A Route to the Synthesis of Trivalent Transition-Metal Porous Carboxylates with Trimeric Secondary Building Units†
Christian Serre
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorFranck Millange
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorSuzy Surblé
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorGérard Férey
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorChristian Serre
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorFranck Millange
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorSuzy Surblé
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorGérard Férey
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France, Fax:(+33) 1-3925-4358
Search for more papers by this authorAuthors are indebted to Daniel Loüer and Gérard Marsolier from Rennes (France) for collecting the X-ray data of MIL-89 ht and Dr C. Mellot-Draznieks for helpful discussions.
Graphical Abstract
Prefabricated construction techniques: A solvothermal route involving iron(III) trimeric secondary building units has been developed. Two new open-framework iron (III) dicarboxylates have been characterized from X-ray powder diffraction studies. Their 3D structures are built up from trimers of iron polyhedra related through dicarboxylates, thus creating cationic frameworks with 1D pore systems filled with solvent molecules and anions (see example).
Supporting Information
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