Switchable Open-Cage Fullerene for Water Encapsulation†
Qianyan Zhang
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorDr. Tobias Pankewitz
Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Search for more papers by this authorShuming Liu
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Wim Klopper
Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Center for Functional Nanostructures (CFN), Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Wim Klopper, Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Liangbing Gan, Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Liangbing Gan
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
Wim Klopper, Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Liangbing Gan, Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorQianyan Zhang
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorDr. Tobias Pankewitz
Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Search for more papers by this authorShuming Liu
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Wim Klopper
Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Center for Functional Nanostructures (CFN), Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Wim Klopper, Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Liangbing Gan, Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorCorresponding Author
Prof. Dr. Liangbing Gan
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
Wim Klopper, Abteilung für Theoretische Chemie, Institut für Physikalische Chemie, Karlsruher Institut für Technologie, Postfach 6980, 76049 Karlsruhe (Germany)
Liangbing Gan, Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory for Organic Solids, Institute of Chemistry, Chinese Academy of Science, Beijing 100080 (China)
Search for more papers by this authorFinancial support was provided by the NNSFC, MOST, and Deutsche Forschungsgemeinschaft (CFN subproject C3.3).
Graphical Abstract
A molecular container for a single water molecule was obtained by chemical transformation of a [60]fullerene cage. A phosphate moiety acts as an effective “stopper” in the orifice (see picture).
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
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| anie_201004879_sm_miscellaneous_information.pdf2.8 MB | miscellaneous_information |
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