Three-Dimensional Ordered Arrays of 58×58×58 Å3 Hollow Frameworks in Ionic Crystals of M2Zn2-Substituted Polyoxometalates†
Dr. Kosuke Suzuki
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Yuji Kikukawa
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Sayaka Uchida
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Hiroko Tokoro
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorKenta Imoto
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorProf. Dr. Shin-ichi Ohkoshi
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Noritaka Mizuno
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)Search for more papers by this authorDr. Kosuke Suzuki
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Yuji Kikukawa
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Sayaka Uchida
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Search for more papers by this authorDr. Hiroko Tokoro
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorKenta Imoto
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorProf. Dr. Shin-ichi Ohkoshi
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033 (Japan)
Search for more papers by this authorCorresponding Author
Prof. Dr. Noritaka Mizuno
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)Search for more papers by this authorThis work was supported by the Global COE Program (Chemistry Innovation through Cooperation of Science and Engineering), Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports, and Technology of Japan (MEXT), Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program). M=Co, Ni, Zn.
Graphical Abstract
A void in the issue: A one-step self-assembly of γ-Keggin sandwich-type silicotungstates with M2Zn2 (M=Co, Ni, Zn) tetranuclear cores and tetrabutylammonium cations gave porous ionic crystals. These porous crystals are hollow frameworks containing large voids (ca. 38×38×38 Å3, see picture, voids yellow), between which guest molecules can be exchanged through the connecting channels.
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