Palladium-Catalyzed Asymmetric [3+3] Cycloaddition of Trimethylenemethane Derivatives with Nitrones†
Ryo Shintani Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorSoyoung Park
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorWei-Liang Duan
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorTamio Hayashi Prof. Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorRyo Shintani Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorSoyoung Park
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorWei-Liang Duan
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorTamio Hayashi Prof. Dr.
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan, Fax: (+81) 75-753-3988
Search for more papers by this authorSupport has been provided in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science, and Technology, Japan (21 COE on Kyoto University Alliance for Chemistry).
Graphical Abstract
Leichte Cyclisierung: Funktionalisierte 1,2-Oxazine sind durch die palladiumkatalysierte asymmetrische [3+3]-Cycloaddition zwischen Trimethylenmethan-Derivaten und Nitronen zugänglich. Der Einsatz eines modifizierten Phosphoramiditliganden liefert diese Verbindungen mit hoher Stereoselektivität (siehe Schema, Cp=Cyclopentadienyl).
Supporting Information
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