Template-Directed Assembly of Zeolite-like Metal–Organic Frameworks (ZMOFs): A usf-ZMOF with an Unprecedented Zeolite Topology†
Yunling Liu Dr.
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P.R. China)
Search for more papers by this authorVictor Ch. Kravtsov Dr.
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
Institute of Applied Physics of Academy of Sciences of Moldova, Academiei 5, MD2028 Chisinau (Moldova)
Search for more papers by this authorMohamed Eddaoudi Prof. Dr.
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
Search for more papers by this authorYunling Liu Dr.
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (P.R. China)
Search for more papers by this authorVictor Ch. Kravtsov Dr.
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
Institute of Applied Physics of Academy of Sciences of Moldova, Academiei 5, MD2028 Chisinau (Moldova)
Search for more papers by this authorMohamed Eddaoudi Prof. Dr.
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA), Fax: (+1) 813-974-3203
Search for more papers by this authorWe gratefully acknowledge the financial support of the National Science Foundation (DMR 0548117) and the Department of Energy DOE-BES (DE0FG02-07ER4670).
Graphical Abstract
Better off med: The assembly of eight-coordinate indium molecular building blocks (MBBs) and 4,5-imidazoledicarboxylate (Himdc) ligands in the presence of a structure-directing agent results in the formation a novel 4-connected zeolite-like metal–organic framework (ZMOF) with an unprecedented zeolite topology (med topology, see picture; In green, C gray, N blue, O red; the framework topology of usf-ZMOF is shown in green tetrahedra).
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- 9Crystallographic data of usf-ZMOF: C50H20In5N20O40, Mr=2114.96, tetragonal, I41/amd, a=29.572(2) Å, c=51.739(8) Å, V=45 245(8) Å3, Z=16, ρcalcd=1.242 g cm−3, 2θmax=48.1° (0≤h≤3, 0≤k≤33, 0≤l≤59), T=100 K, 18 354 measured reflections, R1=0.1049, wR2=0.2651 for 5282 reflections (I>2σ(I)), and R1=0.1729, wR2=0.3051 for 9320 independent reflections (all data) and 702 parameters, GOF=1.004. Data were collected on a Bruker SMART-APEX CCD diffractometer using MoKα radiation (λ=0.71073 Å), operating in the ω and ϕ scan mode and corrected for Lorentz and polarization effects. The SADABS program was used for absorption correction. The structure was solved by direct methods and the structure solution and refinement were based on |F2|. All non-hydrogen atoms were refined with anisotropic displacement parameters. All crystallographic calculations were conducted with the SHELXTL software suite. CCDC 690432 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
- 10The med topology refers to Mohamed Eddaoudi (med), and its addition to the RCSR database is attributed to usf-ZMOF, of which we informed Prof. Michael O'Keeffe upon its discovery; M. O'Keeffe, Reticular Chemistry Structure Resource, http://rcsr.anu.edu.au/.
- 11Vertex symbols for usf-ZMOF: In1 (4, 4, 4, 6, 8, 8), In2 (4, 4, 4, 6, 8, 8), In3 (4, 4, 6, 6, 8, 8); coordination sequences for usf-ZMOF: In1 (CS1 to CS10=4, 9, 18, 32, 48, 67, 93, 123, 154, 190, CUM10=739), In2 (CS1 to CS10=4, 9, 18, 31, 47, 69, 96, 125, 156, 192, CUM10=748), In3 (CS1 to CS10=4, 10, 18, 30, 50, 72, 92, 120, 158, 198, CUM10=753).
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