Polysaccharides
Alphons C. J. Voragen,
Claus Rolin,
Beinta U. Marr,
Ian Challen,
Abdelwahab Riad, Rachid Lebbar, Svein Halvor Knutsen,
Alphons C. J. Voragen
Wageningen, Agricultural University, Department of Food Science, Wageningen, The Netherlands
Search for more papers by this authorClaus Rolin
The Copenhagen Pectin Factory Ltd., Lille Skensved, Denmark
Search for more papers by this authorBeinta U. Marr
The Copenhagen Pectin Factory Ltd., Lille Skensved, Denmark
Search for more papers by this authorIan Challen
NutraSweet Kelco, Waterfield, Tadworth, Surrey, United Kingdom
Search for more papers by this authorSvein Halvor Knutsen
Norwegian Food Research Institute, MATFORSK, Norway, 1430 Ås
Search for more papers by this authorAlphons C. J. Voragen,
Claus Rolin,
Beinta U. Marr,
Ian Challen,
Abdelwahab Riad, Rachid Lebbar, Svein Halvor Knutsen,
Alphons C. J. Voragen
Wageningen, Agricultural University, Department of Food Science, Wageningen, The Netherlands
Search for more papers by this authorClaus Rolin
The Copenhagen Pectin Factory Ltd., Lille Skensved, Denmark
Search for more papers by this authorBeinta U. Marr
The Copenhagen Pectin Factory Ltd., Lille Skensved, Denmark
Search for more papers by this authorIan Challen
NutraSweet Kelco, Waterfield, Tadworth, Surrey, United Kingdom
Search for more papers by this authorSvein Halvor Knutsen
Norwegian Food Research Institute, MATFORSK, Norway, 1430 Ås
Search for more papers by this authorAbstract
The article contains sections titled:
1. |
Introduction |
2. |
Analysis and Characterization |
3. |
Pectin |
3.1. |
Occurrence and Structure |
3.2. |
Pectolytic Enzymes |
3.3. |
Production |
3.4. |
Properties |
3.4.1. |
Physical Properties |
3.4.2. |
Gel Properties |
3.4.3. |
Stability and Chemical Reactions |
3.5. |
Analysis |
3.5.1. |
Measurement and Standardization of Gel-Forming Capacity |
3.5.2. |
Chemical Analysis |
3.6. |
Pharmaceutical and Nutritional Characteristics |
3.7. |
Application in the Food Industry |
3.8. |
Market |
4. |
Alginates |
4.1. |
Occurrence |
4.2. |
Production |
4.3. |
Structure |
4.4. |
Properties |
4.5. |
Propylene Glycol (Propane-1,2-diol) Alginate |
4.6. |
Bacterial Alginates |
4.7. |
Analysis |
4.8. |
Applications |
4.9. |
Market |
5. |
Carrageenan |
5.1. |
Structure |
5.2. |
Sources and Raw Materials |
5.3. |
Production |
5.4. |
Analysis |
5.5. |
Properties |
5.6. |
Applications |
5.7. |
Physiological Properties |
6. |
Agar |
6.1. |
Production |
6.2. |
Structure and Gelling Mechanism |
6.3. |
Quick Soluble Agar |
7. |
Gum Arabic |
8. |
Gum Tragacanth |
9. |
Gum Karaya |
10. |
Gum Ghatti |
11. |
Xanthan Gum |
11.1. |
Production |
11.2. |
Structure and Properties |
11.3. |
Analysis |
11.4. |
Applications, Market |
12. |
Gellan Gum |
13. |
Galactomannans |
13.1. |
Structure |
13.2. |
Production |
13.3. |
Properties |
13.4. |
Analysis and Composition of Commercial Preparations |
13.5. |
Derivatives |
13.6. |
Applications |
13.7. |
Market |
14. |
Acknowledgement |
References
- 1 M. Glicksman: Gum Technology in the Food Industry, Academic Press, New York 1969.
- 2 R. L. Whistler, J. N. BeMiller (eds.): Industrial Gums, 2nd ed., Academic Press, New York 1973.
- 3 H. D. Graham (ed.): Food Colloids, AVI, Westport, Connecticut 1977.
- 4 H. Neukom, W. Pilnik: Gelier- und Verdickungsmittel in Lebensmitteln, Forster Verlag, Zürich 1980.
- 5 G. O. Aspinall: The Polysaccharides, vol. 2, Academic Press, New York 1983.
- 6
P. Harris:
Food Gels,
Elsevier Applied Science Publishers,
London
1990.
10.1007/978-94-009-0755-3 Google Scholar
- 7 J. R. Mitchell, D. A. Ledwàrd: Functional Properties of Food Macromolecules, Elsevier Applied Science Publishers, London 1986.
- 8 M. L. Fishman, J. J. Jen: “Chemistry and Functions of Pectin,” ACS Symp. Ser. 310 (1986)
- 9 D. Oakenfull: “Gelling Agents,” CRC Crit. Rev. Food Sci. Nutr. 26 (1987), 1 – 25.
- 10 M. Yalpani: “Industrial Polysaccharides; Genetic Engineering, Structures/Property Relations and Applications,” Prog. Biotechnol. 3 (1987)
- 11 M. Glicksman: Food Hydrocolloids, CRC Press, Boca Raton Fla. 1986.
- 12
R. H. Walter:
The Chemistry and Technology of Pectin,
Academic Press,
New York
1991.
10.1016/B978-0-08-092644-5.50015-7 Google Scholar
- 13 W. Schmolck, E. Mergenthaler: “Beiträge zur Analytik von Polysacchariden, die als Lebensmittelzusatzstoffe verwendet werden,” Z. Lebensm. Unters. Forsch. 152 (1973) 87 – 99.
- 14 M. E. Endean: The Separation and Identification of Polysaccharide Stabilizers, Thickeners and Gums from Foods, Technical circular no. 575, The British Food Manufacturing Industrie Research Association, Leatherhead, Surrey 1974.
- 15 Schweizerisches Lebensmittelbuch, vol. 3, chap. 40, “Gelier- und Verdickungsmittel,” Eidgen. Drucksachen- und Materialzentrale, Bern 1989.
- 16 R. G. Morley, G. O. Phillips, D. M. Power, Analyst (London) 97 (1972) 315 – 319.
- 17 J. E. Scott, D. Glick (eds.): Methods of Biochemical Analysis, Interscience, New York 1960, pp. 145 –197.
- 18
C. Rolin in
R. L. Whistler,
J. N. BeMiller (eds.):
Industrial Gums,
3rd ed.,
Academic Press,
San Diego
1993,
pp. 257 – 293.
10.1016/B978-0-08-092654-4.50014-0 Google Scholar
- 19 R. Ilker, A. S. Szcezesniak: “Structural and chemical bases for texture of plant foodstuffs,” J. Text. Studies. 21 (1990) 1.
- 20 J. P. Van Buren: “The Chemistry of Texture in Fruits and Vegetables,” J. Text. Studies. 10 (1979) 1.
- 21 M. McNeil, A. G. Darvill, S. C. Fry, P. Albersheim, “Structure and Function of the primary Cell Walls of Plants,” Ann. Rev. Biochem. 53 (1984) 625.
- 22 R. R. Selvendran: The Chemistry of Plant Cell Walls, in G. G. Birch, J. Parker (eds.): Dietary Fibre, Applied Sci. Publ., London 1995.
- 23 M. C. McCann, K. Roberts: The Cytoskeletal Basis of Plant Growth and Form, Academic Press, Oxford 1991, pp. 109 – 129.
- 24 C. M. G. C. Renard, H. A. Schols, A. G. J. Voragen, J. F. Thibault, W. Pilnik: “Studies on Apple Protopectin. III. Characterization of the Material Extracted by Pure Polysaccharidases from Apple Cell Walls,” Carbohydr. Polym. 15 (1991) 13.
- 25 C. M. G. C. Renard, A. G. J. Voragen, J. F. Thibault, W. Pilnik: “Comparison between enzymatically and chemically extracted pectins from apple cell walls,” Animal Feed Sci. Technol. 32 (1991) 69.
- 26 J. A. De Vries, F. M. Rombouts, A. G. J. Voragen, W. Pilnik: “Enzymic Degradation of Apple Pectins,” Carbohydr. Polym. 2 (1982) 25.
- 27 R. R. Selvendran: “Development in the Chemistry and Biochemistry of Pectic and Hemicellulosic Polymers,” J. Cell Sci. Suppl. 2 (1985) 51.
- 28 T. P. Kravtchenko, A. G. J. Voragen, W. Pilnik: “Analytical comparison ot three industrial pectin preparations,” Carbohydr. Polym. 18 (1992) 17.
- 29 H. Thier: “Identification and Quantification of Natural Polysaccharides in Food Stuffs,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry 2, Applications of Hydrocolloids, Pergamon Press, Oxford 1984.
- 30 T. P. Kravtchenko, M. Penci, A. G. J. Voragen, W. Pilnik: “Enzymic and chemical degradation of some industrial pectins,” Carbohydr. Polym. 20 (1993) 195.
- 31 R. H. Walter (ed.): The Chemistry and Technology of Pectins, Academic Press, New York 1991, p. 113.
- 32 J.- F. Thibault, C. M. G. C. Renard, M. A. V. Axelos, P. Roger, M.- J. Crepeau: “Studies of the length of homogalacturonic regions in pectins by acid hydrolysis,” Carbohydr. Res. 238 (1993) 271.
- 33 J. A. de Vries: Repeating units in the structure of pectin, in G. O. Phillips, P. A. Williams, D. J. Wedlock (eds.): Gums and Stabilisers for the Food Industry, vol. 4, IRL Press, Oxford 1988, p. 25.
- 34 S. E. Harding, G. Berth, A. Ball, J. R. Mitchell, J. Garcia de la Torre: “The Molecular Weight Distribution and Conformation of Citrus Pectins in Solution Studies by Hydrodynamics,” Carbohydr. Polym. 16 (1991) 1.
- 35 Z. I. Kertesz: The Pectic Substances, Interscience Publishers, New York 1951.
- 36 O. P. Beerh, B. Raghuramaiah, G. V. Krisnamurthy: “Utilization of mango waste: peel as a source of pectin,” J. Food Sci. Technol. 13 (1976) 96.
- 37 R. M. Weightman, C. M. G. C. Renard, J.- F. Thibault: “Structure and properties of the polysaccharides from pea hulls. Part 1: chemical extraction and fractionation of the polysaccharides,” Carbohydr. Polym. 24 (1994) 139.
- 38 M. J. Y. Lin, E. S. Humbert: “Extraction of pectins from sunflowers heads,” Can. Inst. Food Sci. Technol. J. 11 (1978) 75.
- 39 W. J. Kim, F. Sosulski, S. C. K. Lee: “Chemical and gelation characteristics of ammonia-demethylated sunflower pectins,” J. Food Sci. 43 (1978) 1436.
- 40 N. M. Ptitchkina, I. A. Danilova, G. Doxastakis, S. Kasapis, E. R. Morris: “Pumpkin pectin: gel formation at unusually low concentration,” Carbohydr. Polym. 23 (1994) 265.
- 41 EC Proposal for Counsil Directive on Food Additives Other than Colours and Sweeteners (III/3624/91/EM-REV3) 1992.
- 42 G. H. Joseph, A. H. Keiser, E. F. Bryant: “High-polymer ammonia-demethylated pectinates and their gelation,” Food Technol. 3 (1949) 85.
- 43 J. C. E. Reitsma, J.-F. Thibault, W. Pilnik: “Properties of amidated pectins. I. Preparation and characterization of amidated pectins and amidated pectic acids,” Food Hydrocoll. 1 (1986) 121.
- 44 P. E. Christensen: “Methods of Grading Pectin in Relation to the Molecular Weight (Intrinsic Viscosity) of Pectin,” Food Res. 19 (1954) 163.
- 45 A. Kawabata: “Studies on chemical and physical properties of pectic substances from fruits,” Mem. Tokyo Univ. Agr. 19 (1977) 115.
- 46 W. J. Kim, V. N. M. Rao, C. J. B. Smit: “Effect of chemical composition on compressive mechanical properties of low ester pectin gels,” J. Food Sci. 43 (1978) 572.
- 47 H. A. Deckers, C. Olieman, F. M. Rombouts, W. Pilnik: “Calibration and Application of High-Performance Size Exclusion Columns for Molecular Weight Distribution of Pectins,” Carbohydr. Polym. 6 (1986) 361.
- 48 M. L. Fishman, D. T. Gillespie, S. M. Sondey, Y. S. El-Atawy: “Intrinsic Viscosity and Molecular Weight of Pectin Components,” Carbohydr. Res. 215 (1991) 91.
- 49 M. A. V. Axelos, J.- F. Thibault, J. Lefebvre: “Structure of Citrus Pectins and Viscometric Study of their Solution Properties,” Int. J. Biol. Macromol. 11 (1989) 186.
- 50 J.-F. Thibault, M. Rinaudo: “Interactions of mono- and divalent counterions with alkali- and enzyme-deesterified pectins in salt-free solutions,” Biopolymers 24 (1985) 2131.
- 51 C. Garnier, M. A. V. Axelos, J.- F. Thibault: “Phase Diagrams of Pectin-Calcium Systems: Influence of pH, Ionic Strenght, and Temperature on the Gelation of Pectins with Different Degrees of Methylation,” Carbohydr. Res. 240 (1993) 219.
- 52 H. S. Owens, H. Lotzkar, T. H. Schultz, W. D. Maclay: “Shape and Size of Pectinic Acid Molecules Deduced from Viscometric Measurements,” J. Am. Chem. Soc. 68 (1946) 1628.
- 53 G. Berth, H. Anger, F. Linow: “Streulichtphotometrische und Viskosimetrische Untersuchungen an Pektinen in wäßrigen Lösungen zur Molmassenbestimmung,” Nahrung 21 (1977) 939.
- 54 H. Anger, G. Berth: “Gel Permeation Chromatography and the Mark Houwink Relation for Pectins with Different Degrees of Esterification,” Carbohydr. Polym. 6 (1986) 193.
- 55 G. Ravanat, M. Rinaudo: “Investigation on Oligo- and Polygalacturonic Acids by Potentiometry and Circular Dichroism,” Biopolymers 19 (1980) 2209.
- 56 F. Michel, J.- F. Thibault, J.- L. Doublier: “Viscometric and Potentiometric Study of High-Methoxyl Pectins in the Presence of Sucrose,” Carbohydr. Polym. 4 (1984) 283.
- 57 E. Racapé, J.- F. Thibault, J. C. E. Reitsma, W. Pilnik: “Properties of Amidated Pectins. II. Polyelectrolyte Behavior and Calcium Binding of Amidated Pectins and Amidated Pectic Acids,” Biopolymers 28 (1989) 1435.
- 58 I. G. Plaschina, E. E. Braudo, V. B. Tolstoguzov: “Circular-Dichroism Studies of Pectin Solutions,” Carbohydr. Res. 60 (1978) 1.
- 59 A. Cesàro, F. Delben, S. Paoletti: “Thermodynamics of the Proton Dissociation of Natural Polyuronic Acids,” Int. J. Biol. Macromol. 12 (1990) 170.
- 60 M. D. Walkinshaw, S. Arnott: “Conformations and interactions of pectins, I. X-ray diffraction analysis of sodium pectate in neutral and acidified forms,” J. Mol. Biol. 153 (1981) 1055.
- 61 M. J. Gidley, E. R. Morris, E. J. Murray, D. A. Powell, D. A. Rees: “Spectroscopic and stoichiometric characterization of the calcium-mediated association of pectate chains in gels and in the solid state,” J. Chem. Soc. Chem. Commun. 22 (1979) 990.
- 62 FAO Food and Nutrition Papers 34 and 37, Specifications for Identity and Purity of Certain Food Additives. Distribution and Sales Section, FAO, Rome 1986.
- 63 Food Chemicals Codex, 3rd ed., National Academy of Sciences, Washington, D.C. 1992.
- 64 J. N. BeMiller: “Acid-catalyzed hydrolysis of glycosides,” Adv. Carbohydr. Chem. 22 (1967) 25.
- 65 D. A. Powell, E. R. Morris, M. J. Gidley, D. A. Rees: “Conformations and Interactions of Pectins, II. Influence of Residue Sequence on Chain Association in Calcium Pectate Gels,” J. Mol. Biol. 155 (1982) 517.
- 66 P. Albersheim, H. Neukom, H. Deuel: “Splitting of pectin chain molecules in neutral solutions,” Arch. Biochem. Biophys. 90 (1960) 46.
- 67 W. Heri, H. Neukom, H. Deuel, Helv. Chim. Acta 44 (1961) 1939.
- 68 R. Kohn, I. Furda: “Distribution of free carboxyl groups in the molecule of pectin after esterification of pectic and pectinic acid by methanol,” Collect. Czech. Chem. Commun. 34 (1969) 641.
- 69 E. L. Pippen, R. M. McCready, H. S. Owens: “Gelation properties of partially acetylated pectins,” J. Am. Chem. Soc. 72 (1950) 813.
- 70 L. W. Doner: “Analytical methods for determining pectin composition,” A.C.S. Symp. Ser. 310 (1986) 13.
- 71 FAO, Food and Nutrition Paper 52, Addendum 1, Rome 1992, p. 87.
- 72 Food Chemicals Codex, FCC III Monographs, 3rd ed. (including supplements), National Academy Press, Washington D.C. 1981, p. 215.
- 73 EEC, Council Directive 78/663, Off. J. EEC 14 08 78 (plus Updates), 1978.
- 74 Z. I. Kertesz: The Pectic Substances, Interscience, New York 1951.
- 75 A. Plöger: “Conductivity detection of pectin: a rapid HPLC method to analyze degree of esterification,” J. Food Sci. 57 (1992) 1185.
- 76 H.- J. Zhong, M. A. K. Williams, R. D. Keenan, D. M. Goodall, C. Rolin: Carbohydr. Polym. 32 (1997) 27.
- 77 G. Berth: “Studies on the Heterogeneity of Citrus Pectin by Gel Permeation Chromatography on Sepharose 2B/Sepharose 4B,” Carbohydr. Polym. 8 (1988) 105.
- 78 R. C. Jordan, D. A. Brant: “An Investigation of Pectin and Pectic Acid in Dilute Aqueous Solution,” Biopolymers 17 (1978) 2885.
- 79
S. Sawayama,
A. Kawabata,
H. Nakahara,
T. Kamata:
“A Light Scattering Study on the Effects of pH on Pectin Aggregation in Aqueous Solution,”
Food Hydrocoll.
2
(1988)
3.
10.1016/S0268-005X(88)80035-3 Google Scholar
- 80 R. H. Walter, H. L. Matias: “Pectin Aggregation Number by Light Scattering and Reducing End-Group Analysis,” Carbohydr. Polym. 15 (1991) 33.
- 81 W. D. Holloway, C. Tasman-Jones, K. Maher: “Pectin digestion in humans,” Am. J. Clin. Nutr. 37 (1983) 253.
- 82 E. C. Titgemeyer, L. D. Burquin, G. C. Fahey, Jr., K. A. Garleb: “Fermentability of various fiber sources by human fecal bacteria in vitro,” Am. J. Clin. Nutr. 53 (1991) 1418.
- 83 M. Nyman, N.- G. Asp: “Fermentation of dietary fibre components in the rat intestinal tract,” Br. J. Nutr. 47 (1982) 357.
- 84 M. Nyman, N.- G. Asp, J. Cummings, H. Wiggins: “Fermentation of dietary fiber in the intestinal tract: comparison between man and rat,” Brit. J. Nutr. 55 (1986) 487.
- 85 J. J. Doesburg: “Pectic Substances in Fresh and Preserved Fruits and Vegetables,” I.B.V.T. Communication no. 25, Sprenger Institute, Wageningen 1965.
- 86 R. A. Baker: “Potential Dietary Benefits of Citrus Pectin and Fiber,” Food Technol. (1994) Nov., 133.
- 87 A. Siddhu, S. Sud, R. L. Bijlani, M. G. Karmarkar, U. Nayar: “Nutrient interaction in relation to glycaemic and insulaemic response,” Indian. J. Physiol. Phamacol. 36 (1992) 21 – 28.
- 88 D. J. A. Jenkins, et al.: “Pectin and complications after gastric surgery: normalisation of postprandial glucose and endocrine responses,” Gut 21 (1980) 574.
- 89 S. E. Schwartz, R. A. Levine, A. Singh, J. R. Scheidecker, N. S. Track: “Sustained Pectin Ingestion Delays Gastric Emptying,” Gastroenterology 83 (1982) 812.
- 90 S. Satchithanandam, M. Vargofcak-Apker, R. J. Calvert, A. R. Leeds, M. M. Cassidy: “Alteration of gastrointestinal mucin by fiber feeding in rats,” J. Nutr. 120 (1990) 1179.
- 91 C. D. Lorenzo, C. M. Williams, F. Hajnal, J. E. Valenzuela: “Pectin Delays Gastric Emptying and Increases Satiety in Obese Subjects,” Gastroenterology 95 (1988) 1211.
- 92 D. M. Zimmaro, et al.: “Isotonic Tube Feeding Formula Induces Liquid Stool in Normal Subjects: Reversal by Pectin,” J. Parenteral and Enteral Nutr. 13 (1989) 117.
- 93 X.-B. Sun, T. Matsumoto, H. Yamada: “Anti-Ulcer Activity and Mode of Action of the Polysaccharide Fraction from the Leaves of Panax ginseng,” Planta Med. 58 (1993) 432.
- 94 H. Yamada, M. Hirano, H. Kiyohara: “Partial structure of an anti-ulcer pectic polysaccharide from the roots of Bupleurum falcatum L.,” Carbohydr. Res. 219 (1991) 173.
- 95 X.-B. Sun, T. Matsumoto, H. Yamada: “Effects of a Polysaccharide Fraction from the Roots of Bupleurum falcatum L. on Experimental Gastric Ulcer Models in Rats and Mice,” J. Pharm. Pharmacol. 43 (1991) 699.
- 96 A. Kawabata: Studies on Chemical and Physical Properties of Pectic Substances from Fruits, Memoirs of the Tokyo University of Agriculture XIX, 1977, pp. 115 – 200.
- 97 L. M. Drews, C. Kies, H. M. Fox: “Effect of dietary fiber on copper, zinc, and magnesium utilization by adolescent boys,” Am. J. Clin. Nutr. 32 (1979) 1893.
- 98 K. Y. Lei, M. W. Davis, M. M. Fang, L. C. Young: “Effect of pectin on zinc, copper and iron balances in humans,” Nutr. Rep. Int. 22 (1980) 459.
- 99 J. H. Cummings, et al.: “The digestion of pectin in the human gut and its effect on calcium absorption and large bowel function,” Br. J. Nutr. 41 (1979) 477.
- 100 P.- E. Glahn: “Hydrocolloid stabilization of protein suspensions at low pH,” Prog. Fd. Nutr. Sci. 6 (1982) 171.
- 101
A. Parker,
P. Boulenguer,
T. P Kravtchenko:
Effect of the addition of high methoxyl pectin on the rheology and colloidal stability of acid milk drinks, in
K. Nishinari,
E. Doi (eds.):
Food Hydrocolloids, Structures, Properties and Functions,
Plenum Press,
New York
1994,
p. 307.
10.1007/978-1-4615-2486-1_48 Google Scholar
- 102 P.- E. Glahn, C. Rolin: “Casein-pectin interaction in sour milk beverages,” Food Ingred. Eur. Conf. Proc. 1994, 252.
- 103 B. U. Nielsen: Fiber-Based Fat Mimetics: Pectin, in S. Roller, S. Jones (eds.): Handbook of Fat Replacers, CRC Press, Boca Raton FL, 1996, p. 161.
- 104 W. Pilnik, P. Zwiker: “Pektine,” Gordian 70 (1970) 202 – 204, 252 – 257, 302 – 305, 343 – 346.
- 105 D. B. Nelson, C. J. B. Smit, R. R. Wiles in H. D. Graham (ed.): Food Colloids, Avi, Westport, Connecticut 1977, p. 418.
- 106
C. Rolin,
J. De Vries in
P. Harris (ed.):
Food Gels,
Elsevier Applied Science,
London
1990,
pp. 401 – 434.
10.1007/978-94-009-0755-3_10 Google Scholar
- 107 G. O. Aspinall in J. Preiss (ed.): The Biochemistry of Plants, vol. 3, Academic Press, New York 1980, p. 473.
- 108 J. N. BeMiller, ACS Symp. Ser. 310 (1986) 12.
- 109 J. K. Pederson in R. L. Davidson (ed.): Handbook of Water Soluble Gums and Resins, Chap. 15 – 1, McGraw-Hill, New York 1980.
- 110 S. Hojgaard Christensen: “Pectins” in M. Glicksman (ed.): Food Hydrocolloids, vol. 3, CRC Press, Boca Raton, Fla. 1986, p. 205.
- 111 W. Pilnik: “Pectin – a Many Splendoured Thing” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry 5, IRL Press, Oxford 1990, pp. 209 – 221.
- 112 H. Braconnot, Ann. Chim. Phys. Ser. 2 28 (1825) 173 – 178.
- 113 W. Pilnik, A. G. J. Voragen: “Pectic Substances and Other Uronides,” in A. C. Hulme (ed.): The Biochemistry of Fruits and their Products, vol. 1, Academic Press, London 1970, pp. 53 – 87.
- 114 F. M. Rombouts, W. Pilnik: “Pectic Enzymes” in A. H. Rose, (ed.): Economic Microbiology, vol. 5, “Enzymes and Enzymic Conversions,” Academic Press, London 1980, pp. 225 – 280.
- 115 A. G. J. Voragen, W. Pilnik: “Pectin-Degrading Enzymes in Fruit and Vegetable Processing,” ACS Symp. Ser. 389 (1989) 93 – 115.
- 116 W. Pilnik, A. G. J. Voragen: “The Significance of Endogenous and Exogenous Pectic Enzymes in Fruit and Vegetable Processing” in P. F. Fox (ed.): Food Enzymology, vol. 1, Elsevier Applied Science, London 1991, pp. 303 – 337.
- 117 C. D. May: “Industrial Pectins: Sources, Production and Application,” Carbohydr. Polymers 12 (1990) 79 –90.
- 118 E. M. McComb, R. M. McCready, Anal. Chem. 29 (1957) 819 – 821.
- 119 S. C. Frey: “Cross-Linking of Matrix Polymers in the Growing Cell Wall of Angiosperms,” Ann. Rev. Plant. Physiol. 37 (1986) 165 – 186.
- 120 D. H. Northcote, ACS Symp. Ser. 310 (1986) 134.
- 121 L. Rexova-Benkova, O. Markovic, Adv. Carbohyd. Chem. Biochem. 33 (1976) 101 – 130.
- 122 H. A. Schols et al., Carbohydr. Res. 206 (1990) 105 –115.
- 123
M. J. F. Searle-van Leeuwen
et al.,
Eur. J. Appl. Microbiol. Biotechnol.
38
(1992)
347 – 349.
10.1007/BF00170084 Google Scholar
- 124 W. Pilnik: “Pektine” in R. Heiss (ed.): Lebensmitteltechnologie, Springer Verlag, Berlin 1988, pp. 228 – 234.
- 125 M. A. Joslyn, G. de Luca, J. Colloid Sci. 12 (1957) 108 – 130.
- 126 M. Manabe, Nippon Nogei Kagaku Kaishi 45 (1971) no. 4, 195 – 199.
- 127 Sunkist Growers, US 1 332 985, 1971.
- 128 California Fruit Growers Exchange, US 2 480 710, 1949.
- 129 W. J. Kim, C. J. B. Smit, V. N. M. Rao, J. Food Sci. 43 (1978) 74 – 78.
- 130 W. Pilnik, A. G. J. Voragen: “Gelling Agents (Pectins) from Plants for the Food Industry,” Adv. Plant Cell Biochem. Biotechnol. 1 (1992) 219 – 270.
- 131 W. Pilnik, R. A. MacDonald, Gordian 68 (1968) 531 – 535.
- 132 M. Byland, A. Donutzhuber, Sven. Papperstidn. 15 (1968) 505 – 508.
- 133 T. P. Kravtchenko, I. Arnould, A. G. J. Voragen, W. Pilnik, Carbohyd. Polym. (in press).
- 134 G. H. Joseph, A. H. Kieser, E. F. Bryant, Food. Technol (Chigago) 3 (1949) 85 – 90.
- 135 M. Manabe, Nippon Nogie Kogaku Kaishi 45 (1971) no. 9, 417 – 422.
- 136 F. M. Rombouts, A. K. Wissenburg, W. Pilnik, J. Chromatogr. 168 (1979) 151 – 161.
- 137 W. Somers, J. Visser, F. M. Rombouts, K. van t'Riet: “Developments in Downstream Processing of (Poly)saccharide Converting Enzymes,” J. Biotechnol. 11 (1989) 199 – 222.
- 138 H. Neukom, Schweiz. Landwirtsch. Forsch. 2 (1963) 112 – 122.
- 139 H. F. Launer, Y. Tomimatsu, Anal. Chem. 31 (1959) no. 9, 1569 – 1574.
- 140 D. A. Rees, Adv. Carbohydr. Chem. Biochem. 24 (1969) 267 – 332.
- 141 D. A. Rees, E. R. Morris, D. Thom, J. K. Madden in G. O. Aspinall (ed.): Polysaccharides, vol. 1, Academic Press, New York 1982, pp. 195 – 290.
- 142 D. A. Rees, A. W. Wight, J. Chem. Soc. B 1971, 1366.
- 143 D. Oakenfull, A. Scott: “New Approaches to the Study of Food Gels,” in G. O. Philips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, vol. 3, Elsevier Applied Science Publishers 1985, London, pp. 465 – 475.
- 144 E. R. Morris et al., Int. J. Biol. Macromol. 2 (1980) 237.
- 145 D. Thom, I. C. M. Dea, E. R. Morris, D. A. Powell, Progr. Fd. Nutr. Sci. 6 (1982) 87 – 108.
- 146 V. J. Morris in J. R. Mitchell, D. A. Ledward (eds.): Functional Properties of Food Macromolecules, Elsevier, Amsterdam 1986, pp. 121 – 169.
- 147 Racapé et al., Biopolymers 28 (1989) 1435 – 1448.
- 148 B. Lockwood, Food Process. Ind. 41 (1972) 493, 47 –51.
- 149 I. F. T. Pectin Standardization, Food Technol. (Chicago) 13 (1959) 496 – 500.
- 150 P. C. Crandall, L. Wicker: “Pectin Internal Gel Strength: Theory, Measurement and Methodology,” ACS Symp. Ser. 310 (1986) 79 – 102.
- 151 M. J. H. Keijbets, W. Pilnik, Potato Res. 17 (1974) 169 – 177.
- 152 M. F. Katan, P. v.d. Bovenkamp, Basic Clin. Nutr. 3 (1981) 217 – 239.
- 153 R. F. McFeeters, S. A. Armstrong, Anal. Biochem. 139 (1984) 212 – 217.
- 154 L. G. Bartolome, J. E. Hoff, J. Agric. Food Chem. 20 (1972) 266 – 270.
- 155 M. A. Litchman, R. P. Upton, Anal. Chem. 44 (1972) 1495 – 1497.
- 156 G. C. Cochrane, J. Chromatogr. Sci. 13 (1975) 440 –447.
- 157 E. L. Pippen, R. M. McCready, H. S. Owen, Anal. Chem. 22 (1950) 1457 – 1458.
- 158 A. G. J. Voragen, H. A. Schols, W. Pilnik, Food Hydrocolloids 1 (1986) 65 – 70.
- 159 FAO Food and Nutrition Paper 31/2 (Rome) 1984, p. 75.
- 160 J. C. E. Reitsma, W. Pilnik: “Analysis of Mixtures of Pectins and Amidated Pectins,” Carbohydr. Polym. 10 (1989) 315 – 319.
- 161 T. Bitter, H. M. Muir, Anal. Biochem. 4 (1962) 330.
- 162 N. Blumenkranz, G. Asboe-Hansen, Anal. Biochem. 54 (1973) 484 – 489.
- 163 T. M. C. C. Filisetti-Cozzi, N. C. Carpita, Anal. Biochem. 197 (1991) 157 – 162.
- 164 T. P. Kravtchenko, A. G. J. Voragen, W. Pilnik, Carbohydr. Polym. 18 (1992) 17 – 25.
- 165 R. R. Selvendran, P. Ryden: “Isolation and Analysis of Plant Cell Walls,” in P. M. Dey, J. B. Harborne (eds.): Methods in Plant Biochemistry 2 (1990) 549 –579.
- 166 C. M. G. C. Renard, A. G. J. Voragen, J. F. Thibault, W. Pilnik, Carbohydr. Polym. 12 (1990) 9 –25.
- 167 H. U. Endress: in (12), pp. 251 – 267.
- 168 P. A. Sanderson, J. Baird: “Industrial Utilization of Polysaccharides” in G. O. Aspinall (eds.): The Polysaccharides, vol. 2, Academic Press, London 1983, pp. 411 – 490.
- 169 T. J. Painter in G. O. Aspinall (ed.): The Polysaccharides, vol. 2, Academic Press, London 1983, pp. 257 – 275.
- 170 P. A. Sandford in R. R. Colwell, E. R. Pariser, R. J. Sinskey (eds.): Biotechnology of Marine Polysaccharides Hemisphere, Washington 1985, pp. 454 – 516.
- 171
W. J. Sime. Alignates in
P. Harris (ed.):
Food Gels,
Elsevier Applied Science Press,
New York
1990,
pp. 53 – 78.
10.1007/978-94-009-0755-3_2 Google Scholar
- 172 W. Pilnik, A. G. J. Voragen: “Pektine und Alginate” in H. Neukom and W. Pilnik (eds.): Gelier- und Verdickungsmittel in Lebensmitteln, Forster Verlag, Zürich 1980, pp. 67 – 94.
- 173 E. Percival, R. H. McDowell: “Algal Polysaccharides,” Methods in Plant Biochemistry 2 (1990) 523 – 548.
- 174 V. J. Chapman: Seaweeds and Their Uses, 2nd ed., Methuen & Co. Ltd., London 1970.
- 175 A. Haug: “Composition and Properties of Alginates,” Report no. 30, Norwegian Institute for Seaweed Research, Trondheim 1964.
- 176 E. C. C. Stanford, GB 142, 1881.
- 177 F. G. Fischer, H. Dörfel, Hoppe Seyler's Z. Physiol. Chem. 302 (1955) 186 – 203.
- 178 A. Haug, B. Larsen, O. Smidsrod, Acta Chem. Scand. 21 (1967) 691 – 704.
- 179 W. A. P. Black, J. Mar. Biol. Assoc. U.K. 29 (1950) 45 – 72.
- 180
H. A. Hoppe,
O. J. Schmid,
Bot. Mar. Suppl.
3
(1962)
16 – 66.
10.1515/botm.1962.3.s1.16 Google Scholar
- 181 A. Haug, B. Larsen, Acta Chem. Scand. 16 (1962) 1908 – 1918.
- 182 A. Penman, G. R. Sanderson, Carbohydr. Res. 25 (1972) 273 – 285.
- 183 D. F. Pindar, C. Bucke, Biochem. J. 152 (1975) 617 – 622.
- 184
G. Skjäk-Break,
B. Larsen,
Carbohydr. Res.
139
(1985)
273 – 283.
10.1016/0008-6215(85)90026-6 Google Scholar
- 185 Marine Colloids, US 2 128 551, 1938.
- 186 Kelco, US 2 036 934, 1936.
- 187 A. B. Steiner, W. H. McNeely, US 2 494 911, 1950.
- 188 A. P. Imeson in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry 2, Pergamon Press, Oxford 1984, p. 189.
- 189 A. Haug, B. Larsen, O. Smidsrod, Acta Chem. Scand. 20 (1966) 183 – 190.
- 190 A. Haug, B. Larsen, O. Smidsrod, Acta Chem. Scand. 21 (1967) 2859 – 2870.
- 191 J. Preiss, G. Ashwell, J. Biol. Chem. 237 (1962) 309 – 316.
- 192 M. Jefferies, G. Pass, G. O. Phillips, J. Sci. Fd. Agric. 28 (1977) 173 – 179.
- 193 O. Smidsrod, Faraday Discuss. Chem. Soc. 57 (1974) 263.
- 194 D. Thom, I. C. M. Dea, E. R. Morris, D. A. Powell, Progr. Food Nutr. Sci. 6 (1982) 97.
- 195 K. Taft, Progr. Food Nutr. Sci. 6 (1982) 89.
- 196 H. A. Schols, Analyt. Biochem. (in press).
- 197 H. Grasdalen, Carbohydr. Res. 118 (1983) 225 – 260.
- 198 J. S. Craigie, E. R. Morris, D. A. Rees, D. Thom, Carbohydr. Polym. 4 (1984) 237 – 252.
- 199 G. A. Towle in (281), pp. 237 – 252.
- 200 J. K. Pedersen in (283), pp. 113 – 133.
- 201 N. F. Stanley in (285), pp. 79 – 119.
- 202 Marine Colloids, US 3 094 517, 1963.
- 203 O. Smidsrod, B. Larsen, A. Pernas, A. Haug, Acta Chem. Scand. 21 (1967) 2585 – 2598.
- 204 C. J. Lawson, D. A. Rees, Nature (London) 227 (1970) 390 – 395.
- 205 E. R. Morris, D. A. Rees, G. R. Robinson, J. Mol. Biol. 138 (1980) 349.
- 206 O. Smidsrod, H. Grasdalen, Carbohydr. Polym. 2 (1982) 270.
- 207 I. C. M. Dea et al., Carbohydr. Res. 57 (1977) 249–272.
- 208 B. V. McCleary, Carbohydr. Res. 71 (1977) 249.
- 209
E. R. Morris,
(1990) In
Food Gels,
(Ed P. Harris),
Applied Science Publishers,
London
, pp.
291–359.
10.1007/978-94-009-0755-3_8 Google Scholar
- 210 Marinalg International, world association of seaweed processors, Paris, www.marinalg.org.
- 211 E. Percival, R. H. Mc Dowel, Algal Polysaccharides, in P. M. Dey, J. B. Harborne (eds.): Plant Biochemistry, Vol. 2, Carbohydrates, Academic Press, New York 1990, pp. 536 – 537.
- 212 H. H. Selby, W. H. Wynne, Agar in Industrial Gum., in R. L. Whistler (ed.): Polysaccharides and Their Derivatives, 2nd ed., Academic Press, New York 1973, pp. 29 – 48.
- 213
C. Araki,
J. Chem. Japan
58
(1973)
1338.
10.1246/nikkashi1921.58.12_1338 Google Scholar
- 214 C. Araki, Bull. Chem. Soc. Japan 29 (1956) 543.
- 215 C. Araki, S. Hirase, Bull. Chem. Soc. Japan 33 (1960) 291.
- 216 C. Araki, K. Arai, Bull. Chem. Soc. Japan 30 (1957) 287.
- 217 M. Duckwork, K. C. Hong, W. Yaphe, Carbohydr. Res. 18 (1971) 1 – 9.
- 218 C. Araki, Proc. 5th Intern. Seaweed Symp., Pergamon Press, Oxford 1966, p. 3.
- 219 S. Hirase, Bull. Chem. Soc. Japan 30 (1957) 68.
- 220 M. Duckwork, W. Yaphe, Carbohydr. Res. 16 (1971) 189.
- 221
K. B. Guisely,
Carbohydr. Res.
13
(1970)
247 – 256.
10.1016/S0008-6215(00)80831-9 Google Scholar
- 222 D. A. Rees, Chem. Ind. (1972) 630 – 636.
- 223 M. Glicksman, Polysaccharides in Food, ed. J. M. V and Mitchell, J. R., In Blanshard (1979) 185 – 24, Butterworths, London.
- 224 A. Hayashi, Polym. J. 9 (1977) 219 – 225.
- 225 A. Hayashi, Polym. J. 10 (1978) 485 – 494.
- 226 A. Hayashi, Polym. J. 12 (1980) 447 – 453.
- 227 J. P. Flory, Proc. R. Soc. London. Ser. A 234 (1956) 73.
- 228 E. Pines, W. Prins Macromolecules 6 (1973) no. 6 888 – 895.
- 229 D. A. Rees, Adv. Carbohyd. Chem. Biochem. 24 (1969) 267.
- 230 D. A. Rees, J. Chem. Soc. (1961) 5168.
- 231 C. R. Williams: “The Processing of Gum Arabic to give Improved Functional Properties,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 37 – 40.
- 232 A. P. Imeson: “Exudate Gums,” in A. Imseon (ed.): Thickening and Gelling Agents for Food, Blackie Academic and Professional, London 1992, pp. 66 – 97.
- 233 A. M. Stephen: “Structure and Properties of Exudate Gums,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 3 – 16.
- 234
S. Conolly,
J. C. Fenyo,
M. C. Vandevelde,
Food Hydrocolloids
1
(1987)
477 – 480.
10.1016/S0268-005X(87)80045-0 Google Scholar
- 235 J. C. Fenyo, M. C. Vandevelde: “Physico-Chemical Properties of Gum Arabic in Relation to Structure,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabiliserer for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 17 – 23.
- 236 P. A. Williams, G. O. Phillips, R. C. Randall: “Structure-Relationships of Gum Arabic,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 25 – 36.
- 237 D. M. W. Anderson, Food Hydrocolloids 2 (1988) 417 – 423.
- 238 G. O. Aspinall, V. P. Bhavanadan, T. B. Christensen, J. Chem. Soc. (1965) 2677 – 2684.
- 239 B. Urlacher, B. Dalbe: “Xanthan Gum,” in A. Imeson (ed.): Thickening and Gelling Agents for Food, Blackie Academic and Professional, London 1992, pp. 202 – 226.
- 240 A. R. Jeanes, J. E. Pittsley, F. R. Santi, J. Appl. Polymer Sci. 5 (1961) 519 – 526.
- 241 P. Delest: “Fermentation Technology of Microbial Polysaccharides,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 301 – 313.
- 242 A. A. Lawrence: Edible Gums and Related Substances, Noyes Data Corp., Park Ridge, N.J. 1973.
- 243 P. E. Janson, L. Keene, B. Lindberg, Carbohydr. Res. 45 (1975) 275 – 282.
- 244
R. Moorhouse,
M. D. Walkinshaw,
S. Anott:
Xanthan gum – molecular conformation and interactions, in
P. A. Sandford (ed.):
Extracellular Microbial Polysaccharides. ACS Symposium Series, No. 45.:
American Chemical Society,
Washington, D.C.
1977,
pp. 90 – 102.
10.1021/bk-1977-0045.ch007 Google Scholar
- 245 R. Moorhouse, in A. P. Imeson (ed.): Thickening and Gelling Agents for Food, Chap. 9, Blackie A & O, Glasgow 1992, pp. 202 – 226.
- 246 M. R. Betlach et al.: “Genetic Engineering, Sturcture/Property Relations and Applications,” in M. Yalpani (ed.): Industrial Polysaccharides, Elsevier, Amsterdam 1987, pp. 35 – 50.
- 247 D. J. Petit: Xanthan gum, in M. Glicksman (ed.): Food Hydrocolloids, vol. 1, CRC Press, Boca Raton, FL 1982, pp. 127 – 149.
- 248 P. J. Whitcomb, C. W. Makosko, J. Rheol. 22 (1978) no. 5, 493 – 505.
- 249 Whitcomb, C. W. Makosko, “Rheology of xanthan gum solutions,” J P.J. Rheol. 22 (1978) no. 5, 493 – 505.
- 250 Kelco Co.: “Xanthan gum Keltrol/Kelzan, in Natural Biopolysaccharides for Scientific Water Control,” 2nd ed., Kelco Co., San Diego, CA 1975.
- 251 R. A. Speers, M. A. Tung: “Concentration and temperature dependence of flow behaviour of xanthan gum dispersions,” J. Food Sci. 51 (1986) no. 1, 96 – 98, 103.
- 252 B. Launay, J. L. Doublier, G. Cuvelier, in J. R. Mitchell and D. A. Ledward (eds.): Functional Properties of Macromolecules, Elsevier Applied Science, London 1986, pp. 1 – 78.
- 253
W. H. McNeely,
K. S. Kang in
R. J. Whistler,
N. J. BeMiller (eds):
Industrial Gums,
Academic Press,
New York
1973,
pp. 473 – 521.
10.1016/B978-0-12-746252-3.50026-5 Google Scholar
- 254 A. R. Jeanes, J. E. Pittsley, F. R. Samtis: “Polysaccharide B-1459; a new hydrocolloid polyelectrolyte produced from glucose by bacterial fermentation,” J. Appl. Polym. Sci. 5 (1961) 519 – 526.
- 255 E. R. Morris et al.: “Order – disorder transition for a bacterial polysaccharide in solution: a role for polysaccharide conformation in recognition between Xanthomonas pathogen and its plant host,” J. Mol. Biol. 110 (1977) no. 1, 1 – 16.
- 256 M. Rinaudo, M. Milos, Int. J. Biol. Macromol. 2 (1980) 45 – 48.
- 257 G. A. R. Carnie: “Evaluation of a new polysaccharide gum,” Aust. J. Pharm. 45 (1964) no. 19, 580 – 583.
- 258 I. T. Norton et al., J. Mol. Biol. 175 (1984) 371.
- 259 V. J. Morris, Food Biotechnol. 4 (1990) 45 – 57.
- 260 V. J. Morris: “Science, Structure and Applications of Microbial Polysaccharides,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 315 – 328.
- 261 A. W. Thomas, H. A. Murray: “Gum arabic,” J. Phys. Chem. 32 (1928) no. 6, 676 – 697.
- 262 US 3 413 125, 1971 (H. R. Schuppner).
- 263 US 3 721 571, 1973 (M. Glicksman, H. E. Farks).
- 264 R. O. Mannion et al.: “Xanthan/locust bean gum interactions at room temperature,” Carbohydr. Polym. 19 (1992) no. 2, 91 – 97.
- 265 P. B. Fernandez: “Influence of galactomannan on the structure and thermal behaviour of xanthan/galactomannan mixtures,” J. Food. Eng. 2 (1995) 269 – 283.
- 266 H. Luyten, W. Kloek, T. Van Vliet: “Yielding behaviour of mixtures of xanthan and enzyme-modified galactomannans,” Food Hydrocolloids 8 (1994) no. 5, 431 – 440.
- 267 B. Dalbe: Interactions between xanthan gum and konjac mannan, in G. O. Phillips, D. J. Williams (eds.): Gums and Stabilisers for the Food Industry, vol. 6, Oxford University Press, Oxford 1992 pp. 201 – 208.
- 268 G. R. Sanderson: “The interaction of xanthan gum in food systems,” Prog. Food. Nut. Sci. 6 (1982) 77 – 87.
- 269 G. R Sanderson: “Gellan Gum,” in (285) , pp. 201 –232.
- 270 W. Gibson: “Gellan Gum,” in A. Imeson (ed.): Thickening and Gelling Agents for Food, Blackie Academic and Professional, London 1992, pp. 227 – 249.
- 271 K. S. Lang et al.: “Agar-like polysaccharide produced by Pseudomonas species: production and basic properties,” Appl. Environ. Microbiol. 43 (1982) 1086.
- 272 “Gellan Gum: Multifunctional Polysaccharide for Gelling and Texturising,” NutraSweet Kelco publication, 1994.
- 273 H. Grasdalen, O. Smidsrod: “Gelation of gellan gum,” Carbohydr. Polym. 7 (1987) 371.
- 274 M. S. Kuo, A. Dell, A. J. Mort: “Identification and location of L-glycerate, an unusual substituent in gellan gum,” Carbohydr. Res. 156 (1968) 173.
- 275 C. Upstill, E. D. T. Atkins, P. T. Atwool: “Helical conformations of gellan gum,” Int. J. Biol. Macromol. 8 (1986) 275.
- 276 R. Chandrasekaran, A. Radha, V. G. Thailambal: “Roles of potassium ions, acetyl and L-glyceryl groups in native gellan double helix: an x-ray study,” Carbohydr. Res. 224 (1992) 1.
- 277 R. Chandrasekaran, R. P. Millane, S. Arnott: “Crystal structure of gellan,” Carbohydr. Res. 175 (1988) 1.
- 278 R. Chandrasekaran, L. C. Puigjaner, K. L. Joyce, S. Arnott: “Cation interactions in gellan: an x-ray study of the potassium salt,” Carbohydr. Res. 181 (1988) 23.
- 279 R. Chandrasekaran, V. G. Thilambal, Carbohydr. Polym. 12 (1990) no. 4, 431 – 442.
- 280 G. R. Sanderson, R. C. Clark: “Gellan Gum”, Food Technol. 37 (1983) 63.
- 281 G. R. Sanderson, V. L. Bell, R. C. Clark, D. Ortega: The texture of gellan gum gels, in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 4th ed., IRL Press, Oxford 1988, p. 219.
- 282 G. R. Sanderson, V. L. Bell, D. Ortega: “A comparison of gellan gum, agar, ϰ-carageenan and algin,” Cereal Foods World 34 (1989) 991.
- 283 G. Owen: Gellan-gum quick setting gelling systems, in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, vol. 5, IRL Press, Oxford 1989, pp. 345 – 349.
- 284 R. C. Clark: Flavour and texture factors in model gel systems, in A. Turner (ed.): Food Technology International Europe, Sterling Publications International, London 1990, pp. 272 – 277.
- 285 US 6027 930115, 1994 (W. F. Chalupa, G. R. Sanderson).
- 286
A. Nissinovitch,
N. Peleg,
E. Mey-Tal:
“Continuous monitoring of changes in shrinking gels,”
Lebensm. Wissen. Tech.
28
(1995)
no. 3,
347 – 349.
10.1016/S0023-6438(95)94740-X Google Scholar
- 287 C. K Darty: “Applications of gellan gum as a fining agent in alcoholic beverages,” Res. Disclosure, No. 348, 256 (1993).
- 288 W. Gibson et al.: “Production of low calorie (low joule) or sugar-free jelly sweets using polydextrose and gellan gum, where final total solids exceeds 80 %,” Res. Disclosure, No. 361, 276–7 (1994).
- 289 “Gellan Gum: a stabiliser of many means,” Prepared Foods 160 (1995) no. 6, 125.
- 290 J. Giese: “Developments in beverage additives,” Food Technol. 49 (1995) no. 5, 63 – 65, 68 – 70, 72.
- 291 EP-A 0 473 854 A1, 1992 (I. T. Norton).
- 292 V. L. Bell et al.: “Use of gellan gum to prepare gels that can be dried and subsequently rehydrated to their original shape,” Res. Disclosure, No 345, 42 (1993).
- 293 Toxicological evaluation of certain food additives, WHO Food Additives Series 28, World Health Organisation, Geneva 1991.
- 294 Reports of the Scientific Committee for Food 26th Series, Commission of the European Committees, Report EUR 13913, Luxemburg 1992.
- 295 Official Journal of the European Committee, L61, April 18, 1995.
- 296 Compendium of Food Additive Specification, FAO Food and Nutrition Paper 52. Add 5., FAO, Rome 1997.
- 297 Food Chemicals Codex, 4th ed., National Academy Press, Washington D.C. 1996.
- 298 J. E. Fox: “Seed Gums,” in A. Imeson (ed.) Thickening and Gelling Agents for Food, Blackie Academic and Professional, London 1992, pp. 153 – 170.
- 299 I. C. M. Dea: “Structure/Function Relationships of Galactomannans and Food Grade Cellulosics,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 5th ed., IRL Press, Oxford 1990, pp. 373 – 382.
- 300 A. H. Clark, I. C. M. Dea, B. V. McCleary: “The Effect of the Galactomannan Fine Structure on Their Interaction Properties,” in G. O. Phillips, D. J. Wedlock, P. A. Williams (eds.): Gums and Stabilisers for the Food Industry, 3rd ed., Elsevier Applied Science Publishers, London 1985, pp. 429 – 440.
- 301 I. C. M. Dea, A. H. Clark, B. V. McCleary, Carbohyd. Res. 142 (1986) 275 – 294.
- 302 P. M. Dey, Adv. Carbohydr. Chem. Biochem. 35 (1978) 341 – 376.
- 303 B. V. McCleary, Int. J. Biol. Macromol. 8 (1986) 349 – 354.
- 304 T. J. Painter, in G Aspinall (ed.): The Polysaccharides, Vol. 2, Academic Press, London, 1983, pp. 195–285.
- 305 M. Lahaye, J. Appl. Phycol. 13 (2001) 173–184.
- 306 G. A. DeRuiter, B. Rudolph, Trends Food Sci. Technol. 8 (1997) 389–395.
- 307 S. H. Knutsen, D. E. Myslabodski, B. Larsen, A. I. Usov: “A modified system of nomenclature for red algal galactans”, Bot. Mar. 37 (1994) 163–169.
- 308 D. A. Rees, Adv. Carb. Biochem. 24 (1969) 267–332.
- 309 E. Zablackis, G. A. Santos, Botanica Marina 29 (1986) 319–322.
- 310 D. N. Smidt, W. H. Cook, Arch. Biochem. Biophys. 45 (1953) 232–233.
- 311 C. Bellion et al., Carbohydr. Res. 119 (1983) 31–48.
- 312 K. F. Wong, J. S. Craigie, Plant. Physiol. 61 (1978) 663–666.
- 313 E. L. McCandless, J. S. Craigie, J. A. Walter, Planta (Berl.) 112 (1973) 201–212.
- 314 R. Falshaw, R. H. Furneaux, Carbohydr. Res. 276 (1995) 155–165.
- 315 R. Falshaw, H. J. Bixler, K. Johndro, Food Hydrocoll. 15 (2001) 441–452.
- 316 F. Vande Velde, H. A. Peppelman, H. S. Rollema, R. H. Tromp, Carbohydr. Res. 331 (2001) 271–283.
- 317 H. J. Bixler, K. Johndro, R. Falshaw, Food Hydrocoll. 15 (2001) 619–630.
- 318 A. Amimi et al., Cabohydr. Res. 333 (2001) 271–279.
- 319 A. I. Usov, V. V. Barbakadze, Bioorg. Khim. 4 (1978) 1107–1115.
- 320 M. Ciancia, M. C. Matulewicz, A. S. Cerezo, Phytochemistry 34 (1993) 1541–1543.
- 321 R. Takano et al., Phytochemistry 37 (1994) 1615–1619.
- 322 G. M. King, G. E. Lauterbach, Botanica Marina 30 (1987) 33–39.
- 323 C. K. Tseng, Science 101 (1945) 597–602.
- 324 H. J. Bixler, K. Johndro, R. Falshaw: “Kappa-2 carrageenan: structure and performance of commercial extracts II. Performance in two simulated dairy applications”, Food Hydrocolloids 15 (2001) 619.
- 325 T. Barbeyron, D. Flament, G. Michel, P. Potin, B. Kloareg, Cahiers De Biologie Marine 42 (2001) 169.
- 326 H. J. Bixler, Hydrobiologia 327 (1996) 35.
- 327 R. A. Hoffmann, M. J. Gidley, D. Cooke, W. J. Frith, Food Hydrocoll. 9 (1995) 281–289.
- 328 A. P. Imeson, in G. O. Phillips, P. A. Williams (eds.): Handbook of Hydrocolloids, Woodhead Publishing Ltd., Cambridge, 2000, pp. 87–102.
- 329 W. Yaphe, G. P. Arsenault, Anal. Biochem. 13 (1965) 143–148.
- 330 C. N. Jol et al., Anal. Biochem. 268 (1999) 213–222.
- 331 A. I. Usov, N. G. Klochkova, Botanica Marina 35 (1992) 371–378.
- 332 R. Falshaw, R. H. Furneaux, Carbohydr. Res. 269 (1995) 183–189.
- 333 D. J. Stancioff, N. F. Stanley, Proc. Int. Seaweed Symp. 6 (1969) 595–609.
- 334 T. Chopin, E. Whalen, Carbohydr. Res. 246 (1993) 51–59.
- 335 A. I. Usov, Botanica Marina 27 (1984) 189–202.
- 336 M. Ciancia, M. C. Matulewicz, P. Finc, A. S. Cerezo, Carbohydr. Res. 238 (1993) 241–248.
- 337 D. Welti, J. Chem. Res. (M) (1977) 3566–3587.
- 338 S. H. Knutsen, D. E. Myslabodski, H. Grasdalen, Carbohydr. Res. 206 (1990) 367–372.
- 339 T. Turquois, S. Acquistapace, F. A. Vera, D. H. Welti, Carbohydr. Polym. 31 (1996) 269–278.
- 340 S. H. Knutsen, H. Grasdalen, Carbohydr. Polym. 19 (1992) 199–210.
- 341 T. Hjerde, O. Smidsrod, B. E. Christensen, Biopolymers 49 (1999) 71–80.
- 342 C. Viebke, P. A. Williams, Food Hydrocoll. 14 (2000) 265–270.
- 343 M. A. Roberts, B. Quemener, Trends Food Sci. Technol. 10 (1999) 169–181.
- 344 E. Bjerre-Petersen, J. Christensen, P. Hemmingsen, in R. L. Whistler and B. J. N. (eds.): Industrial gums. Polysaccharides and their derivatives, Academic Press, New York, 1973, pp. 123–136.
- 345 L. Piculell, in A. M. Stephen (ed.): Food polysaccharides and their applications, Marcel Dekker, Inc., New York, 1995, pp. 205–244.
- 346 T. Hjerde, O. Smidsrod, B. T. Stokke, B. E. Christensen, Macromolecules 31 (1998) 1842–1851.
- 347 C. Viebke, J. Borgstrom, L. Piculell, Carbohydr. Polym. 27 (1995) 145–154.
- 348
N. F. Stanley, in
P. Harris (ed.):
Food gels,
Elsevier Applied Science,
London,
1990, pp.
79–119.
10.1007/978-94-009-0755-3_3 Google Scholar
- 349 K. Bongaerts et al. Macromolecules 33 (2000) 8709–8719.
- 350 L. Piculell, C. Hakansson, S. Nilsson, Int. J. Biol. Macromol. 9 (1987) 297–301.
- 351 K. B. Guiseley, N. F. Stanley, P. A. Whitehouse in R. L. Davidson (ed.): Handbook of water soluble gums and resins, McGraw-Hill, New York 1980.
- 352 FMC Biopolymer: “Not Just Products. Partners. (2000), p. 10 (www.fmcbiopolymer.com).
- 353
G. H. Therkelsen, in
R. L. Whistler,
J. N. BeMiller (eds.):
Industrial gums: Polysaccharides and their derivatives,
Academic Press,
San Diego,
1993, pp.
145–180.
10.1016/B978-0-08-092654-4.50011-5 Google Scholar
- 354 M. DiRosa, J. Pharm. Pharmacol. 24 (1972) 89–102.
- 355 L. Aschheim, S. Raffel, Res. J. Reticuloendothel. Soc. (1972) 253–262.
- 356 P. Cantanzaro, H. Schwartz, R. Graham, Am. J. Pathol. 64 (1971) 387–404.
- 357 D. J. Schaeffer, V. S. Krylov, Ecotoxicol. Environ. Saf. 45 (2000) 208–227.
- 358 C. Haslin, M. Lahaye, M. Pellegrini, J. C. Chermann, Planta Medica 67 (2001) 301–305.
- 359 M. J. Carlucci et al. Antiviral Res. 43 (1999) 93–102.
- 360 P. Potin, K. Bouarab, F. Kupper, B. Kloareg, Curr. Opin. Microbiol. 2 (1999) 276–283.
- 361 F. Vande Velde, G. A. DeRuiter, in S. De Baets, E. J. VanDamme, S. Steinbüchel (eds.): Biopolymers, vol. 6 Polysaccharides II, Wiley-VCH, Weinheim, Germany, 2002.
- 362 L. G. Ekstrøm, Carbohydr. Res. 135 (1985) 283–289.
- 363 T. T. Stevenson, R. H. Furneaux, Carbohydr. Res. 210 (1991) 277–298.
Further Reading
- J. M. Aguilera, P. Lillford (eds.): Food Materials Science, Springer, New York, NY 2008.
-
G. L. Cote,
J. A. Ahlgren:
Microbial Polysaccharides,
Kirk Othmer Encyclopedia of Chemical Technology,
5th edition,
John Wiley & Sons,
Hoboken, NJ,
online DOI: 10.1002/0471238961.1309031803152005.a01.
10.1002/0471238961.1309031803152005.a01 Google Scholar
-
W. P. Edwards:
The Science of Bakery Products,
Royal Society of Chemistry,
Cambridge, UK
2007.
10.1039/9781847557797 Google Scholar
-
H.-G. Elias:
Macromolecules,
Wiley-VCH,
Weinheim
2008.
10.1002/9783527627233 Google Scholar
- H.-J. Gabius (ed.): The Sugar Code, Wiley-VCH, Weinheim 2009.
- H. G. Garg, M. K. Cowman, C. A. Hales: Carbohydrate Chemistry, Biology and Medical Applications, Elsevier, Amsterdam 2008.
- T. Heinze (ed.): Polysaccharides, Springer, Berlin 2005.
- T. Heinze, T. Liebert, A. Koschella: Esterification of Polysaccharides, Springer, Berlin 2006.
-
M. Rinaudo:
Polysaccharides,
Kirk Othmer Encyclopedia of Chemical Technology,
5th edition,
John Wiley & Sons,
Hoboken, NJ,
online DOI: 10.1002/0471238961.polyrina.a01.
10.1002/0471238961.polyrina.a01 Google Scholar
