Communication
The First Templated Borogermanate (C2N2H10)2[(BO2.5)2(GeO2)3]: Linkage of Tetrahedra of Significantly Different Sizes
Mike S. Dadachov Dr.,
Kai Sun Dr.,
Tony Conradsson,
Xiaodong Zou Dr.,
Mike S. Dadachov Dr.
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorKai Sun Dr.
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorTony Conradsson
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorXiaodong Zou Dr.
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorMike S. Dadachov Dr.,
Kai Sun Dr.,
Tony Conradsson,
Xiaodong Zou Dr.,
Mike S. Dadachov Dr.
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorKai Sun Dr.
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorTony Conradsson
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorXiaodong Zou Dr.
Structural Chemistry, Stockholm University S-106 91 Stockholm (Sweden) Fax: (+46) 8-16-31-18
Search for more papers by this authorFirst published: 13 October 2000
Citations: 66
This work was supported by the Swedish Natural Science Research Council (NFR).
Abstract
Incorporation of boron into templated germanate frameworks has been achieved for the first time. Clusters of GeO4 three-rings are connected by pairs of BO4 tetrahedra into a two-dimensional framework structure with nine-ring channels (see picture; GeO4: light gray; BO4: dark gray). The structure topology is very similar to that of (NH4)4[(GeO2)3(GeO1.5F3)2]⋅0.67 H2O, although very different types and sizes of polyhedra are present in the structures.
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