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Migratory Insertion of Alkenes into Metal–Oxygen and Metal–Nitrogen Bonds
Dr. Patrick S. Hanley,
Prof. John F. Hartwig,
Dr. Patrick S. Hanley
Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801 (USA)
Search for more papers by this authorCorresponding Author
Prof. John F. Hartwig
Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801 (USA)
University of California, Department of Chemistry, 718 Latimer Hall, Berkeley, CA 94720 (USA)
Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801 (USA)Search for more papers by this authorDr. Patrick S. Hanley,
Prof. John F. Hartwig,
Dr. Patrick S. Hanley
Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801 (USA)
Search for more papers by this authorCorresponding Author
Prof. John F. Hartwig
Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801 (USA)
University of California, Department of Chemistry, 718 Latimer Hall, Berkeley, CA 94720 (USA)
Department of Chemistry, University of Illinois Urbana-Champaign, Urbana, IL 61801 (USA)Search for more papers by this authorGraphical Abstract
In the middle of things: Recent work has shown that the insertions of unactivated alkenes into the metal–oxygen and metal–nitrogen bonds of metal alkoxo and metal amido complexes can occur as rapidly or more rapidly than insertions into metal–alkyl bonds. Studies on catalytic and stoichiometric reactions occurring through this increasingly common class of organometallic reactions are reviewed.
Abstract
The insertion of an unsaturated ligand into a MC or MH bond proceeds through migratory insertion, a fundamental organometallic reaction. Recent literature documents evidence of the migratory insertion of alkenes into an MO and MN bonds for alkene alkoxylation and alkene amination reactions, respectively. Herein we provide an overview of the literature and a perspective on how these recent experiments relate to classic experiments on CO and CN bond formation with alkene complexes of the late transition metals.
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