Nikolay Zelinsky (1861–1953): Mendeleev's Protege, a Brilliant Scientist, and the Top Soviet Chemist of the Stalin Era
Prof. Elena K. Beloglazkina
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1–3, Moscow, 119991 Russia
Search for more papers by this authorAssist. Prof. Tatiana V. Bogatova
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1–3, Moscow, 119991 Russia
Search for more papers by this authorCorresponding Author
Prof. Valentine G. Nenajdenko
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1–3, Moscow, 119991 Russia
Search for more papers by this authorProf. Elena K. Beloglazkina
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1–3, Moscow, 119991 Russia
Search for more papers by this authorAssist. Prof. Tatiana V. Bogatova
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1–3, Moscow, 119991 Russia
Search for more papers by this authorCorresponding Author
Prof. Valentine G. Nenajdenko
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1–3, Moscow, 119991 Russia
Search for more papers by this authorAbstract
This Essay outlines the life path and scientific achievements of Nikolai Zelinsky to testify to his contributions to organic chemistry, catalysis, and petrochemistry. His legacy includes four name reactions (the Hell–Volhard–Zelinsky reaction, 1887; the Zelinsky–Stadnikov reaction, 1906; Zelinsky irreversible catalysis, 1911; the Zelinsky–Kazansky acetylene trimerization, 1924), pioneering contributions to the main oil-refining processes (thermal cracking, catalytic cracking, hydrodesulfurization, reforming, and oxidative regeneration of coked catalysts), the coal gas mask, Pd/C and other supported catalysts, and a very large scientific school.
References
- 1
- 1aD. E. Lewis, Early Russian Organic Chemists and Their Legacy, Springer Briefs in Molecular Science, Springer, Berlin, Heidelberg, 2012;
10.1007/978-3-642-28219-5 Google Scholar
- 1bD. E. Lewis, Angew. Chem. Int. Ed. 2019, 58, 3694–3705; Angew. Chem. 2019, 131, 3732–3743.
- 2I. P. Beletskaya, V. G. Nenajdenko, Angew. Chem. Int. Ed. 2019, 58, 4778–4789; Angew. Chem. 2019, 131, 4828–4839.
- 3N. Zelinsky, Ber. Dtsch. Chem. Ges. 1887, 20, 2026.
10.1002/cber.188702001452 Google Scholar
- 4V. N. Ipatieff, The life of a chemist: Memoirs of V. N. Ipatieff (Eds.: X. J. Eudin, H. D. Fisher, H. H. Fisher), Stanford Univ. Press, 1946.
- 5N. D. Zelinsky, Selected works, Moscow, Nauka, 1968, p. 581.
- 6A. Bely, At the turn of two centuries, Moscow, Khudojestvennaya Literatura, 1989, p. 82.
- 7
- 7aN. Zelinsky, Ber. Dtsch. Chem. Ges. 1895, 28, 780–783;
- 7bN. Zelinsky, W. Rudewitsch, Ber. Dtsch. Chem. Ges. 1895, 28, 1341–1344.
- 8
- 8aN. Zelinsky, Ber. Dtsch. Chem. Ges. 1895, 28, 1022–1025;
- 8bN. Zelinsky, A. Reformatsky, Ber. Dtsch. Chem. Ges. 1896, 29, 214–216;
- 8cN. Zelinsky, M. Rudsky, Ber. Dtsch. Chem. Ges. 1896, 29, 403–405;
- 8dN. Zelinsky, V. Generozov, Ber. Dtsch. Chem. Ges. 1896, 29, 729–733;
- 8eN. Zelinsky, S. Naumov, Ber. Dtsch. Chem. Ges. 1898, 31, 3206–3208.
- 9
- 9aN. Zelinsky, I. Tselikov, Zh. Russ. Fiz.-Khim. O-va. 1901, 33, 655–662; N. Zelinsky, I. Gutt, Zh. Russ. Fiz.-Khim. O-va. 1906, 38, 472; N. Zelinsky, Ber. Dtsch. Chem. Ges. 1902, 35, 2488–2493; N. Zelinsky, A. Aleksandrov, Zh. Russ. Fiz.-Khim. O-va. 1913, 45, 378.
- 10
- 10aN. Zelinsky, Zh. Russ. Fiz.-Khim. O-va. 1909, 41, 720–722;
- 10bN. Zelinsky, N. Shuikin, Zh. Russ. Fiz.-Khim. O-va. 1928, 61, 2245–2250;
- 10cN. Zelinsky, N. Elagina, Dokl. Akad. Nauk SSSR 1945, 49, 591–594;
- 10dN. Zelinsky, N. Elagina, Dokl. Akad. Nauk SSSR 1946, 52, 22–25.
- 11
- 11aA. Nikiforov, Chem. Ztg. 1896, 20, 8–15;
- 11bA. Letny, Zh. Russ. Fiz.-Khim. O-va. 1877, 9, 78–89;
- 11cA. Letnyi, Zh. Russ. Fiz.-Khim. O-va. 1877, 9, 269–273;
- 11dA. Letny, Ber. Dtsch. Chem. Ges. 1878, 11, 1210–1212.
10.1002/cber.187801101326 Google Scholar
- 12R. Levina, Yu, Yuriev, Academician N. D. Zelinsky (on the occasion of his 80th birthday), Leningrad, Priroda, 1941, 103–108.
- 13N. Zelinsky, I. Pappe, Zh. Russ. Fiz.-Khim. O-va. 1905, 37, 625–632.
- 14
- 14aN. Zelinsky, M. Turowa-Pollak, Ber. Dtsch. Chem. Ges. 1925, 58, 1292–1298;
- 14bN. Zelinsky, M. Turowa-Pollak, Ber. Dtsch. Chem. Ges. 1929, 62, 1658–1663;
10.1002/cber.19290620647 Google Scholar
- 14cN. Zelinsky, M. Turowa-Pollak, Ber. Dtsch. Chem. Ges. 1932, 65, 1299–1301.
10.1002/cber.19320650814 Google Scholar
- 15
- 15aN. Zelinsky, Yu. Arbuzov, Dokl. Akad. Nauk SSSR 1939, 23, 793;
- 15bN. Zelinsky, Yu. Arbuzov, Dokl. Akad. Nauk SSSR 1939, 24, 542–546;
- 15cN. Zelinsky, Yu. Arbuzov, Dokl. Akad. Nauk SSSR 1941, 30, 712–715.
- 16N. Zelinsky, Yu. Arbuzov, Dokl. Akad. Nauk SSSR 1945, 46, 165–168.
- 17
- 17aN. Zelinsky, G. Stadnikov, Zh. Russ. Fiz.-Khim. O-va. 1906, 38, 473–475;
- 17bN. Zelinsky, G. Stadnikov, Zh. Russ. Fiz.-Khim. O-va. 1906, 38, 722–734.
- 18A. Strecker, Lieb. Ann. 1850, 75, 27–45.
10.1002/jlac.18500750103 Google Scholar
- 19
- 19aN. Zelinsky, A. Anenkov, I. Kulikov, Zh. Russ. Fiz.-Khim. O-va. 1911, 43, 1091–1101;
- 19bN. Zelinsky, E. Dengin, Ber. Dtsch. Chem. Ges. 1922, 55, 3354–3361.
10.1002/cber.19220550948 Google Scholar
- 20
- 20aN. Zelinsky, V. Sadikov, Bioch. Z. 1923, 136, 241–249;
- 20bN. Zelinsky, V. Sadikov, Bioch. Z. 1923, 138, 156–160;
- 20cN. Zelinsky, V. Sadikov, Bioch. Z. 1924, 147, 30–69.
- 21N. Zelinsky, Zh. Russ. Fiz.-Khim. O-va. 1911, 43, 1220–1228.
- 22R. Willstätter, Aus meinem Leben, Verlag Chemie, Weinheim/Bergstrasse, 2. Nachdruck der 2. Auflage, 1973.
- 23P. Sabatier, J.-B. Senderens, Ann. Chim. 1905, 4, 367.
- 24N. Zelinsky, W. Kommarewsky, Ber. Dtsch. Chem. Ges. 1924, 57, 667–669.
- 25
- 25aN. Zelinsky, M. Turowa-Pollak, Ber. Dtsch. Chem. Ges. 1925, 58, 1298–1303;
- 25bN. Zelinsky, M. Turowa-Pollak, Ber. Dtsch. Chem. Ges. 1929, 62, 2865–2869.
10.1002/cber.19290621031 Google Scholar
- 26The note reads, “These are the considerations, based on experimental data, that led us to pay special attention to charcoal as a solid universal gas mask with which, if appropriately applied to the purpose, it would be possible to protect one properly from all asphyxiating gases and vapors, whatever their origin.”.
- 27V. G. Shukhov, S. P. Gavrilov (Russian Empire), patent no. 12926, November 27, 1891.
- 28P. H. Giddens, Standard Oil Company (Indiana): Oil Pioneer of the Middle West, New York, Appleton-Century-Crofts, 1955, pp. 167–168.
- 29A. Zecchina, S. Califano, The Development of Catalysis: A History of Key Processes and Personas in Catalytic Science and Technology, Wiley, 2017, pp. 80–87.
- 30C. P. Nicholas, ACS Catal. 2018, 8, 8531–8539.
- 31N. Zelinsky, Zh. Russ. Fiz.-Khim. O-va. 1915, 47, 1807–1813.
- 32A. G. Oblad, Heterogeneous Catalysis: Selected American Histories, ACS Symposium Series Vol. 222, American Chemical Society, Washington, 1983, pp. 61–75. DOI: 10.1021/bk-1983-0222.ch006.
- 33
- 33aK. S. Egorova, V. P. Ananikov, Angew. Chem. Int. Ed. 2016, 55, 12150–12162; Angew. Chem. 2016, 128, 12334–12347;
- 33bI. P. Beletskaya, V. P. Ananikov, Russ. J. Org. Chem. 2015, 51, 145–147.
- 34
- 34aN. Zelinsky, N. Glinka, Zh. Russ. Fiz.-Khim. O-va. 1911, 43, 1084–1091;
- 34bN. Zelinsky, G. Pavloff, Ber. Dtsch. Chem. Ges. 1924, 57, 1066–1070;
10.1002/cber.19240570632 Google Scholar
- 34cN. Zelinsky, Ber. Dtsch. Chem. Ges. 1925, 58, 185–187;
10.1002/cber.19250580135 Google Scholar
- 34dN. Zelinsky, B. Kazansky, Ber. Dtsch. Chem. Ges. 1924, 57, 2055–2057;
- 34eN. Zelinsky, G. Pavloff, Ber. Dtsch. Chem. Ges. 1933, 66, 1420–1422;
- 34fN. Zelinsky, R. Levina, Ber. Dtsch. Chem. Ges. 1929, 62, 399.
- 35R. Delaby, S. F. Birch, J. Chem. Soc. 1954, 2, 4059–4061.
- 36E. G. Gordeev, E. O. Pentsak, V. P. Ananikov, J. Am. Chem. Soc. 2020, 142, 3784–3796.
- 37M. Berthelot, Ann. Chim. Phys. 1866, 9, 445.
- 38N. Zelinsky, G. Pavloff, Ber. Dtsch. Chem. Ges. 1911, 44, 2781–2782.
10.1002/cber.191104403116 Google Scholar
- 39
- 39aN. Zelinsky, V. Longinoff, Ber. Dtsch. Chem. Ges. 1923, 56, 787–788;
- 39bN. Zelinsky, E. Margolic, Russ. J. Org. Chem. 1932, 2, 755–783;
- 39cN. Zelinsky, I. Tits, Ber. Dtsch. Chem. Ges. 1931, 64, 183–188;
- 39dN. Zelinsky, I. Tits, L. Fatejew, Ber. Dtsch. Chem. Ges. 1926, 59, 2580–2590.
- 40N. Zelinsky, B. Kazansky, A. Plate, Russ. J. Org. Chem. 1934, 4, 168–180.
- 41
- 41aN. Zelinsky, P. Borisoff, Ber. Dtsch. Chem. Ges. 1924, 57, 150–153;
- 41bP. Borissow, Ber. Dtsch. Chem. Ges. 1930, 63, 2278;
10.1002/cber.19300630866 Google Scholar
- 41cN. Zelinsky, Yu. Yuriev, Russ. J. Org. Chem. 1931, 1, 1–4.
- 42N. Zelinsky, E. Shakhnazarova, Izv. AN. Ser. Khim. (Russ. Chem. Bull.) 1936, 571–577.
- 43
- 43aN. Zelinsky, Yu. Yuriev, Izv. AN. Ser. Khim. (Russ. Chem. Bull.) 1930, 851–854;
- 43bN. Zelinsky, Yu. Yurieff, Brennst.-Chem. 1933, 14, 347–349;
- 43cN. Zelinsky, G. Galpern, I. Musaev, Izv. AN. Ser. Khim. (Russ. Chem. Bull.) 1936, 1017–1018.
- 44N. Zelinsky, I. Shuikin, Russ. J. Org. Chem. 1934, 4, 901–907.
- 45B. Kasansky, A. Plate, Ber. Dtsch. Chem. Ges. 1936, 69, 1862–1869.
- 46S. Gembiki, Vladimir Haensel. A Biographical Memoir, Biographical Memoirs, Vol. 88, National Academy of Science, Washington, D.C, 2006.
- 47https://web.archive.org/web/20061230130259/http://www.uop.com/refining/1030.html (Ind. Eng. Chem. 1950, 4, 582).
- 48F. Fischer, H. Tropsch, U.S. Patent 1,746,464, 1926.
- 49N. Zelinsky, Yu. Yuriev, Izv. AN. Ser. Khim. (Russ. Chem. Bull.) 1940, 289–293.
- 50N. Zelinsky, M. Marushkin, Dokl. Akad. Nauk SSSR 1941, 32, 136–139.
- 51N. Zelinsky, Izbrannye trudy (Selected Works), Vol. 2, Izd. AN SSSR, Moscow-Leningrad, 1941, p. 24.
- 52A. A. Balandin, Catalysis and chemical kinetics, Academic Press, New York, 1964.
- 53
- 53aN. Zelinsky, K. Lawrowsky, Ber. Dtsch. Chem. Ges. 1928, 61, 1054–1057;
10.1002/cber.19280610526 Google Scholar
- 53bN. Zelinsky, Ber. Dtsch. Chem. Ges. 1927, 60, 1793–1800;
10.1002/cber.19270600812 Google Scholar
- 53cN. Zelinsky, N. Koslow, Ber. Dtsch. Chem. Ges. 1931, 64, 2130–2135.
10.1002/cber.19310640843 Google Scholar
- 54I. S. Antipin, M. A. Kazymova, M. A. Kuznetsov, A. V. Vasilyev, M. A. Ishchenko, A. A. Kiryushkin, L. M. Kuznetsova, S. V. Makarenko, V. A. Ostrovskii, M. L. Petrov, O. V. Solod, Yu. G. Trishin, I. P. Yakovlev, V. G. Nenaidenko, E. K. Beloglazkina, I. P. Beletskaya, Yu. A. Ustynyuk, P. A. Solov′ev, I. V. Ivanov, E. V. Malina, N. V. Sivova, V. V. Negrebetskii, Yu. I. Baukov, N. A. Pozharskaya, V. F. Traven′, A. E. Shchekotikhin, A. V. Varlamov, T. N. Borisova, Yu. A. Lesina, E. A. Krasnokutskaya, S. I. Rogozhnikov, S. N. Shurov, T. P. Kustova, M. V. Klyuev, O. G. Khelevina, P. A. Stuzhin, A. Yu, Fedorov, A. V. Gushchin, V. A. Dodonov, A. V. Kolobov, V. V. Plakhtinskii, V.Yu. Orlov, A. P. Kriven′ko, O. V. Fedotova, N. V. Pchelintseva, V. N. Charushin, O. N. Chupakhin, Yu. N. Klimochkin, A.Yu. Klimochkina, V. N. Kuryatnikov, Yu. A. Malinovskaya, A. S. Levina, O. E. Zhuravlev, L. I. Voronchikhina, A. S. Fisyuk, A. V. Aksenov, N. A. Aksenov, I. V. Aksenova, Russ. J. Org. Chem. 2017, 53, 1275–1437.
- 55N. D. Zelinsky, Collected Works, Vol. 1, Moscow, 1954, p. 19.
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