Volume 44, Issue 16 pp. 2407-2410
Communication

Reversible Transformation of Two Diphenylphosphanido Ligands into the Neutral Tetraphenyldiphosphane Ligand

Juan Forniés Prof.

Juan Forniés Prof.

Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187

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Consuelo Fortuño Dr.

Consuelo Fortuño Dr.

Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187

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Susana Ibáñez

Susana Ibáñez

Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187

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Antonio Martín Dr.

Antonio Martín Dr.

Departamento de Química Inorgánica and Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza—CSIC, 50009 Zaragoza, Spain, Fax: (+34) 976-761-187

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Athanasios C. Tsipis Dr.

Athanasios C. Tsipis Dr.

Section of Inorganic and Analytical Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece

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Constantinos A. Tsipis Prof.

Constantinos A. Tsipis Prof.

Laboratory of Applied Quantum Chemistry, Faculty of Chemistry, Aristotle University of Thessaloniki, 54006 Thessaloniki, Greece, Fax: (+30) 2310-99-7851

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First published: 13 April 2005
Citations: 39

Polynuclear Homo- or Heterometallic Palladium(II)-Platinum(II) Pentafluorophenyl Complexes Containing Bridging Diphenylphosphido Ligands, Part 16. Part 15: I. Ara, N. Chaouche, J. Forniés, C. Fortuño, A. Kribii, A. C. Tsipis, C. A. Tsipis, Inorg. Chim. Acta DOI: 10.1016/j.ica.2004.04.006. This work was supported by the Ministerio de Ciencia y Tecnología y Fondos FEDER (Project BQU2002-03997-C02-02) and the Diputación General de Aragón. S.I. thanks the Ministerio de Ciencia y Tecnología for a grant.

Graphical Abstract

From a theoretical prediction to an experimental finding: Oxidation of two bridging diphenylphosphanido ligands to a neutral tetraphenyldiphosphane is predicted theoretically and achieved experimentally in a trinuclear Pt2Pd complex (see scheme, RF=C6F5, P*=PPh2).

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