A Stair-Shaped Molecular Silver(0) Chain†
Hoi Ri Moon
Department of Chemistry, Seoul National University, Seoul 151-747 (Korea), Fax: (+82) 2-886-8516
Search for more papers by this authorCheol Ho Choi Prof.
Department of Chemistry, Kyungpook National University, Taegu 702-701 (Korea)
Search for more papers by this authorMyunghyun Paik Suh Prof.
Department of Chemistry, Seoul National University, Seoul 151-747 (Korea), Fax: (+82) 2-886-8516
Search for more papers by this authorHoi Ri Moon
Department of Chemistry, Seoul National University, Seoul 151-747 (Korea), Fax: (+82) 2-886-8516
Search for more papers by this authorCheol Ho Choi Prof.
Department of Chemistry, Kyungpook National University, Taegu 702-701 (Korea)
Search for more papers by this authorMyunghyun Paik Suh Prof.
Department of Chemistry, Seoul National University, Seoul 151-747 (Korea), Fax: (+82) 2-886-8516
Search for more papers by this authorThis work was supported by a Korea Research Foundation Grant funded by the Korean Government (MOEHRD Basic Research Promotion Fund, KRF-2005-084-C00020), and by a Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MEST, No. R11-2005-008-00000-0).
Graphical Abstract
Bound in chains: The molecular Ag0 chain [Ag4py2]n (py=C5H5N) is formed from two covalently linked infinite zigzag chains of Ag, in which AgAg bonds alternate between long and short (see picture; blue Ag, gray C, orange N). Theoretical calculations indicate that partially positively (+0.35) and negatively (−0.30) charged Ag atoms are alternately located along the chain, which has a bandgap of 4.1 eV.
Supporting Information
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References
- 1
- 1aM. R. Bermejo, A. M. González-Noya, R. M. Pedrido, M. J. Romero, M. Vázquez, Angew. Chem. 2005, 117, 4254–4259;
10.1002/ange.200500840 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 4182–4187;
- 1bM. Shatruk, A. Dragulescu-Andrasi, K. E. Chambers, S. A. Stoian, E. L. Bominaar, C. Achim, K. R. Dunbar, J. Am. Chem. Soc. 2007, 129, 6104–6116.
- 2
- 2aQ.-M. Wang, T. C. W. Mak, Chem. Eur. J. 2003, 9, 44–50;
- 2bQ.-M. Wang, H. K. Lee, T. C. W. Mak, New J. Chem. 2002, 26, 513–515.
- 3
- 3aT. Yamaguchi, F. Yamazaki, T. Ito, J. Am. Chem. Soc. 2001, 123, 743–744;
- 3bJ. F. Berry, F. A. Cotton, L. M. Daniels, C. A. Murillo, J. Am. Chem. Soc. 2002, 124, 3212–3213;
- 3cJ. F. Berry in Multiple Bonds Between Metal Atoms (Eds.: ), Springer Science and Business Media Inc., New York, 2005, pp. 669–706.
10.1007/0-387-25829-9_15 Google Scholar
- 4
- 4aI-W. P. Chen, M.-D. Fu, W.-H. Tseng, J.-Y. Yu, S.-H. Wu, C.-J. Ku, C.-h. Chen, S.-M. Peng, Angew. Chem. 2006, 118, 5946–5950; Angew. Chem. Int. Ed. 2006, 45, 5814–5818;
- 4bS.-Y. Lin, I.-W. P. Chen, C.-h. Chen, M.-H. Hsieh, C.-Y. Yeh, T.-W. Lin, Y.-H. Chen, S.-M. Peng, J. Phys. Chem. B 2004, 108, 959–964.
- 5P. L. Stiles, R. E. Miller, J. Phys. Chem. A 2007, 111, 7382–7390.
- 6
- 6aZ.-M. Tian, Y. Tian, W.-M. Wei, T.-J. He, D.-M. Chen, F.-C. Liu, Chem. Phys. Lett. 2006, 420, 550–555;
- 6bM. Pereiro, D. Baldomir, Phys. Rev. A 2007, 75, 033202;
- 6cG. F. Zhao, Y. Lei, Z. Zeng, Chem. Phys. 2006, 327, 261–268.
- 7F. Bachechi, A. Burini, M. Fontani, R. Galassi, A. Macchioni, B. R. Pietroni, P. Zanello, C. Zuccaccia, Inorg. Chim. Acta 2001, 323, 45–54.
- 8
- 8aH. Yamada, J. Michalik, H. Sadlo, J. Perlinska, S. Takenouchi, S. Shimomura, Y. Uchida, Appl. Clay Sci. 2001, 19, 173–178;
- 8bJ. Michalik, L. Kevan, J. Am. Chem. Soc. 1986, 108, 4247–4253.
- 9
- 9aM. P. Suh, H. R. Moon, E. Y. Lee, S. Y. Jang, J. Am. Chem. Soc. 2006, 128, 4710–4718;
- 9bH. R. Moon, J. H. Kim, M. P. Suh, Angew. Chem. 2005, 117, 1287–1291;
10.1002/ange.200461408 Google ScholarAngew. Chem. Int. Ed. 2005, 44, 1261–1265;
- 9cY. E. Cheon, M. P. Suh, Chem. Eur. J. 2008, 14, 3961–3967.
- 10
- 10aM. P. Suh, Y. E. Cheon, E. Y. Lee, Chem. Eur. J. 2007, 13, 4208–4215;
- 10bE. Y. Lee, S. Y. Jang, M. P. Suh, J. Am. Chem. Soc. 2005, 127, 6374–6381;
- 10cE. Y. Lee, M. P. Suh, Angew. Chem. 2004, 116, 2858–2861; Angew. Chem. Int. Ed. 2004, 43, 2798–2801;
- 10dH. J. Choi, M. P. Suh, J. Am. Chem. Soc. 2004, 126, 15844–15851;
- 10eM. P. Suh, J. W. Ko, H. J. Choi, J. Am. Chem. Soc. 2002, 124, 10976–10977;
- 10fK. S. Min, M. P. Suh, J. Am. Chem. Soc. 2000, 122, 6834–6840.
- 11
- 11aZ. Shervani, Y. Ikushima, M. Sato, H. Kawanami, Y. Hakuta, T. Yokoyama, T. Nagase, H. Kuneida, K. Aramaki, Colloid Polym. Sci. 2008, 286, 403–410;
- 11bC. Y. Kim, S. H. Jeong, S.-C. Yi, J. Ceram. Process. Res. 2007, 8, 445–449;
- 11cB. He, J. J. Tan, K. Y. Liew, H. Liu, J. Mol. Catal. A 2004, 221, 121–126;
- 11dL.-J. Chen, C.-C. Wan, Y.-Y. Wang, J. Colloid Interface Sci. 2006, 297, 143–150.
- 12L. M. Engelhardt, S. Gotsis, P. C. Healy, J. D. Kildea, B. W. Skelton, A. H. White, Aust. J. Chem. 1989, 42, 149–176.
- 13We prepared [Ag2I2py2]n according to the method described in Ref. [12] and obtained an X-ray single crystal structure and EDS data. The X-ray crystallographic data are provided in the Supporting Information.
- 14T. R. Cundari, W. J. Stevens, J. Chem. Phys. 1993, 98, 5555–5565.
- 15M. W. Schmidt, K. K. Baldridge, J. A. Boatz, S. T. Elbert, M. S. Gordon, J. H. Jensen, S. Koseki, N. Matsunaga, K. A. Nguyen, S. Su, T. L. Windus, M. Dupuis, J. A. Montgomery, Jr., J. Comput. Chem. 1993, 14, 1347–1363.
- 16M. Kertesz, C. H. Choi, S. Yang, Chem. Rev. 2005, 105, 3448–3481.
