This chapter contains sections titled:

• Introduction

• Stille couplings

• Suzuki couplings

• Negishi couplings

• Heck couplings

• Cyanation and Sonogashira reactions

• Carbon–heteroatom coupling reactions

• Asymmetric molybdenum-catalysed allylic alkylations

• Carbonylative couplings

• Outlook

• Acknowledgement

• References