Volume 115, Issue 32 pp. 3915-3918
Zuschrift

Templating of Silsesquioxane Cross-Linking Using Unimolecular Self-Organizing Polymers

Eric F. Connor

Eric F. Connor

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Linda K. Sundberg

Linda K. Sundberg

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Ho-Cheol Kim

Ho-Cheol Kim

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Jeroen J. Cornelissen

Jeroen J. Cornelissen

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Teddie Magbitang

Teddie Magbitang

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Phil M. Rice

Phil M. Rice

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Victor Y. Lee

Victor Y. Lee

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Craig J. Hawker

Craig J. Hawker

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Willi Volksen

Willi Volksen

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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James L. Hedrick

James L. Hedrick

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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Robert D. Miller

Robert D. Miller

IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120, USA, Fax: (+1) 408-927-3310

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First published: 13 August 2003
Citations: 19

Partial funding by the National Institute of Science and Technology (NIST) through an ATP cooperative agreement (70NANB8H4013) and the NSF Center for Polymeric Interfaces and Macromolecular Assemblies (CPIMA) is acknowledged. L.K.S. acknowledges partial financial support from JSR Microelectronics. The authors thank Eugene Delenia for expert assistance with TEM studies and Richard Siemens and Lucy Li for their definitive thermal analysis studies.

Graphical Abstract

Sternförmige micellare Polymere dienen als Template für die kontrollierte Umwandlung amorpher wärmehärtender organischer Silsesquioxane in geordnete nanoporöse Materialien für Halbleiterchips (siehe Bild). Die Porengröße hängt allein von der Polymergröße ab, nicht von der Konzentration oder den Herstellungsbedingungen.

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