A Multifunctional Polymer as an Interfacial Layer for Efficient and Stable Perovskite Solar Cells
Bingqian Zhang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Conceptualization (equal), Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Project administration (equal), Validation (lead), Visualization (equal), Writing - original draft (lead), Writing - review & editing (equal)
Search for more papers by this authorChen Chen
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Data curation (supporting), Formal analysis (supporting), Investigation (supporting), Methodology (supporting), Visualization (supporting)
Search for more papers by this authorXianzhao Wang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Data curation (supporting), Formal analysis (supporting), Investigation (supporting), Resources (equal), Validation (supporting)
Search for more papers by this authorXiaofan Du
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Methodology (supporting), Software (lead)
Search for more papers by this authorDachang Liu
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Formal analysis (supporting), Methodology (supporting), Resources (supporting), Validation (supporting), Visualization (supporting), Writing - review & editing (supporting)
Search for more papers by this authorXiuhong Sun
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Formal analysis (supporting), Investigation (supporting), Validation (supporting), Writing - review & editing (supporting)
Search for more papers by this authorZhipeng Li
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Methodology (supporting), Validation (supporting), Visualization (supporting)
Search for more papers by this authorLianzheng Hao
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Investigation (supporting), Methodology (supporting), Validation (supporting)
Search for more papers by this authorCaiyun Gao
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Formal analysis (supporting), Resources (supporting), Validation (supporting)
Search for more papers by this authorYimeng Li
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Investigation (supporting), Validation (supporting)
Search for more papers by this authorZhipeng Shao
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Investigation (supporting), Methodology (supporting)
Search for more papers by this authorCorresponding Author
Xiao Wang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Conceptualization (equal), Formal analysis (supporting), Funding acquisition (equal), Investigation (supporting), Methodology (supporting), Project administration (equal), Supervision (equal), Validation (equal), Visualization (equal), Writing - review & editing (equal)
Search for more papers by this authorProf. Guanglei Cui
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Methodology (supporting), Supervision (supporting)
Search for more papers by this authorCorresponding Author
Prof. Shuping Pang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Conceptualization (equal), Data curation (supporting), Formal analysis (supporting), Funding acquisition (equal), Investigation (supporting), Methodology (supporting), Project administration (equal), Supervision (equal), Validation (equal), Visualization (equal), Writing - review & editing (equal)
Search for more papers by this authorBingqian Zhang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Conceptualization (equal), Data curation (lead), Formal analysis (lead), Investigation (lead), Methodology (lead), Project administration (equal), Validation (lead), Visualization (equal), Writing - original draft (lead), Writing - review & editing (equal)
Search for more papers by this authorChen Chen
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Data curation (supporting), Formal analysis (supporting), Investigation (supporting), Methodology (supporting), Visualization (supporting)
Search for more papers by this authorXianzhao Wang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Data curation (supporting), Formal analysis (supporting), Investigation (supporting), Resources (equal), Validation (supporting)
Search for more papers by this authorXiaofan Du
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Methodology (supporting), Software (lead)
Search for more papers by this authorDachang Liu
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Formal analysis (supporting), Methodology (supporting), Resources (supporting), Validation (supporting), Visualization (supporting), Writing - review & editing (supporting)
Search for more papers by this authorXiuhong Sun
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Formal analysis (supporting), Investigation (supporting), Validation (supporting), Writing - review & editing (supporting)
Search for more papers by this authorZhipeng Li
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Methodology (supporting), Validation (supporting), Visualization (supporting)
Search for more papers by this authorLianzheng Hao
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Investigation (supporting), Methodology (supporting), Validation (supporting)
Search for more papers by this authorCaiyun Gao
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Formal analysis (supporting), Resources (supporting), Validation (supporting)
Search for more papers by this authorYimeng Li
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Investigation (supporting), Validation (supporting)
Search for more papers by this authorZhipeng Shao
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Contribution: Investigation (supporting), Methodology (supporting)
Search for more papers by this authorCorresponding Author
Xiao Wang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Conceptualization (equal), Formal analysis (supporting), Funding acquisition (equal), Investigation (supporting), Methodology (supporting), Project administration (equal), Supervision (equal), Validation (equal), Visualization (equal), Writing - review & editing (equal)
Search for more papers by this authorProf. Guanglei Cui
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Methodology (supporting), Supervision (supporting)
Search for more papers by this authorCorresponding Author
Prof. Shuping Pang
Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, 266101 P. R. China
Shandong Energy Institute, Qingdao, 266101 P. R. China
Contribution: Conceptualization (equal), Data curation (supporting), Formal analysis (supporting), Funding acquisition (equal), Investigation (supporting), Methodology (supporting), Project administration (equal), Supervision (equal), Validation (equal), Visualization (equal), Writing - review & editing (equal)
Search for more papers by this authorAbstract
Metal-cation defects and halogen-anion defects in perovskite films are critical to the efficiency and stability of perovskite solar cells (PSCs). In this work, a random polymer, poly(methyl methacrylate-co-acrylamide) (PMMA-AM), was synthesized to serve as an interfacial passivation layer for synergistically passivating the under-coordinated Pb2+ and anchor the I- of the [PbI6]4− octahedron. Additionally, the interfacial PMMA-AM passivation layer cannot be destroyed during the hole transport layer deposition because of its low solubility in chlorobenzene. This passivation leads to an enhancement in the open-circuit voltage from 1.12 to 1.22 V and improved stability in solar cell devices, with the device maintaining 95 % of the initial power conversion efficiency (PCE) over 1000 h of maximum power point tracking. Additionally, a large-area solar cell module was fabricated using this approach, achieving a PCE of 20.64 %.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
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