Large-Scale Self-Assembly of MOFs Colloidosomes for Bubble-Propelled Micromotors and Stirring-Free Environmental Remediation
Hai Huang
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (lead), Investigation (lead), Methodology (lead), Software (lead), Visualization (lead), Writing - original draft (lead)
Search for more papers by this authorJie Li
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (equal), Methodology (equal), Writing - original draft (supporting)
Search for more papers by this authorMengge Yuan
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Software (supporting), Writing - original draft (supporting)
Search for more papers by this authorHaowei Yang
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (supporting), Software (supporting), Writing - original draft (supporting)
Search for more papers by this authorYu Zhao
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (supporting), Software (supporting), Writing - original draft (supporting)
Search for more papers by this authorCorresponding Author
Yulong Ying
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Conceptualization (lead), Funding acquisition (lead), Project administration (lead), Supervision (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Sheng Wang
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Funding acquisition (supporting), Writing - review & editing (supporting)
Search for more papers by this authorHai Huang
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (lead), Investigation (lead), Methodology (lead), Software (lead), Visualization (lead), Writing - original draft (lead)
Search for more papers by this authorJie Li
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (equal), Methodology (equal), Writing - original draft (supporting)
Search for more papers by this authorMengge Yuan
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Software (supporting), Writing - original draft (supporting)
Search for more papers by this authorHaowei Yang
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (supporting), Software (supporting), Writing - original draft (supporting)
Search for more papers by this authorYu Zhao
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Data curation (supporting), Software (supporting), Writing - original draft (supporting)
Search for more papers by this authorCorresponding Author
Yulong Ying
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Conceptualization (lead), Funding acquisition (lead), Project administration (lead), Supervision (lead), Writing - review & editing (lead)
Search for more papers by this authorCorresponding Author
Sheng Wang
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou, 310018 P. R. China
Contribution: Funding acquisition (supporting), Writing - review & editing (supporting)
Search for more papers by this authorAbstract
The design of MOF-based micromotors (MOFtors) is still challenging and with limited approaches, especially for the MOF nanoparticles (NPs). Herein, we report a universal and straightforward strategy to efficiently self-assembly MOF NPs into robust MOFtors for enhanced organic- or heavy-metal-ion-contaminants remediation without mechanical stirring. Based on the transient Pickering emulsion method, Fe3O4@NH2-UiO-66 (Fe-UiO) NPs are rapidly self-assembled into Fe3O4@NH2-UiO-66 colloidosomes (Fe-UiOSomes) on a large scale, and the formation mechanism is systematically studied. The Fe-UiOSomes-Pt micromotors through chemical reduction (Micromotor-C) presented a higher motility of 450±180 μm s−1 in a 5 wt% H2O2 aqueous solution. Finally, the bubble-propelled Micromotor-C was employed to efficiently remove dyes and heavy metal ions (94 % for MO and 91 % for CrVI).
Conflict of interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
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