T-Shaped Nets of Antimony Atoms in the Binary Antimonide Hf5Sb9†
Abdeljalil Assoud Dr.
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorKatja M. Kleinke
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorNavid Soheilnia
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorHolger Kleinke Prof.
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorAbdeljalil Assoud Dr.
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorKatja M. Kleinke
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorNavid Soheilnia
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorHolger Kleinke Prof.
Department for Chemistry, University of Waterloo, Waterloo, Ontario, N2L 3G1, Canada, Fax: (+1) 519-746-0435
Search for more papers by this authorWe are indebted to the Natural Sciences and Engineering Research Council of Canada for financial support.
Graphical Abstract
T time: The new binary antimonide Hf5Sb9 forms a unique variant of a square-planar net, namely an unprecedented yet simple T-shaped net (see picture, green) formed by antimony atoms (red). The electronic structure and bonding in the solid state are analyzed by theoretical methods.
References
- 1G. Cordier, H. Schäfer, P. Woll, Z. Kristallogr. 1985, 40B, 1097–1099.
- 2A. Leithe-Jasper, P. Rogl, J. Alloys Compd. 1994, 203, 133–136.
- 3O. Sologub, K. Hiebl, P. Rogl, H. Noël, O. Bodak, J. Alloys Compd. 1994, 210, 153–157.
- 4P. Wollesen, W. Jeitschko, M. Brylak, L. Dietrich, J. Alloys Compd. 1996, 245, L 5–L8.
- 5J. H. Albering, W. Jeitschko, Z. Naturforsch. B 1996, 51, 257–262.
- 6K. D. Myers, S. L. Bud'ko, I. R. Fisher, Z. Islam, H. Kleinke, A. H. Lacerda, P. C. Canfield, J. Magn. Magn. Mater. 1999, 205, 27–52.
- 7R. Wang, H. Steinfink, Inorg. Chem. 1967, 6, 1685–1692.
- 8A. M. Mills, A. Mar, J. Am. Chem. Soc. 2001, 123, 1151–1158.
- 9M. J. Ferguson, R. E. Ellenwood, A. Mar, Inorg. Chem. 1999, 38, 4503–4509.
- 10M. Brylak, W. Jeitschko, Z. Naturforsch. B 1995, 50, 899–904.
- 11M. J. Ferguson, R. W. Hushagen, A. Mar, J. Alloys Compd. 1997, 249, 191–198.
- 12W. Tremel, R. Hoffmann, J. Am. Chem. Soc. 1987, 109, 124–140.
- 13G. A. Papoian, R. Hoffmann, Angew. Chem. 2000, 112, 2500–2544;
10.1002/1521-3757(20000717)112:14<2500::AID-ANGE2500>3.0.CO;2-T Google ScholarAngew. Chem. Int. Ed. 2000, 39, 2408–2448.10.1002/1521-3773(20000717)39:14<2408::AID-ANIE2408>3.0.CO;2-U PubMed Web of Science® Google Scholar
- 14F. Hulliger, R. Schmelczer, D. Schwarzenbach, J. Solid State Chem. 1977, 21, 371–374.
- 15R. Ceolin, N. Rodier, P. Khodadad, J. Less-Common Met. 1977, 53, 137–140.
- 16Y. C. Wang, K. M. Poduska, R. Hoffmann, F. J. DiSalvo, J. Alloys Compd. 2001, 314, 132–139.
- 17E. Dashjav, O. Oeckler, T. Doert, H. Mattausch, P. Böttcher, Angew. Chem. 2000, 112, 2089–2091;
10.1002/1521-3757(20000602)112:11<2089::AID-ANGE2089>3.0.CO;2-B Google ScholarAngew. Chem. Int. Ed. 2000, 39, 1987–1988.
- 18R. Tamazyan, S. van Smaalen, I. G. Vasilyeva, H. Arnold, Acta Crystallogr. B 2003, 59, 709–719.
- 19R. Patschke, M. G. Kanatzidis, Phys. Chem. Chem. Phys. 2002, 4, 3266–3281.
- 20H. Kleinke, Chem. Commun. 1998, 2219–2220.
- 21A. Kjekshus, Acta Chem. Scand. 1972, 26, 1633–1639.
- 22W. Rossteutscher, K. Schubert, Z. Metallkd. 1965, 56, 813–822.
- 23P. Villars, Pearson's Handbook, Desk Edition, American Society for Metals, Materials Park, OH, 1997.
- 24R. Ferro, Accad. Med. Accad. Lincei 1952, 13, 151–157.
- 25R. Ferro, Acta Crystallogr. 1956, 9, 817–818.
- 26H. Kleinke, Inorg. Chem. 1999, 38, 2931–2935.
- 27Apparatus: NETZSCH STA 409PC Luxx. The measurement was performed under a constant flow of argon, with heating and cooling rates of 20 °C min−1. The sample started to lose weight above 780 °C, with a total weight loss of 3.2 %.
- 28Electron microscope: LEO 1530, with an additional EDS device (EDAX Pegasus 1200). No impurities, for example, stemming from the reaction container, were found.
- 29The single-crystal structure study was performed using a Smart APEX CCD diffractometer (Bruker), utilizing MoKα radiation, up to 2θ=70°. Hf5Sb9 crystallizes in the tetragonal space group P4/n, with lattice dimensions of a=874.83(3), c=866.46(6) pm (Z=2). Final residual factors are R1=0.0355, wR2=0.0899, GOF=1.246 (all data, 1330 independent reflections, 35 parameters). Further details on the crystal-structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (+49) 7247-808-666; e-mail: [email protected]), on quoting the depository number CSD-413979.
- 30I. Elder, C.-S. Lee, H. Kleinke, Inorg. Chem. 2002, 41, 538–545.
- 31A. Ienco, D. M. Proserpio, R. Hoffmann, Inorg. Chem. 2004, 43, 2526–2540.
- 32H. Holseth, A. Kjekshus, Acta Chem. Scand. 1968, 22, 3284–3292.
- 33C.-S. Lee, H. Kleinke, Eur. J. Inorg. Chem. 2002, 591–596.
- 34H. Kleinke, J. Am. Chem. Soc. 2000, 122, 853–860.
- 35W. S. Sheldrick, M. Wachhold, Angew. Chem. 1995, 107, 490–491;
10.1002/ange.19951070412 Google ScholarAngew . Chem. Int. Ed. Engl. 1995, 34, 450–451.
- 36W. S. Sheldrick, M. Wachhold, Chem. Commun. 1996, 607–608.
- 37L. Pauling, The Nature of the Chemical Bond, 3rd ;Ed. 1948.
- 38Q. Liu, N. Goldberg, R. Hoffmann, Chem. Eur. J. 1996, 2, 390–397.
- 39F. Boucher, R. Rousseau, Inorg. Chem. 1998, 37, 2351–2357.
- 40O. K. Andersen, Phys. Rev. B 1975, 12, 3060–3083.
- 41R. Dronskowski, P. E. Blöchl, J. Phys. Chem. 1993, 97, 8617–8624.
- 42E. Garcia, J. D. Corbett, J. Solid State Chem. 1988, 73, 452–467.
- 43G. Papoian, R. Hoffmann, J. Am. Chem. Soc. 2001, 123, 6600–6608.
- 44Y. Zhu, H. Kleinke, Z. Anorg. Allg. Chem. 2002, 628, 2233.
- 45H. Kleinke, Inorg. Chem. 2001, 40, 95–100.
- 46N. Soheilnia, A. Assoud, H. Kleinke, Inorg. Chem. 2003, 42, 7319–7325.
