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Macroscopic Spinning Chirality Memorized in Spin-Coated Films of Spatially Designed Dendritic Zinc Porphyrin J-Aggregates^†

Tatsuya Yamaguchi Dr.

Aida Nanospace Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), 2-41 Aomi, Koto-ku, Tokyo 135-0064, Japan, Fax: (+81) 3-5841-7310

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Tatsumi Kimura Dr.,

Tatsumi Kimura Dr.

Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi Tsukuba, Ibaraki 305-8565, Japan

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Hiro Matsuda Dr.,

Hiro Matsuda Dr.

Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi Tsukuba, Ibaraki 305-8565, Japan

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Takuzo Aida Prof. Dr.,

Takuzo Aida Prof. Dr.

[email protected]

Aida Nanospace Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), 2-41 Aomi, Koto-ku, Tokyo 135-0064, Japan, Fax: (+81) 3-5841-7310

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Tatsuya Yamaguchi Dr.,

Tatsuya Yamaguchi Dr.

Aida Nanospace Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), 2-41 Aomi, Koto-ku, Tokyo 135-0064, Japan, Fax: (+81) 3-5841-7310

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Tatsumi Kimura Dr.,

Tatsumi Kimura Dr.

Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi Tsukuba, Ibaraki 305-8565, Japan

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Hiro Matsuda Dr.,

Hiro Matsuda Dr.

Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi Tsukuba, Ibaraki 305-8565, Japan

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Takuzo Aida Prof. Dr.,

Takuzo Aida Prof. Dr.

[email protected]

Aida Nanospace Project, Exploratory Research for Advanced Technology (ERATO), Japan Science and Technology Agency (JST), 2-41 Aomi, Koto-ku, Tokyo 135-0064, Japan, Fax: (+81) 3-5841-7310

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First published: 23 November 2004

https://doi.org/10.1002/anie.200461431

Citations: 195

^†

T.Y. thanks the JSPS Young Scientist Fellowship.

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Graphical Abstract

Supramolecular polymerization of dendritic zinc porphyrins with two carboxylic acid functionalities leads to the formation of J-aggregates through multipoint π-stacking interactions. Spin-coating of the J-aggregate solutions gives optically active films, whose sense of chirality can be selected by the spinning direction (see picture). The chiroptical memory is thermally stable up to the melting temperatures of the spin-coated films.

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Volume43, Issue46

November 26, 2004

Pages 6350-6355

Macroscopic Spinning Chirality Memorized in Spin-Coated Films of Spatially Designed Dendritic Zinc Porphyrin J-Aggregates^†

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Macroscopic Spinning Chirality Memorized in Spin-Coated Films of Spatially Designed Dendritic Zinc Porphyrin J-Aggregates†

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Macroscopic Spinning Chirality Memorized in Spin-Coated Films of Spatially Designed Dendritic Zinc Porphyrin J-Aggregates^†