Hoch aktive und belastbare Katalysatoren für die Alkinmetathese†
Dr. Kuthanapillil Jyothish
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Wei Zhang
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (USA)
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (USA)Search for more papers by this authorDr. Kuthanapillil Jyothish
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (USA)
Search for more papers by this authorCorresponding Author
Prof. Dr. Wei Zhang
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (USA)
Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 (USA)Search for more papers by this authorWir danken der NSF (DMR-1055705) und der University of Colorado (“Innovative Seed Grant Program”) für finanzielle Unterstützung.
Graphical Abstract
Gratwanderung: Jüngere Fortschritte bei Alkinmetathese-Katalysatoren beruhen auf der Entwicklung maßgeschneiderten Liganden, die einerseits die Aktivität der Katalysatoren und andererseits ihre Beständigkeit verbessern (siehe Schema; M=W, Mo; R=CR′, N). Wichtige Kriterien sind die Elektrophilie und die Substrat-Bindestellen am Übergangsmetallzentrum.
References
- 1
- 1aF. Pennella, R. L. Banks, G. C. Bailey, J. Chem. Soc. Chem. Commun. 1968, 1548.
- 2
- 2a Handbook of Metathesis, Band 1–3 (Hrsg.: ), Wiley-VCH, Weinheim, 2003;
- 2bR. R. Schrock, C. Czekelius, Adv. Synth. Catal. 2007, 349, 55;
- 2cA. Fürstner, P. W. Davies, Chem. Commun. 2005, 2307;
- 2dW. Zhang, J. S. Moore, Adv. Synth. Catal. 2007, 349, 93;
- 2eM. Mori, Adv. Synth. Catal. 2007, 349, 121.
- 3
- 3aO. Coutelier, A. Mortreux, Adv. Synth. Catal. 2006, 348, 2038;
- 3bR. M. Gauvin, O. Coutelier, E. Berrier, A. Mortreux, L. Delevoye, J.-F. Paul, A.-S. Mamede, E. Payen, Dalton Trans. 2007, 3127.
- 4
- 4aR. R. Schrock, Chem. Rev. 2002, 102, 145;
- 4bR. R. Schrock, Angew. Chem. 2006, 118, 3832;
10.1002/ange.200600085 Google ScholarAngew. Chem. Int. Ed. 2006, 45, 3748.
- 5
- 5aC. E. Laplaza, A. L. Odom, W. M. Davis, C. C. Cummins, J. D. Protasiewicz, J. Am. Chem. Soc. 1995, 117, 4999;
- 5bC. E. Laplaza, C. C. Cummins, Science 1995, 268, 861.
- 6
- 6aA. Fürstner, C. Mathes, C. W. Lehmann, J. Am. Chem. Soc. 1999, 121, 9453;
- 6bA. Fürstner, C. Mathes, C. W. Lehmann, Chem. Eur. J. 2001, 7, 5299.
10.1002/1521-3765(20011217)7:24<5299::AID-CHEM5299>3.0.CO;2-X CAS PubMed Web of Science® Google Scholar
- 7
- 7aW. Zhang, S. Kraft, J. S. Moore, Chem. Commun. 2003, 832;
- 7bW. Zhang, S. Kraft, J. S. Moore, J. Am. Chem. Soc. 2004, 126, 329.
- 8
- 8aW. Zhang, J. S. Moore, Angew. Chem. 2006, 118, 4524; Angew. Chem. Int. Ed. 2006, 45, 4416;
- 8bW. Zhang, J. S. Moore, J. Am. Chem. Soc. 2004, 126, 12796;
- 8cW. Zhang, J. S. Moore, Macromolecules 2004, 37, 3973;
- 8dU. H. F. Bunz, Acc. Chem. Res. 2001, 34, 998.
- 9
- 9aH. Weissman, K. N. Plunkett, J. S. Moore, Angew. Chem. 2006, 118, 599;
10.1002/ange.200502840 Google ScholarAngew. Chem. Int. Ed. 2006, 45, 585;
- 9bH. M. Cho, H. Weissman, S. R. Wilson, J. S. Moor e, J. Am. Chem. Soc. 2006, 128, 14742;
- 9cM. Chabanas, A. Baudouin, C. Coperet, J. M. Basset, J. Am. Chem. Soc. 2001, 123, 2062.
- 10
- 10aB. Haberlag, X. Wu, K. Brandhorst, J. Grunenberg, C. G. Daniliuc, P. G. Jones, M. Tamm, Chem. Eur. J. 2010, 16, 8868;
- 10bS. Beer, C. G. Hrib, P. G. Jones, K. Brandhorst, J. Grunenberg, M. Tamm, Angew. Chem. 2007, 119, 9047;
10.1002/ange.200703184 Google ScholarAngew. Chem. Int. Ed. 2007, 46, 8890;
- 10cX. Wu, M. Tamm, Beilstein J. Org. Chem. 2011, 7, 82.
- 11
- 11aM. Bindl, R. Stade, E. K. Heilmann, A. Picot, R. Goddard, A. Fürstner, J. Am. Chem. Soc. 2009, 131, 9468;
- 11bJ. Heppekausen, R. Stade, R. Goddard, A. Fürstner, J. Am. Chem. Soc. 2010, 132, 11045.
- 12K. Jyothish, W. Zhang, Angew. Chem. 2011, 123, 3497; Angew. Chem. Int. Ed. 2011, 50, 3435.
- 13F. R. Fischer, C. Nuckolls, Angew. Chem. 2010, 122, 7415; Angew. Chem. Int. Ed. 2010, 49, 7257.
Citing Literature
This is the
German version
of Angewandte Chemie.
Note for articles published since 1962:
Do not cite this version alone.
Take me to the International Edition version with citable page numbers, DOI, and citation export.
We apologize for the inconvenience.
