Catalytic Regioselective Oxidation of Glycosides†
Manuel Jäger
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
Search for more papers by this authorMarcel Hartmann
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
Search for more papers by this authorCorresponding Author
Prof. Dr. Johannes G. de Vries
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
DSM Innovative Synthesis, BV P.O. box 18, 6160 MD Geleen (The Netherlands)
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/Search for more papers by this authorCorresponding Author
Prof. Dr. Adriaan J. Minnaard
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/Search for more papers by this authorManuel Jäger
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
Search for more papers by this authorMarcel Hartmann
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
Search for more papers by this authorCorresponding Author
Prof. Dr. Johannes G. de Vries
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
DSM Innovative Synthesis, BV P.O. box 18, 6160 MD Geleen (The Netherlands)
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/Search for more papers by this authorCorresponding Author
Prof. Dr. Adriaan J. Minnaard
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/
Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen (The Netherlands) http://www.rug.nl/research/bio-organic-chemistry/minnaard/Search for more papers by this authorThis research has been performed within the framework of the CatchBio program. The authors gratefully acknowledge the support of the Smart Mix Program of the Netherlands Ministry of Economic Affairs, Agriculture and Innovation and the Netherlands Ministry of Education, Culture and Science.
Graphical Abstract
Discrimination among equals: A catalytic method for the selective oxidation of unprotected glycosides, both monosaccharides and disaccharides, has been developed. The resulting ketosaccharides are isolated in moderate to excellent yields. This approach provides a basis for protecting-group-free synthetic transformations of carbohydrates.
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