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Application of In Situ Electrochemical-Cell Transmission Electron Microscopy for the Study of Rechargeable Batteries

Wentao Yao

Wentao Yao

Michigan Technological University, Houghton, MI, USA

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Reza Shahbazian-Yassar

Reza Shahbazian-Yassar

University of Illinois at Chicago, Chicago, IL, USA

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First published: 14 March 2019

Abstract

With the capability of direct visualizing the solid–liquid reactions at high resolutions, in situ liquid-cell transmission electron microscopy (TEM) plays an important role in the fundamental studies of rechargeable batteries, including the lithiation behavior of various electrode materials, the striping/plating behavior of lithium metal anode, the formation of solid–electrolyte interfaces, electrolyte degradation behaviors, as well as the formation/dissolution behavior of Li2O2/NaO2 in the metal–air battery cathode. This article summarized the recent progress of in situ electrochemical-cell TEM technique in the battery field by comparing its advantages/disadvantages with traditional open-cell TEM technique as well as other in situ techniques. With the improvement of the chemical analysis capabilities and new holder designs, in situ liquid-cell TEM will see further applications in battery systems beyond lithium-ion.

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