Volume 135, Issue 51 e202314883

Forschungsartikel

Engineering Fluorine-rich Double Protective Layer on Zn Anode for Highly Reversible Aqueous Zinc-ion Batteries

Titi Li

School of Physics and Technology, University of Jinan, Shandong, 250022 China

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

These authors contributed equally to this work.

Contribution: Conceptualization (lead), Data curation (lead), Investigation (lead), Resources (lead), Writing - original draft (lead)

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Sanlue Hu,

Sanlue Hu

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

These authors contributed equally to this work.

Contribution: Methodology (lead), Software (lead), Writing - review & editing (equal)

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Chenggang Wang,

Chenggang Wang

School of Physics and Technology, University of Jinan, Shandong, 250022 China

These authors contributed equally to this work.

Contribution: Supervision (lead), Writing - review & editing (equal)

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Dun Wang,

Dun Wang

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead)

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Minwei Xu,

Minwei Xu

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Resources (lead), Supervision (lead)

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Caiyun Chang,

Corresponding Author

Caiyun Chang

[email protected]

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Conceptualization (lead), Data curation (lead), Investigation (lead), Methodology (lead), Resources (equal), Writing - review & editing (equal)

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Xijin Xu,

Corresponding Author

Xijin Xu

[email protected]

School of Physics and Technology, University of Jinan, Shandong, 250022 China

Contribution: Resources (lead), Supervision (lead), Writing - review & editing (lead)

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Cuiping Han,

Corresponding Author

Cuiping Han

[email protected]

orcid.org/0000-0003-1186-3234

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Methodology (lead), Resources (lead), Supervision (lead), Writing - review & editing (lead)

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Titi Li,

Titi Li

School of Physics and Technology, University of Jinan, Shandong, 250022 China

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

These authors contributed equally to this work.

Contribution: Conceptualization (lead), Data curation (lead), Investigation (lead), Resources (lead), Writing - original draft (lead)

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Sanlue Hu,

Sanlue Hu

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

These authors contributed equally to this work.

Contribution: Methodology (lead), Software (lead), Writing - review & editing (equal)

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Chenggang Wang,

Chenggang Wang

School of Physics and Technology, University of Jinan, Shandong, 250022 China

These authors contributed equally to this work.

Contribution: Supervision (lead), Writing - review & editing (equal)

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Dun Wang,

Dun Wang

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead)

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Minwei Xu,

Minwei Xu

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Resources (lead), Supervision (lead)

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Caiyun Chang,

Corresponding Author

Caiyun Chang

[email protected]

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Conceptualization (lead), Data curation (lead), Investigation (lead), Methodology (lead), Resources (equal), Writing - review & editing (equal)

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Xijin Xu,

Corresponding Author

Xijin Xu

[email protected]

School of Physics and Technology, University of Jinan, Shandong, 250022 China

Contribution: Resources (lead), Supervision (lead), Writing - review & editing (lead)

Search for more papers by this author

Cuiping Han,

Corresponding Author

Cuiping Han

[email protected]

orcid.org/0000-0003-1186-3234

Faculty of Materials Science and Energy Engineering/Institute of Technology for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Shenzhen Key Laboratory of Energy Materials for Carbon Neutrality, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

Contribution: Methodology (lead), Resources (lead), Supervision (lead), Writing - review & editing (lead)

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First published: 04 November 2023

https://doi.org/10.1002/ange.202314883

Citations: 1

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Abstract

The high thermodynamic instability and side reactions of Zn-metal anode (ZMA), especially at high current densities, greatly impede the commercialization of aqueous zinc-ion batteries (AZIBs). Herein, a fluorine-rich double protective layer strategy is proposed to obtain the high reversibility of AZIBs through the introduction of a versatile tetradecafluorononane-1,9-diol (TDFND) additive in aqueous electrolyte. TDFND molecule with large adsorption energy (−1.51 eV) preferentially absorbs on the Zn anode surface to form a Zn(OR)₂⁻ (R=−CH₂−(CF₂)₇−CH₂−) cross-linking complex network, which balances space electric field and controls the Zn²⁺ ion flux, thus enabling the uniform and compact deposition of Zn (002) crystal planes. Meanwhile, TDFND with low Lowest unoccupied molecular orbital (LUMO, 0.10 eV) energy level is priorly decomposed to regulate the interfacial chemistry of ZMA by building a ZnF₂-rich solid electrode/electrolyte interface (SEI) layer. It is found that a 14 nm-thick SEI layer delivers excellent structural integrity to suppress parasitic reactions by blocking the direct contact of active water and ZMA. Consequently, the Zn electrode exhibits a superior cycling life over 430 h at 10 mA cm⁻² and a high average Coulombic efficiency of 99.8 % at 5 mA cm⁻². Furthermore, a 68 mAh pouch cell delivers 80.3 % capacity retention for 1000 cycles.

Conflict of interest

The authors declare no conflict of interest.

Open Research

Data Availability Statement

Research data are not shared.

Supporting Information

References

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Engineering Fluorine-rich Double Protective Layer on Zn Anode for Highly Reversible Aqueous Zinc-ion Batteries

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Conflict of interest

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

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Engineering Fluorine-rich Double Protective Layer on Zn Anode for Highly Reversible Aqueous Zinc-ion Batteries

Abstract

Conflict of interest

Open Research

Data Availability Statement

Supporting Information

References

Citing Literature

References

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