Kurzaufsatz
Mixed-Metal MOFs: Unique Opportunities in Metal–Organic Framework (MOF) Functionality and Design
Dr. Mohammad Yaser Masoomi,
Prof. Ali Morsali,
Prof. Amarajothi Dhakshinamoorthy,
Prof. Hermenegildo Garcia,
Dr. Mohammad Yaser Masoomi
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
Search for more papers by this authorCorresponding Author
Prof. Ali Morsali
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
Search for more papers by this authorProf. Amarajothi Dhakshinamoorthy
School of Chemistry, Madurai Kamaraj University, Madurai-, 625 021 India
Search for more papers by this authorCorresponding Author
Prof. Hermenegildo Garcia
Dep. de Quimica y, Instituto Universitario de Tecnologia Quimica (CSIC-UPV), Universitat Politecnica de Valencia, Valencia, 46022 Spain
Search for more papers by this authorDr. Mohammad Yaser Masoomi,
Prof. Ali Morsali,
Prof. Amarajothi Dhakshinamoorthy,
Prof. Hermenegildo Garcia,
Dr. Mohammad Yaser Masoomi
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
Search for more papers by this authorCorresponding Author
Prof. Ali Morsali
Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14155-4838, Tehran, Iran
Search for more papers by this authorProf. Amarajothi Dhakshinamoorthy
School of Chemistry, Madurai Kamaraj University, Madurai-, 625 021 India
Search for more papers by this authorCorresponding Author
Prof. Hermenegildo Garcia
Dep. de Quimica y, Instituto Universitario de Tecnologia Quimica (CSIC-UPV), Universitat Politecnica de Valencia, Valencia, 46022 Spain
Search for more papers by this authorAbstract
Mixed-metal metal–organic frameworks (MM-MOFs) can be considered to be those MOFs having two different metals anywhere in the structure. Herein we summarize the various strategies for the preparation of MM-MOFs and some of their applications in adsorption, gas separation, and catalysis. It is shown that compared to homometallic MOFs, MM-MOFs bring about the opportunity to take advantage of the complexity and the synergism derived from the presence of different metal ions in the structure of MOFs. This is reflected in a superior performance and even stability of MM-MOFs respect to related single-metal MOFs. Emphasis is made on the use of MM-MOFs as catalysts for tandem reactions.
Conflict of interest
The authors declare no conflict of interest.
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