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Bimetallic Figure-Eight Octaphyrins Split into Four-Pyrrolic Macrocycles
Lechosław Latos-Grażyński Prof. Dr.,
Lechosław Latos-Grażyński Prof. Dr.
Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie Street, Wrocław 50 383, Poland, Fax: (+48) 713-282-348
Search for more papers by this authorLechosław Latos-Grażyński Prof. Dr.,
Lechosław Latos-Grażyński Prof. Dr.
Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie Street, Wrocław 50 383, Poland, Fax: (+48) 713-282-348
Search for more papers by this authorGraphical Abstract
Molecular mitosis: Figure-eight octaphyrins form binuclear metal complexes that can split into two covalently spiro-linked corrolates. In a unique case binuclear CuII [36]octaphyrin divides thermally into two CuII [18]porphyrins presumably with participation of a transient spirocyclobutane species (see schematic representation).
References
- 1J. L. Sessler, D. Seidel, Angew. Chem. 2003, 115, 5292;
10.1002/ange.200200561 Google ScholarAngew. Chem. Int. Ed. 2003, 42, 5134.
- 2S. J. Weghorn, J. L. Sessler, V. Lynch, T. F. Baumann, J. W. Sibert, Inorg. Chem. 1996, 35, 1089.
- 3W. A. Reiter, A. Gerges, S. Lee, T. Deffo, T. Clifford, A. Danby, J. Bowman-James, Coord. Chem. Rev. 1998, 174, 343.
- 4A. Srinivasan, T. Ishizuka, A. Osuka, H. Furuta, J. Am. Chem. Soc. 2003, 125, 878.
- 5J. M. Veauthier, W.-S. Cho, V. M. Lynch, J. L. Sessler, Inorg. Chem. 2004, 43, 1220.
- 6S. J. Narayanan, B. Sridevi, T. K. Chandrashekar, U. Englich, K. Ruhlandt-Senge, Inorg. Chem. 2001, 40, 1637.
- 7G. Givaja, A. J. Blake, C. Wilson, M. Schröder, J. B. Love, Chem. Commun. 2003, 2508.
- 8H. Adams, M. R. J. Elsegood, D. E. Fenton, S. L. Heath, S. J. Ryan, J. Chem. Soc. Dalton Trans. 1999, 2031.
- 9A. Werner, M. Michels, L. Zander, J. Lex, E. Vogel, Angew. Chem. 1999, 111, 3866;
10.1002/(SICI)1521-3757(19991216)111:24<3866::AID-ANGE3866>3.0.CO;2-R Google ScholarAngew. Chem. Int. Ed. 1999, 38, 3650.10.1002/(SICI)1521-3773(19991216)38:24<3650::AID-ANIE3650>3.0.CO;2-F CAS PubMed Web of Science® Google Scholar
- 10J. Bley-Escrich, J. P. Gisselbrecht, E. Vogel, M. Gross, Eur. J. Inorg. Chem. 2002, 2829.
- 11E. Vogel, M. Michels, L. Zander, J. Lex, N. S. Tuzun, K. N. Houk, Angew. Chem. 2003, 115, 2964;
10.1002/ange.200250690 Google ScholarAngew. Chem. Int. Ed. 2003, 42, 2857.
- 12G. Hohlneicher, D. Bremm, J. Wytko, J. Bley-Escrich, J.-P. Gisselbert, M. Gross, M. Michels, J. Lex, E. Vogel, Chem. Eur. J. 2003, 9, 5636.
- 13J. Bley-Escrich, J.-P. Gisselbert, M. Michels, L. Zander, E. Vogel, M. Gross, Eur. J. Inorg. Chem. 2004, 492.
- 14Y. Tanaka, W. Hoshino, S. Shimizu, K. Youfu, N. Aratani, N. Maruyama, S. Fujita, A. Osuka, J. Am. Chem. Soc. 2004, 126, 3046.
- 15E. Vogel, M. Bröring, J. Fink, D. Rosen, H. Schmickler, J. Lex, K. W. K. Chan, Y.-D. Wu, D. A. Plattner, M. Nendel, K. N. Houk, Angew. Chem. 1995, 107, 2705;
10.1002/ange.19951072211 Google ScholarAngew. Chem. Int. Ed. Engl. 1995, 34, 2511.
- 16M. Bröring, J. Jendrny, L. Zander, H. Schmickler, J. Lex, Y.-D. Wu, M. Nendel, J. G. Cheng, D. A. Plattner, K. N. Houk, E. Vogel, Angew. Chem. 1995, 107, 2709;
10.1002/ange.19951072212 Google ScholarAngew. Chem. Int. Ed. Engl. 1995, 34, 2515.
- 17D. Seidel, V. Lynch, J. L. Sessler, Angew. Chem. 2002, 114, 1480;
10.1002/1521-3757(20020415)114:8<1480::AID-ANGE1480>3.0.CO;2-8 Google ScholarAngew. Chem. Int. Ed. 2002, 41, 1422.10.1002/1521-3773(20020415)41:8<1422::AID-ANIE1422>3.0.CO;2-O CAS PubMed Web of Science® Google Scholar
- 18J. L. Sessler, D. Seidel, V. Lynch, J. Am. Chem. Soc. 1999, 121, 11 257.
- 19J. Setsune, S. Maeda, J. Am. Chem. Soc. 2000, 122, 12 405.
- 20J.-Y. Shin, H. Furuta, K. Yoza, S. Igarashi, A. Osuka, J. Am. Chem. Soc. 2001, 123, 7190.
- 21J. L. Sessler, S. J. Weghorn, V. Lynch, M. R. Johnson, Angew. Chem. 1994, 106, 1572; Angew. Chem. Int. Ed. Engl. 1994, 33, 1509.
- 22J. A. Wytko, M. Michels, L. Zander, J. Lex, H. Schmickler, E. Vogel, J. Org. Chem. 2000, 65, 8709.
- 23N. Sprutta, L. Latos-Grażyński, Chem. Eur. J. 2001, 7, 5099.
10.1002/1521-3765(20011203)7:23<5099::AID-CHEM5099>3.0.CO;2-M CAS PubMed Web of Science® Google Scholar
- 24A. Tsuda, H. Furuta, A. Osuka, J. Am. Chem. Soc. 2001, 123, 10 304.
- 25X. Peng, N. Aratani, A. Tagaki, T. Matsumoto, T. Kawai, I.-W. Hwang, T. K. Ahn, D. Kim, A. Osuka, J. Am. Chem. Soc. 2004, 126, 4468.
