Hole–Shell Microparticles from Controllably Evolved Double Emulsions†
Dr. Wei Wang
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorMao-Jie Zhang
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorDr. Rui Xie
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorDr. Xiao-Jie Ju
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorChao Yang
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorChuan-Lin Mou
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorProf. David A. Weitz
School of Engineering and Applied Sciences, Department of Physics, Harvard University, Cambridge, MA 02138 (USA)
Search for more papers by this authorCorresponding Author
Prof. Liang-Yin Chu
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
State Key Laboratory of Polymer Materials Engineering, and Collaborative Innovation Center for Biomaterials Science and Technology, Sichuan University, Chengdu, Sichuan, 610065 (China)
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/Search for more papers by this authorDr. Wei Wang
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorMao-Jie Zhang
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorDr. Rui Xie
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorDr. Xiao-Jie Ju
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorChao Yang
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorChuan-Lin Mou
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
Search for more papers by this authorProf. David A. Weitz
School of Engineering and Applied Sciences, Department of Physics, Harvard University, Cambridge, MA 02138 (USA)
Search for more papers by this authorCorresponding Author
Prof. Liang-Yin Chu
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/
State Key Laboratory of Polymer Materials Engineering, and Collaborative Innovation Center for Biomaterials Science and Technology, Sichuan University, Chengdu, Sichuan, 610065 (China)
School of Chemical Engineering, Sichuan University, Chengdu, Sichuan, 610065 (China) http://teacher.scu.edu.cn/ftp_teacher0/cly/Search for more papers by this authorThe authors gratefully acknowledge support from the National Natural Science Foundation of China (21136006, 21076127), and the Program for Changjiang Scholars and Innovative Research Team in University of China (IRT1163).
Graphical Abstract
Hole in one! Hole–shell microparticles (blue, see picture) with controllable structures and flexible internal surfaces have been fabricated from W/O/W emulsions. These microparticles could be used as microcontainers for the controlled capture/release of molecules, microsphere classification/separation, confined cell culture, or as microreactors for catalysis.
Supporting Information
As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors.
| Filename | Description |
|---|---|
| anie_201301590_sm_miscellaneous_information.pdf9.6 MB | miscellaneous_information |
| anie_201301590_sm_movie-s1.avi3.1 MB | movie-s1 |
| anie_201301590_sm_movie-s2.avi722.4 KB | movie-s2 |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1S. H. Im, U. Y. Jeong, Y. N. Xia, Nat. Mater. 2005, 4, 671–675.
- 2E. Amstad, S. H. Kim, D. A. Weitz, Angew. Chem. 2012, 124, 12667–12671;
10.1002/ange.201206531 Google ScholarAngew. Chem. Int. Ed. 2012, 51, 12499–12503.
- 3Y. F. Zhu, J. L. Shi, W. H. Shen, X. P. Dong, J. W. Feng, M. L. Ruan, Y. S. Li, Angew. Chem. 2005, 117, 5213–5217; Angew. Chem. Int. Ed. 2005, 44, 5083–5087.
- 4R. De Rose, A. N. Zelikin, A. P. R. Johnston, A. Sexton, S. F. Chong, C. Cortez, W. Mulholland, F. Caruso, S. J. Kent, Adv. Mater. 2008, 20, 4698–4703.
- 5S. Ota, S. Yoshizawa, S. Takeuchi, Angew. Chem. 2009, 121, 6655–6659;
10.1002/ange.200902182 Google ScholarAngew. Chem. Int. Ed. 2009, 48, 6533–6537.
- 6S. Ma, J. Thiele, X. Liu, Y. Bai, C. Abell, W. T. S. Huck, Small 2012, 8, 2356–2360.
- 7A. D. Dinsmore, M. F. Hsu, M. G. Nikolaides, M. Marquez, A. R. Bausch, D. A. Weitz, Science 2002, 298, 1006–1009.
- 8L. Y. Chu, T. Yamaguchi, S. Nakao, Adv. Mater. 2002, 14, 386–389.
- 9G. Guan, Z. Zhang, Z. Wang, B. Liu, D. Gao, C. Xie, Adv. Mater. 2007, 19, 2370–2374.
- 10S. Sacanna, W. T. M. Irvine, P. M. Chaikin, D. J. Pine, Nature 2010, 464, 575–578.
- 11W. Yin, M. Z. Yates, Langmuir 2008, 24, 701–708.
- 12H. Minami, H. Kobayashi, M. Okubo, Langmuir 2005, 21, 5655–5658.
- 13J. Han, G. Song, R. Guo, Adv. Mater. 2006, 18, 3140–3144.
- 14M. Li, J. Xue, Langmuir 2011, 27, 3229–3232.
- 15Y. T. Lim, J. K. Kim, Y. W. Noh, M. Y. Cho, B. H. Chung, Small 2009, 5, 324–328.
- 16H. N. Yow, A. F. Routh, Soft Matter 2008, 4, 2080–2085.
- 17G. H. Ma, Z. G. Su, S. Omi, D. Sundberg, J. Stubbs, J. Colloid Interface Sci. 2003, 266, 282–294.
- 18M. Q. Zhu, G. C. Chen, Y. M. Li, J. B. Fan, M. F. Zhu, Z. Tang, Nanoscale 2011, 3, 4608–4612.
- 19M. W. Chang, E. Stride, M. Edirisinghe, Langmuir 2010, 26, 5115–5121.
- 20W. Wang, R. Xie, X. J. Ju, T. Luo, L. Liu, D. A. Weitz, L. Y. Chu, Lab Chip 2011, 11, 1587–1592.
- 21L. Y. Chu, A. S. Utada, R. K. Shah, J. W. Kim, D. A. Weitz, Angew. Chem. 2007, 119, 9128–9132; Angew. Chem. Int. Ed. 2007, 46, 8970–8974.
- 22A. S. Utada, E. Lorenceau, D. R. Link, P. D. Kaplan, H. A. Stone, D. A. Weitz, Science 2005, 308, 537–541.
- 23W. Lan, S. Li, J. Xu, G. Luo, Microfluid. Nanofluid. 2012, 13, 491–498.
- 24S. H. Kim, A. Abbaspourrad, D. A. Weitz, J. Am. Chem. Soc. 2011, 133, 5516–5524.
- 25T. Nisisako, T. Torii, Adv. Mater. 2007, 19, 1489–1493.
- 26Z. H. Nie, S. Q. Xu, M. Seo, P. C. Lewis, E. Kumacheva, J. Am. Chem. Soc. 2005, 127, 8058–8063.
- 27J. Wang, Y. Hu, R. Deng, W. Xu, S. Liu, R. Liang, Z. Nie, J. Zhu, Lab Chip 2012, 12, 2795–2798.
- 28P. Poulin, J. Bibette, Langmuir 1998, 14, 6341–6343.
- 29M. P. Aronson, H. M. Princen, Nature 1980, 286, 370–372.
- 30S. H. Kim, S. J. Jeon, S. M. Yang, J. Am. Chem. Soc. 2008, 130, 6040–6046.
- 31N. Bremond, J. Bibette, Soft Matter 2012, 8, 10549–10559.
- 32T. Sun, G. Qing, Adv. Mater. 2011, 23, H 57–H77.
- 33M. C. Daniel, D. Astruc, Chem. Rev. 2004, 104, 293–346.
