A Classical Example of a Disappearing Polymorph and the Shortest Intermolecular H⋅⋅⋅H Separation Ever Found in an Organic Crystal Structure†
Petra Bombicz Dr.
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59–67, PBox 17, 1525 Budapest, Hungary, Fax: (+36) 1-325-7554
Search for more papers by this authorMátyás Czugler Dr.
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59–67, PBox 17, 1525 Budapest, Hungary, Fax: (+36) 1-325-7554
Search for more papers by this authorRoland Tellgren Prof. Dr.
Department of Materials Chemistry, The Ångström Laboratory, Uppsala University, PBox 538, SE-751 21 Uppsala, Sweden
Search for more papers by this authorAlajos Kálmán Prof. Dr.
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59–67, PBox 17, 1525 Budapest, Hungary, Fax: (+36) 1-325-7554
Search for more papers by this authorPetra Bombicz Dr.
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59–67, PBox 17, 1525 Budapest, Hungary, Fax: (+36) 1-325-7554
Search for more papers by this authorMátyás Czugler Dr.
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59–67, PBox 17, 1525 Budapest, Hungary, Fax: (+36) 1-325-7554
Search for more papers by this authorRoland Tellgren Prof. Dr.
Department of Materials Chemistry, The Ångström Laboratory, Uppsala University, PBox 538, SE-751 21 Uppsala, Sweden
Search for more papers by this authorAlajos Kálmán Prof. Dr.
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, Pusztaszeri út 59–67, PBox 17, 1525 Budapest, Hungary, Fax: (+36) 1-325-7554
Search for more papers by this authorThe authors express their gratitude to Prof. Jack Dunitz for invaluable discussions. The authors acknowledge Dr. József Kovács, Mr. Csaba Kertész, and Dr. János Madarász (Budapest), Mr. Håkan Rundlöf and Dr. Valéry Baron (Studsvik). P.B. is indebted to the Royal Swedish Academy of Sciences for the support of her stay at the Studsvik Neutron Research Laboratory, Uppsala University.
Graphical Abstract
Taucht nur alle Jubeljahre auf: Neutronen- und Röntgenbeugungsuntersuchungen bei tiefen Temperaturen ergaben ein empfindliches Gleichgewicht zwischen anziehenden und abstoßenden intermolekularen Kräften in den beiden kristallinen Formen von 1,2,3,5-Tetra-O-acetyl-β-D-ribofuranose (zu sehen ist die weniger stabile Form; O: rot, H: blau, C: grau). Sehr kleine intermolekulare H⋅⋅⋅H-Abstände, die nur in der weniger stabilen Kristallform vorliegen, sind für deren Verschwinden maßgeblich.
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