Gold–Silane and Gold–Stannane Complexes: Saturated Molecules as σ-Acceptor Ligands†
Pauline Gualco
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorTzu-Pin Lin
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA)
Search for more papers by this authorMarie Sircoglou Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorMaxime Mercy
Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, 31077 Toulouse (France)
CNRS, LPCNO UMR 5215, 31077 Toulouse (France)
Search for more papers by this authorSonia Ladeira
Structure Fédérative Toulousaine en Chimie Moléculaire, Toulouse (France)
Search for more papers by this authorGhenwa Bouhadir Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorLisa M. Pérez Dr.
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA)
Search for more papers by this authorAbderrahmane Amgoune Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorLaurent Maron Dr.
Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, 31077 Toulouse (France)
CNRS, LPCNO UMR 5215, 31077 Toulouse (France)
Search for more papers by this authorFrançois P. Gabbaï Dr.
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA)
Search for more papers by this authorDidier Bourissou Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorPauline Gualco
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorTzu-Pin Lin
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA)
Search for more papers by this authorMarie Sircoglou Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorMaxime Mercy
Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, 31077 Toulouse (France)
CNRS, LPCNO UMR 5215, 31077 Toulouse (France)
Search for more papers by this authorSonia Ladeira
Structure Fédérative Toulousaine en Chimie Moléculaire, Toulouse (France)
Search for more papers by this authorGhenwa Bouhadir Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorLisa M. Pérez Dr.
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA)
Search for more papers by this authorAbderrahmane Amgoune Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorLaurent Maron Dr.
Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, 31077 Toulouse (France)
CNRS, LPCNO UMR 5215, 31077 Toulouse (France)
Search for more papers by this authorFrançois P. Gabbaï Dr.
Department of Chemistry, Texas A&M University, College Station, TX 77843 (USA)
Search for more papers by this authorDidier Bourissou Dr.
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse (France)
CNRS, LHFA UMR 5069, 31062 Toulouse (France), Fax: (+33) 5-6155-8204
Search for more papers by this authorFinancial support from the Centre National de la Recherche Scientifique, the Université de Toulouse, the Agence Nationale de la Recherche (ANR-06-BLAN-0034), the National Science Foundation (CHE-0646916), and the Welch Foundation (A-1423) is gratefully acknowledged. We thank: the Unidade de RaiosX of the Universidade de Santiago de Compostela for the X-ray diffraction analyses of 4 and 5; Christopher Cummins (MIT) for useful discussions regarding the use of the Dgrid program; the Laboratory for Molecular Simulation at Texas A&M University for providing software and computation resources. L.M. thanks the Institut Universitaire de France and D.B. thanks the COST action CM0802 PhoSciNet for supporting this work.
Graphical Abstract
Gold gets a grip: Spectroscopic, structural, and computational results provide evidence for unprecedented Au→Si and Au→Sn interactions in gold(I) complexes derived from diphosphino-substituted silane and stannane ligands (see scheme).
Supporting Information
Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.
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