Metal-ion Binding to Self-assembled Monolayers on Surfaces

Alexander Vaskevich

Alexander Vaskevich

Weizmann Institute of Science, Rehorot, Israel

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Israel Rubinstein

Israel Rubinstein

Weizmann Institute of Science, Rehorot, Israel

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First published: 15 December 2007

Abstract

The sections in this article are

  • Introduction
  • Binding of Metal Ions to Functionalized SAMs: General Phenomena and Case Studies
    • Stoichiometry of Surface Metal-organic Complexes
    • Solution-surface Equilibrium
  • SAMs as Metal-ion Receptors
    • Ion Binding to SAMs: Direct Electrochemical Reporting
    • Binding of Electrochemically Inert Ions: Reporting by Redox Reactions of Solution Species
    • Binding of Electrochemically Inert Ions: Reporting by Redox Centers in the SAM
    • Binding of Electrochemically Inert Ions: Application of Electrochemical Impedance Spectroscopy (EIS)
    • Optical Methods for Control and Reporting of Ion Binding to SAMs
  • Bilayers Formed by Metal-organic Coordination
    • Coordinated Organic Bilayers
    • Immobilization of Biological Molecules through Coordination Binding
    • Binding of Macrocycle Molecules

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