Long-Range Magnetic Ordering in a TbIII–MoV Cyanido-Bridged Quasi-One-Dimensional Complex†
Ferry Prins
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-4451 http://www.chem.leidenuniv.nl/cbac
Search for more papers by this authorEdoardo Pasca Dr.
Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, PO Box 9504, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-5404
Search for more papers by this authorL. Jos de Jongh Prof.
Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, PO Box 9504, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-5404
Search for more papers by this authorHuub Kooijman Dr.
Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands
Search for more papers by this authorAnthony L. Spek Prof.
Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands
Search for more papers by this authorStefania Tanase Dr.
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-4451 http://www.chem.leidenuniv.nl/cbac
Search for more papers by this authorFerry Prins
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-4451 http://www.chem.leidenuniv.nl/cbac
Search for more papers by this authorEdoardo Pasca Dr.
Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, PO Box 9504, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-5404
Search for more papers by this authorL. Jos de Jongh Prof.
Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, PO Box 9504, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-5404
Search for more papers by this authorHuub Kooijman Dr.
Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands
Search for more papers by this authorAnthony L. Spek Prof.
Bijvoet Center for Biomolecular Research, Crystal and Structural Chemistry, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands
Search for more papers by this authorStefania Tanase Dr.
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, PO Box 9502, 2300 RA, Leiden, The Netherlands, Fax: (+31) 71-527-4451 http://www.chem.leidenuniv.nl/cbac
Search for more papers by this authorThe authors acknowledge Prof. Jan Reedijk (Leiden University) for valuable discussions. This research was supported by a Veni grant from the Netherlands Organization for Scientific Research (NWO) to S.T. and the ECNetwork of Excellence Magmanet (No. 515767-2).
Graphical Abstract
One-dimensional polymer [Tb(pzam)3(H2O)Mo(CN)8]⋅H2O (see picture, pzam=pyrazine-2-carboxamide; C black, Mo yellow, N blue, O red, Tb green) has been synthesized and characterized. Its magnetic susceptibility data indicate substantial ferromagnetic superexchange between TbIII and MoV via the cyanido bridge, and the occurrence of long-range magnetic ordering between chains at Tc≈1 K.
References
- 1S. J. Blundell, F. L. Pratt, J. Phys. Condens. Matter 2004, 16, R 771–R828.
- 2O. Kahn, Acc. Chem. Res. 2000, 33, 647–657.
- 3J. S. Miller, A. J. Epstein, Angew. Chem. 1994, 106, 399–432; Angew. Chem. Int. Ed. Engl. 1994, 33, 385–415.
- 4W. R. Entley, G. S. Girolami, Science 1995, 268, 397–400.
- 5T. Mallah, S. Thiebaut, M. Verdaguer, P. Veillet, Science 1993, 262, 1554–1557.
- 6M. Ohba, H. Okawa, Coord. Chem. Rev. 2000, 198, 313–328.
- 7S. Tanase, J. Reedijk, Coord. Chem. Rev. 2006, 250, 2501–2510.
- 8M. Verdaguer, A. Bleuzen, V. Marvaud, J. Vaissermann, M. Seuleiman, C. Desplanches, A. Scuiller, C. Train, R. Garde, G. Gelly, C. Lomenech, I. Rosenman, P. Veillet, C. Cartier, F. Villain, Coord. Chem. Rev. 1999, 192, 1023–1047.
- 9J. M. Herrera, V. Marvaud, M. Verdaguer, J. Marrot, M. Kalisz, C. Mathoniere, Angew. Chem. 2004, 116, 5584–5587;
10.1002/ange.200460387 Google ScholarAngew. Chem. Int. Ed. 2004, 43, 5468–5471.
- 10S. Ohkoshi, H. Tokoro, T. Hozumi, Y. Zhang, K. Hashimoto, C. Mathoniere, I. Bord, G. Rombaut, M. Verelst, C. C. D. Moulin, F. Villain, J. Am. Chem. Soc. 2006, 128, 270–277.
- 11B. Sieklucka, R. Podgajny, P. Przychodzen, T. Korzeniak, Coord. Chem. Rev. 2005, 249, 2203–2221.
- 12S. Ikeda, T. Hozumi, K. Hashimoto, S. Ohkoshi, Dalton Trans. 2005, 2120–2123.
- 13P. Przychodzen, K. Lewinski, R. Pelka, M. Balanda, K. Tomala, B. Sieklucka, Dalton Trans. 2006, 625–628.
- 14S. Tanase, F. Prins, J. M. M. Smits, R. de Gelder, CrystEngComm 2006, 8, 863–865.
- 15Z. X. Wang, X. F. Shen, J. Wang, P. Zhang, Y. Z. Li, E. N. Nfor, Y. Song, S. I. Ohkoshi, K. Hashimoto, X. Z. You, Angew. Chem. 2006, 118, 3365–3369; Angew. Chem. Int. Ed. 2006, 45, 3287–3291.
- 16R. L. Carlin, Magnetochemistry, Springer, Berlin, 1997.
- 17M. Evangelisti, M. L. Kahn, J. Bartolome, L. J. de Jongh, C. Meyers, J. Leandri, Y. Leroyer, C. Mathoniere, Phys. Rev. B 2003, 68, 2534–2549.
- 18C. K. Loong, L. Soderholm, G. L. Goodman, M. M. Abraham, L. A. Boatner, Phys. Rev. B 1993, 48, 6124–6131.
- 19J. W. Orton, Electronic Paramagnetic Resonance. An Introduction to Transition Group Ions in Crystals, Gordon and Breach, New York, 1968.
- 20H. Sen, D. Neogy, B. M. Wanklyn, J. Magn. Magn. Mater. 1988, 73, 221–228.
- 21L. J. de Jongh, A. R. Miedema, Adv. Phys. 2001, 50, 947–1170.
- 22A. Abragam, B. Bleaney, Electron Paramagnetic Resonance of Transition Ions, Clarendon, Oxford, 1970.
- 23C. H. Anderson, E. S. Sabisky, Phys. Rev. B 1971, 3, 527–536.
- 24J. Villain, J. M. Loveluck, J. Phys. Lett. 1977, 38, L77–L80.
- 25G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen (Germany), 1997.
