Coal Pyrolysis

Ludwig Briesemeister

Ludwig Briesemeister

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Andreas Geißler

Andreas Geißler

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Stefan Halama

Stefan Halama

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Stephan Herrmann

Stephan Herrmann

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Ulrich Kleinhans

Ulrich Kleinhans

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Markus Steibel

Markus Steibel

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Markus Ulbrich

Markus Ulbrich

Technische Universität München, Lehrstuhl für Energiesysteme, 85748 Garching, Germany

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Alan W. Scaroni

Alan W. Scaroni

The Pennsylvania State University, University Park, Pennsylvania, 16802 United States

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M. Rashid Khan

M. Rashid Khan

USDOE, Morgantown Energy Technology Center, Morgantown, West Virginia, 26505 United States

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Semih Eser

Semih Eser

The Pennsylvania State University, University Park, Pennsylvania, 16802 United States

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Ljubisa R. Radovic

Ljubisa R. Radovic

The Pennsylvania State University, University Park, Pennsylvania, 16802 United States

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First published: 16 December 2022
Citations: 3

Abstract

The article contains sections titled:

1. Introduction
2. Thermoplastic Properties of Coal
2.1. Development of Thermoplasticity
2.1.1. Softening
2.1.2. Swelling
2.1.3. Resolidification
2.2. Experimental Methods
2.3. Experimental Variables
2.3.1. Coal Rank and Petrographic Composition
2.3.2. Heating Rate
2.3.3. Particle Size
2.3.4. Pressure
2.3.5. Atmosphere
2.3.6. Preoxidation
2.3.7. Additives
2.4. Coke Microstructure and Mesophase Formation
2.4.1. Microscopic Characterization
2.4.2. Carbonaceous Mesophase
2.4.3. Modification of Optical Texture and Properties
3. Yield and Distribution of Pyrolysis Products
3.1. Experimental Methods
3.1.1. Muffle Furnace
3.1.2. Thermogravimetric Analyzers (TGA)
3.1.3. Wire-Mesh Reactors
3.1.4. Flow Reactors
3.1.5. Fixed-Bed Reactors
3.1.6. Fluidized-Bed Reactors
3.1.7. Summary of Methods
3.2. Experimental Variables
3.2.1. Final Temperature and Residence Time
3.2.2. Coal Rank
3.2.3. Heating Rate
3.2.4. Pressure
3.2.5. Atmosphere
3.2.6. Summary of Parameter Sensitivity
4. Pyrolysis Kinetics and Modeling
5. Pyrolysis Processes
5.1. High-Temperature Processes
5.1.1. Coke Ovens
5.1.2. Formed-Coke Processes
5.1.3. Coke Properties
5.1.4. Byproducts
5.1.5. Environmental Aspects
5.2. Low-Temperature Processes
5.3. Contemporary Processes

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