Communication

Alkane Carbonylation with Carbon Monoxide on Sulfated Zirconia: NMR Observation of Ketone and Carboxylic Acid Formation from Isobutane and CO

Alexander G. Stepanov Dr.

[email protected]

Group of NMR Spectroscopy for Catalytic Hydrocarbon Conversion and Laboratory for Zeolites and Acid-Base Catalysis Boreskov Institute of Catalysis Siberian Branch of the Russian Academy of Sciences Prospekt Akademika Lavrentieva 5, Novosibirsk 630090 (Russia) Fax: (+7) 3832-34-3056

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Mikhail V. Luzgin Dr.,

Mikhail V. Luzgin Dr.

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Alexey V. Krasnoslobodtsev,

Alexey V. Krasnoslobodtsev

Natural Science Department, Novosibirsk State University ul. Pirogova 2, Novosibirsk 630090 (Russia)

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Vera P. Shmachkova Dr.,

Vera P. Shmachkova Dr.

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Nina S. Kotsarenko Dr.,

Nina S. Kotsarenko Dr.

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Alexander G. Stepanov Dr.,

Alexander G. Stepanov Dr.

[email protected]

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Mikhail V. Luzgin Dr.,

Mikhail V. Luzgin Dr.

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Alexey V. Krasnoslobodtsev,

Alexey V. Krasnoslobodtsev

Natural Science Department, Novosibirsk State University ul. Pirogova 2, Novosibirsk 630090 (Russia)

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Vera P. Shmachkova Dr.,

Vera P. Shmachkova Dr.

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Nina S. Kotsarenko Dr.,

Nina S. Kotsarenko Dr.

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First published: 13 October 2000

https://doi.org/10.1002/1521-3773(20001016)39:20<3658::AID-ANIE3658>3.0.CO;2-C

Citations: 19

This work was supported by grant No. 99-03-32454 from the Russian Foundation for Basic Research (RFBR) and in part by a joint RFBR-INTAS grant (No. 95-0194). The authors sincerely thank Dr. V. N. Sidelnikov for GC-MS analysis.

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Abstract

Coadsorbed water determines the reaction products when isobutane undergoes carbonylation by CO on a sulfated zirconia catalyst at 70°C. This is shown by the results of in situ solid-state ¹³C NMR and ex situ ¹³C high-resolution NMR spectroscopy and by GC-MS analyses. Methyl isopropyl ketone selectively forms in the absence of water, while pivalic acid represents the primary reaction product the presence of coadsorbed water (see scheme).

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Volume39, Issue20

October 16, 2000

Pages 3658-3660

Alkane Carbonylation with Carbon Monoxide on Sulfated Zirconia: NMR Observation of Ketone and Carboxylic Acid Formation from Isobutane and CO

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Alkane Carbonylation with Carbon Monoxide on Sulfated Zirconia: NMR Observation of Ketone and Carboxylic Acid Formation from Isobutane and CO

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