Highly Luminescent One-Dimensional Organic–Inorganic Hybrid Double-Perovskite-Inspired Materials for Single-Component Warm White-Light-Emitting Diodes
Tianxin Bai
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorXiaochen Wang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorZhongyi Wang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorSujun Ji
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorXuan Meng
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorQiujie Wang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorRuiling Zhang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorPeigeng Han
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorProf. Dr. Ke-li Han
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, 116023 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100049 P. R. China
Deceased (17 March 2022)
Search for more papers by this authorDr. Junsheng Chen
Nano-Science Center & Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
Search for more papers by this authorCorresponding Author
Feng Liu
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorCorresponding Author
Bin Yang
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, 116023 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorTianxin Bai
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorXiaochen Wang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorZhongyi Wang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorSujun Ji
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorXuan Meng
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorQiujie Wang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorRuiling Zhang
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorPeigeng Han
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorProf. Dr. Ke-li Han
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, 116023 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100049 P. R. China
Deceased (17 March 2022)
Search for more papers by this authorDr. Junsheng Chen
Nano-Science Center & Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
Search for more papers by this authorCorresponding Author
Feng Liu
Institute of Molecular Sciences and Engineering, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao, 266237 P. R. China
Search for more papers by this authorCorresponding Author
Bin Yang
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, 116023 P. R. China
University of the Chinese Academy of Sciences, Beijing, 100049 P. R. China
Search for more papers by this authorAbstract
Double perovskites (DPs) are one of the most promising candidates for developing white light-emitting diodes (WLEDs) owing to their intrinsic broadband emission from self-trapped excitons (STEs). Translation of three-dimensional (3D) DPs to one-dimensional (1D) analogues, which could break the octahedral tolerance factor limit, is so far remaining unexplored. Herein, by employing a fluorinated organic cation, we report a series of highly luminescent 1D DP-inspired materials, (DFPD)2MIInBr6 (DFPD=4,4-difluoropiperidinium, MI=K+ and Rb+). Highly efficient warm-white photoluminescence quantum yield of 92 % is achieved by doping 0.3 % Sb3+ in (DFPD)2KInBr6. Furthermore, single-component warm-WLEDs fabricated with (DFPD)2KInBr6:Sb yield a luminance of 300 cd/m2, which is one of the best-performing lead-free metal-halides WLEDs reported so far. Our study expands the scope of In-based metal-halides from 3D to 1D, which exhibit superior optical performances and broad application prospects.
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
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