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Lithiumboryl—A Synthon for a Nucleophilic Boryl Anion
Holger Braunschweig Prof. Dr.,
Holger Braunschweig Prof. Dr.
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, Fax: (+49) 931-888-4623
Search for more papers by this authorHolger Braunschweig Prof. Dr.,
Holger Braunschweig Prof. Dr.
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany, Fax: (+49) 931-888-4623
Search for more papers by this authorGraphical Abstract
B negative: By reduction of a 2-bromo-1,3,2-diazaborole Yamashita, Nozaki, and co-workers have obtained the first three-coordinate boryl anion (see formula), which provides an unprecedented and synthetically highly useful source for a nucleophilic boron species.
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