Huang, Adv. Mater. 2012, 24, 362–369.
- 49S. Y. Dong, B. Zheng, D. H. Xu, X. Z. Yan, M. M. Zhang, F. H. Huang, Adv. Mater. 2012, 24, 3191–3195.
- 50X. Z. Yan, F. Wang, B. Zheng, F. H. Huang, Chem. Soc. Rev. 2012, 41, 6042–6065.
