Dual-Function Presodiation with Sodium Diphenyl Ketone towards Ultra-stable Hard Carbon Anodes for Sodium-Ion Batteries
Hengyi Fang
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
These authors contributed equally to this work.
Search for more papers by this authorSuning Gao
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
These authors contributed equally to this work.
Search for more papers by this authorMeng Ren
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorYaohui Huang
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorProf. Fangyi Cheng
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300071 China
Search for more papers by this authorProf. Jun Chen
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300071 China
Search for more papers by this authorCorresponding Author
Prof. Fujun Li
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300071 China
Search for more papers by this authorHengyi Fang
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
These authors contributed equally to this work.
Search for more papers by this authorSuning Gao
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
These authors contributed equally to this work.
Search for more papers by this authorMeng Ren
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorYaohui Huang
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Search for more papers by this authorProf. Fangyi Cheng
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300071 China
Search for more papers by this authorProf. Jun Chen
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300071 China
Search for more papers by this authorCorresponding Author
Prof. Fujun Li
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin, 300071 China
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin, 300071 China
Search for more papers by this authorAbstract
Hard carbon (HC) is a promising anode material for sodium-ion batteries, yet still suffers from low initial Coulombic efficiency (ICE) and unstable solid electrolyte interphase (SEI). Herein, sodium diphenyl ketone (Na-DK) is applied to realize dual-function presodiation for HC anodes. It compensates the irreversible Na uptake at the oxygen-containing functional groups and reacts with carbon defects of five/seven-membered rings for quasi-metallic sodium in HC. The as-formed sodium induces robust NaF-rich SEI on HC in 1.0 M NaPF6 in diglyme, favoring the interfacial reaction kinetics and stable Na+ insertion and extraction. This renders the presodiated HC (pHC) with high ICE of ≈100 % and capacity retention of 82.4 % after 6800 cycles. It is demonstrated to couple with Na3V2(PO4)3 cathodes in full cells to show high capacity retention of ≈100 % after 700 cycles. This work provides in-depth understanding of chemical presodiation and a new strategy for highly stable sodium-ion batteries.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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