A Hybrid Solid with Giant Pores Prepared by a Combination of Targeted Chemistry, Simulation, and Powder Diffraction
Gérard Férey
Institut universitaire de France, Fax:(+33) 1-3925-4358
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorChristian Serre
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorCaroline Mellot-Draznieks
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorFranck Millange
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorSuzy Surblé
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorJulien Dutour
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorGérard Férey
Institut universitaire de France, Fax:(+33) 1-3925-4358
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorChristian Serre
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorCaroline Mellot-Draznieks
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorFranck Millange
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorSuzy Surblé
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorJulien Dutour
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
Search for more papers by this authorGraphical Abstract
A perfect combination: The association of a chromium(III) trimeric building unit and 1,3,5-benzenetricarboxylate led to the powdered solid MIL-100. Simulations provided a crystal structure solution, which matched the experimental powder XRD pattern. This unique simulation/diffraction combination allowed the structure determination of a giant-pore solid with a zeotype architecture, built up from hybrid supertetrahedra (see picture).
Supporting Information
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